• Title/Summary/Keyword: C/N RATIO

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7075-T651 Al合金의 表面균열進展에 미치는 應力比의 影響 (The Effect of Stress Ratio on the Surface Crack Growth Behavior in 7075-T651 Aluminum Alloy)

  • 박영조;김정규;신용승;김성민
    • 대한기계학회논문집
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    • 제10권1호
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    • pp.62-69
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    • 1986
  • 본 연구에서는 표면균열의 전파거동에 관한 연구의 일환으로 경량화재료 로서 항공기 구조용으로 널리 사용되고 있는 7075-T651 알루미늄합금을 준비하고 제하탄성 compliance법을 이용하여 표면 및 깊이 방향의 균열진전거동의 특성을 밝히고져 한다.

졸-겔법에 의한 Cobalt 치환된 Ba-ferrite 분말의 자기적 특성 (Magnetic Properties of Co-substituted Ba-ferrite Powder by Sol-gel Method)

  • 최현승;박효열;윤석영;신학기;김태옥
    • 한국세라믹학회지
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    • 제39권8호
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    • pp.789-794
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    • 2002
  • 본 연구에서는 TMS[Tetramethylsilane:$Si(CH_3)_4$], $NH_3$$H2$를 이용하여 나노크기의 Si-C-N precursor 분말을 합성하기 위하여 CVC법을 이용하였으며 반응온도, TMS/$NH_3$ 비 그리고 TMS/$H_2$ 비를 변화시켰다. XRD와 FESEM 분석을 통해서 결정상과 입자의 크기 그리고 입자의 형태를 관찰하고자 하였으며, 그 결과 제조된 분말은 모든 실험 조건하에서 87∼130 nm 크기를 지닌 균일한 구형의 비정질 분말이 얻어졌다. 입자 크기는 반응온도의 감소에 따라 감소하였으며, 또한 TMS/$NH_3$, TMS/$H_2$ 비가 작아질수록 감소하였다. EA 분석 결과 제조된 분말은 Si, N, C, H로 이루어졌음을 알 수 있었으며 FT-IR를 통하여 Si-N, C-N, Si-C 결합을 가진 Si-C-N precursor 분말이 제조되었다.

Effects of dietary fat saturation level on growth performance, carcass traits, blood lipid parameters, tissue fatty acid composition and meat quality of finishing pigs

  • Chen, Jing;Li, Jiantao;Liu, Xianjun;He, Yang
    • Animal Bioscience
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    • 제34권5호
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    • pp.895-903
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    • 2021
  • Objective: The objective of this study was to investigate the effects of various dietary unsaturated to saturated fatty acids ratios (UFA to SFA ratios) on growth performance, carcass traits, blood lipid parameters, tissue fatty acid (FA) composition, and meat quality of finishing pigs. Methods: A total of 45 crossbred pigs ([Duroc×Landrace]×Yorkshire), with an average initial body weight of 60.3±2.4 kg, were randomly allocated to three treatment groups of 1:1, 2:1, and 3:1 dietary UFA to SFA ratios. Results: Both average daily gain and average daily feed intake of pigs were decreased linearly (p<0.05), whereas backfat thickness was decreased linearly (p<0.05) with increasing of dietary UFA to SFA ratio. Serum triglyceride and low density lipoprotein cholesterol were decreased quadratically or linearly (p<0.05) respectively, whereas high density lipoprotein cholesterol was increased quadratically (p<0.05) with increasing dietary UFA to SFA ratio. In M. longissimus thoracis, the proportion of C18:1 and monounsaturated FA was decreased linearly (p<0.05), whereas the proportion of C18:2n-6, C20:4n-6 and polyunsaturated FA (PUFA) were increased linearly (p<0.05) as dietary UFA to SFA ratio increased. In the subcutaneous adipose tissue, the proportion of SFA was decreased linearly (p<0.05), whereas the proportion of n-6 PUFA, n-3 PUFA, and the UFA to SFA ratios were increased linearly (p<0.05) with increasing of dietary UFA to SFA ratio. Meat color scores and shear force of pigs were decreased linearly (p<0.05), whereas drip loss and cooking loss were increased linearly (p<0.05) with increasing of dietary UFA to SFA ratio. Conclusion: Appropriately boosted dietary UFA to SFA ratio could be conductive to optimize blood lipid parameters and tissue FA composition. However, when the ratio is too high or too low it tends to have negative effects on growth performance and meat quality.

