• Journal of Hydrogen and New Energy
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• v.16 no.4
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• pp.391-399
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• 2005

This paper deals with the survey of domestic hydrogen production, consumption, and distribution. The amount of domestic hydrogen production and consumption has not been identified, and we survey the amount of domestic hydrogen production and consumption by industries. The hydrogen production industries are classified into the oil industry, the petrochemical industry, the chemical industry, and the other industry. In 2004, the amount of domestic hydrogen production was 972,601 ton, which corresponded to 1.9% of the global hydrogen production. The oil industry produced 635,683 ton(65.4%), the petrochemical industry produced 241,970 ton(24.9%), the chemical industry produced 66,250 ton(6.8%), the other industry produced 28,698 ton(2.9%). The hydrogen consumptions of corresponding industries were close to the hydrogen productions of industries except that of the other industry. Most hydrogen was used as non-energy for raw materials and hydrogen additions to the process. Only 122,743 ton(12.6%) of domestic hydrogen was used as energy for heating boilers. In 2004, 47,948 ton of domestic hydrogen was distributed. The market shares of pipeline, tube trailers and cylinders were 84.4% and 15.6%, respectively. The purity of 31,848 ton(66.4%) of the distributed hydrogen was 99.99%, and 16,100 ton(33.6%) was greater than or equal to 99.999%. Besides domestic hydrogen, we also identify the byproduct gases which contain hydrogen. The iron industry produces COG( coke oven gas), BFG(blast furnace gas), and LDG(Lintz Donawitz converter gas) that contain hydrogen. In 2004, byproduct gases of the iron industry contained 355,000 ton of hydrogen.

• Journal of Hydrogen and New Energy
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• v.13 no.4
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• pp.330-338
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• 2002

A long-term energy system in the future is expected to be based on the ideal circulation system between water and hydrogen in the sense that the hydrogen prepared from water eventually returns to water again after its use. Currently, with respect to the hydrogen energy system, it is predicted that the turning-point at which the production cost of hydrogen will become to be lower than that of fossil fuels would be after 2010. However, fuel cell technology would be able to be practically used for the applications to the transportation vehicles and small-scale power sources from 2004, and therefore, an efficient construction of the infrastructure covering hydrogen production and supply systems would be required with short-/mid-term technologies for the $CO_2$ reduction associated with fossil fuel utilization. In this paper, the hydrogen quantity available in domestic market has been estimated focusing on the hydrogen by-produced from domestic industries, and also the infrastructure for hydrogen-driven vehicles like fuel cell cars has been reviewed.

• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.13-18
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• 2017

Sodium borohydride, $NaBH_4$, shows a number of advantages as hydrogen source for UAV PEMFC (Unmaned Aerial Vehicle Proton Exchange Membrane Fuel Cells). In order to use for UAV, the weight and volume of byproduct should be small after $NaBH_4$ hydrolysis reaction. Therefore, the weight and volume of byproduct were studied after $NaBH_4$ hydrolysis reaction using unsupported catalyst. The effect of catalyst type, concentration of $NaBH_4$, concentration of NaOH and thickness of catalyst pack on the weight and volume of byproduct were studied. Most of byproduct was $NaB(OH)_4$ and superficial volume of byproduct increased due to foam evolved from byproduct. The weight and volume of byproduct were not affected by concentration of NaOH used stabilizer. The weight of byproduct decreased as concentration of $NaBH_4$ solution increased, but maximum volume of byproduct obtained at 23 wt% of $NaBH_4$. Suitable defoaming agent reduced the volume of byproduct.

• Journal of Hydrogen and New Energy
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• v.7 no.2
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• pp.193-206
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• 1996

The simplest and lightest element-hydrogen is an alternative fuel which provides a clean and renewable energy source. Hydrogen can be used to power gas-type appliance and modified automobiles with water vapor as the only byproduct of combustion. Historically, production of hydrogen from coal was one of the mass production technology of hydrogen. In this paper, the status of hydrogen production process from coal was investigated to review the current situation of hydrogen production and utilization.