D.C. Magnetron Sputter를 이용한 (Ti, Al)N 피막의 고온산화특성 (High Temperature Oxidation Characteristics of the (Ti, Al)N Coating on the STS 304 by D.C. Magnetron Sputtering)

  • 최장현;이상래
    • 한국표면공학회지
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    • 제25권5호
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    • pp.235-252
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    • 1992
  • (Ti, Al)N films were deposited on 304 stainless steel sheet by D.C. magnetron sputtering using Al target and Ti plate. The high temperature oxidation of (T, Al)N films with the variation of composition has been investigated. The chemical composition of (Ti, Al)N films with the variation of composition has been investigated. The chemical composition of (Ti, Al)N films was similar to the sputter area ratio of titanium to aluminum target by means of EDS and AES survey. The high temperature oxidation test of (Ti, Al)N showed that (Ti, Al)N has better high temperature resistance than TiN and TiC films. TiC films were cracked at 40$0^{\circ}C$ in air TiN films quickly were oxidised at $600^{\circ}C$, were spalled more than $700^{\circ}C$. But (Ti, Al)N films are relatively stable to$ 900^{\circ}C$. The good resistance to high temperature oxida-tion of (Ti, Al)N films are due to the formation of dense Al2O3 and TiO2 oxide layer. Especially, Al2O3 oxide layer is more important. The results obtained from this study show, it is believe that the (Ti, Al)N film by D.C. magnetron sputtering is promising for the use of high temperature and wear resistance mate-rials.

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메탄생산 향상을 위한 음폐수와 미세조류의 혐기성 통합소화 (Anaerobic co-digestion of food waste leachate with microalgae for improvement of methane production)

  • 이관용;프롬폴;김대기;박종진;최장승;박기영
    • 상하수도학회지
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    • 제28권1호
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    • pp.55-60
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    • 2014
  • Food waste leachate (FWL) is a serious pollutant waste coming from the food waste recycling facilities in Korea. FWL has a high organic matter content and high COD to nitrogen (COD/N) ratio, which can disturb efficient methane production in the anaerobic digestion of FWL. In the present study a microalga, Clorella vulgaris (C.V), was used as co-substrate for the FWL anaerobic digestion in order to supply nutrients, decrease the COD/N ratio and increase its methane yield. Different co-digestion mixtures (COD/N ratios) were studied by using biochemical methane potential test and modified Gompertz equation for kinetic study. Mixed substrate of FWL and C. vulgaris in the co-digestion clearly showed more the biomethane yield than the sole substrates. The maximum methane production, 827.7 mL-$CH_4$/g-VS added, was obtained for COD/N ratio of 24/1, whereas the highest improvement of methane yield was found for COD/N ratio of 15/1.

Estimation of N Mineralization Potential and N Mineralization Rate of Organic Amendments in Upland Soil

  • Shin, Jae-Hoon;Lee, Sang-Min;Lee, Byun-Woo
    • 한국토양비료학회지
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    • 제48권6호
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    • pp.751-760
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    • 2015
  • Management of renewable organic resources is important in attaining the sustainability of agricultural production. However, nutrient management with organic resources is more complex than fertilization with chemical fertilizer because the composition of the organic input or the environmental condition will influence organic matter decomposition and nutrient release. One of the most effective methods for estimating nutrient release from organic amendment is the use of N mineralization models. The present study aimed at parameterizing N mineralization models for a number of organic amendments being used as a nutrient source for crop production. Laboratory incubation experiment was conducted in aerobic condition. N mineralization was investigated for nineteen organic amendments in sandy soil and clay soil at $20^{\circ}C$, $25^{\circ}C$, and $30^{\circ}C$. N mineralization was facilitated at higher temperature condition. Negative correlation was observed between mineralized N and C:N ratio of organic amendments. N mineralization process was slower in clay soil than in sandy soil and this was mainly due to the delayed nitrification. The single and the double exponential models were used to estimate N mineralization of the organic amendments. N mineralization potential $N_p$ and mineralization rate k were estimated in different temperature and soil conditions. Estimated $N_p$ ranged from 28.8 to 228.1 and k from 0.0066 to 0.6932. The double exponential model showed better prediction of N mineralization compared with the single exponential model, particularly for organic amendments with high C:N ratio. It is expected that the model parameters estimated based on the incubation experiment could be used to design nutrient management planning in environment-friendly agriculture.

Nutrient Uptake and Growth Kinetics of Chattonella antiqua (Hada) Ono (Raphidophyceae) Isolated from Korea

  • Seo, Kyung-Suk;Lee, Chang-Kyu
    • ALGAE
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    • 제22권3호
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    • pp.235-240
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    • 2007
  • The red tide-causing flagellate Chattonella anticfua can cause mass fish kills by their clogging in fish gills. Thisstudy examined the nutrient requirements of C. antiqua isolated from Korea. C. anticfua displayed maximum growthat the day five, followed by a decrease in cell density. Nitrate and nitrite were the preferred nitrogen sources, alonewith adenosine diphosphate for phosphorus compounds. In medium that contained ammonium, a significantdecrease in cell density was observed. Half-saturation constants, Ks, calculated from the maximum growth ratewere 4.94 U|M for NC>3 and 0.79 flM for P04. The growth of C. antiqua was not within the function of the N:P ratio (RU= 0.29). With an N:P ratio as low as 10, the increase in cell density was apparent, with a higher division rate. At lev-els above 50 fiM of NaNOg or 8 ;uM of NaHUPCU, the growth rates were somewhat decreased. Phosphate was thelimiting factor for C. antiqua growth since the starvation of phosphate had brought about a rapid decrease in celldensity in semi-continuous culture. Studies about the temporal modification of the efficiency of nitrate or phosphateuptake may be necessary to explain the bloom dynamics of C. antiaua.

유기자재 시용이 벼의 생육과 질소이용효율에 미치는 영향 (Effect of Organic Materials on Growth and Nitrogen Use Efficiency of Rice in Paddy)

  • 조정래;최현석;이연;이상민;정석규
    • 한국유기농업학회지
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    • 제20권2호
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    • pp.211-220
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    • 2012
  • 탄질비가 다른 유기자재를 시용하여 벼를 유기재배 할 때 자재별 무기화 정도와 벼의 질소 이용효율을 조사하기 위해서 2009년부터 2011년까지 시험을 수행하였다. 유기자재 처리는 질소함량 90kg/ha 수준으로 가축분퇴비, 유박, 유박2배, 헤어리베치, 헤어리베치+호밀 처리구를 두었고 화학비료구와 대조구를 두었다. 유기자재 중 유박은 가장 낮은 탄소:질소비(탄질비)를 나타내었고 가축분퇴비가 가장 높은 탄질비를 보였다. 토양 pH, 탄소, 질소, 칼슘, 그리고 마그네슘 농도는 처리간에 차이가 관찰되지 않았다. 2009년과 2010년의 질소 이용효율은 유박처리구가 화학비료구와 헤어리베치 그리고 퇴비구보다 높았다. 강수량이 많았던 2011년에는 축분퇴비구가 질소이용효율이 높은 것으로 관찰되었다.

Greenhouse gases emission from aerobic methanotrophic denitrification (AeOM-D) in sequencing batch reactor

  • Lee, Kwanhyoung;Choi, Oh Kyung;Lee, Jae Woo
    • Membrane and Water Treatment
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    • 제8권2호
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    • pp.171-184
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    • 2017
  • This study presents the effect of hydraulic retention time (HRT) on the characteristics of emission of three major greenhouse gases (GHGs) including $CH_4$, $CO_2$ and $N_2O$ during operation of a sequencing batch reactor for aerobic oxidation of methane with denitrification (AeOM-D SBR). Dissolved $N_2O$ concentration increased, leveled-off and slightly decreased as the HRT increased from 0.25 to 1d. Concentration of the dissolved $N_2O$ was higher at the shorter HRT, which was highly associated with the lowered C/N ratio. A longer HRT resulted in a higher C/N ratio with a sufficient carbon source produced by methanotrophs via methane oxidation, which provided a favorable condition for reducing $N_2O$ formation. With a less formation of the dissolved $N_2O$, $N_2O$ emission rate was lower at a longer HRT condition due to the lower C/N ratio. Opposite to the $N_2O$ emission, emission rates of $CH_4$ and $CO_2$ were higher at a longer HRT. Longer HRT resulted in the greater total GHGs emission as $CO_2$ equivalent which was doubled when the HRT increased from 0.5d to 1.0 d. Contribution of $CH_4$ onto the total GHGs emission was most dominant accounting for 98 - 99% compared to that of $N_2O$ (< 2%).

세자리 Schiff Base 리간드의 몰리브덴 착물에 관하여 (제1보) (Studies on the Molybdenum Complexes with Tridentate Schiff Base Ligand (I))

  • 조기형
    • 대한화학회지
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    • 제17권3호
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    • pp.169-173
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    • 1973
  • 세자리 schiff base리간드로서 salicylidene amino-o-hydroxy benzene 은 salicylaldehyde와 o-amino phenol로서 합성하였으며 이 세자리 schiff base 리간드와 Mo(VI), Mo(V), Mo(IV) 및 Mo(III) 의 과산화상태의 몰리브덴 착물들의 반응으로 새로운 착물[Mo O$_2(H_2O)\;(C_{13}H_9O_2N)]$, [MoO Cl(H$_2O)(C_13H_9O_2N)]$, $[Mo(SCN)_2(H_2O)(C_{13}H_9O2_N)]$$[Mo(H_2O)_2 (C_{13}H_9O_2N)]_2O$들을 얻었다. 이들 착물에서 Mo(VI), Mo(V) 및 Mo(IV)착물들은 리간드와 몰리브덴의 mole비가 1:1인 착물로서 몰리브덴 이온은 6배위 팔면체로서 주어지나 Mo(III) 착물은 Mo-O-Mo의 산소 bridge bond를 갖는 poly nuclear 착물로서 mole비 1:1인 착물로 주어짐을 원소분석치와 자외선흡광도 및 적외선 spectra의 고찰로서 알아보았다.

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