• Nuclear Engineering and Technology
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• v.39 no.1
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• pp.1-8
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• 2007

Hydrogen and electricity are expected to dominate the world energy system in the long term. The world currently consumes about 50 million metric tons of hydrogen per year, with the bulk of it being consumed by the chemical and refining industries. The demand for hydrogen is expected to increase, especially if the U.S. and other countries shift their energy usage towards a hydrogen economy, with hydrogen consumed as an energy commodity by the transportation, residential and commercial sectors. However, there is strong motivation to not use fossil fuels in the future as a feedstock for hydrogen production, because the greenhouse gas carbon dioxide is a byproduct and fossil fuel prices are expected to increase significantly. An advanced reactor technology receiving considerable international interest for both electricity and hydrogen production, is the modular helium reactor (MHR), which is a passively safe concept that has evolved from earlier high-temperature gas-cooled reactor (HTGR) designs. For hydrogen production, this concept is referred to as the H2-MHR. Two different hydrogen production technologies are being investigated for the H2-MHR; an advanced sulfur-iodine (SI) thermochemical water splitting process and high-temperature electrolysis (HTE). This paper describes pre-conceptual design descriptions and economic evaluations of full-scale, nth-of-a-kind SI-Based and HTE-Based H2-MHR plants. Hydrogen production costs for both types of plants are estimated to be approximately $2 per kilogram.

• Korean Journal of Metals and Materials
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• v.50 no.2
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• pp.183-190
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• 2012

Hydrogen was generated by the reaction of metal hydride with water. The variation of hydrogen generation with the kind of powders (milled $MgH_2$, and $MgH_2$ milled with various contents of MgO, $MgCl_2$ or $Ni+Nb_2O_5$) was investigated. $MgH_2$ powder with a hydrogen content of 6.05 wt% from Aldrich Company was used. Hydrogen is generated by the reaction of Mg as well as $MgH_2$ with water, resulting in the formation of byproduct $Mg(OH)_2$. For about 5 min of reaction time, milled $95%MgH_2+5%MgO$ has the highest hydrogen generation rate among milled $MgH_2+x%MgO$ (x=0, 5, 10, 15 and 20) samples. Milled $90%MgH_2+10%MgCl_2$ has the highest hydrogen generation rate among all the samples.

• Journal of the Korean Institute of Gas
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• v.25 no.1
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• pp.1-6
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• 2021

Based on Korea's Hydrogen Economy Activation Roadmap, an annual supply of 5.26 million tonnes of hydrogen is required by 2040. But if the hydrogen production from byproduct, extraction, and electrolysis of water is not able to meet the target which is 50% of total production, it would be necessary to increase the portion of imported hydrogen. Therefore, it is essential to secure a variety of sources for overseas production. In this technical report, hydrogen production/transportation policies, current condition, and future prospects of Canada, a major supply candidate, is examined and an example of blue hydrogen project which is considered the most realistic hydrogen supply method is introduced.

• Korean Chemical Engineering Research
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• v.45 no.1
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• pp.25-31
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• 2007

In a petrochemical complex, large amount of hydrogen is produced as a by-product and used as a fuel in petrochemical and oil refinery plants. By recycling this byproduct hydrogen as a raw material, the value of hydrogen can be greatly improved. This paper proposes a design methodology for optimal hydrogen recycle network between plants in petrochemical complex by analyzing the hydrogen pinch, required cost and constraints.

• Journal of The Korean Society of Clinical Toxicology
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• v.2 no.2
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• pp.147-150
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• 2004

Hydrogen sulfide is a colorless, and malodorous 'rotten eggs' gas that results from the decay of organic material. It is a byproduct of industry and agriculture. The mechanism of its toxicity is primarily related to inhibition of oxidative phosphorylation, which causes a decrease in available cellular energy. Because there is no rapid method of detection that is of clinical diagnostic use, management decisions must be made based on history, clinical presentation, and diagnostic tests that imply hydrogen sulfide's presence. Although there is some anecdotal evidence to suggest that the early use of hyperbaric oxygen is beneficial, supportive care remains the mainstay of therapy. We describe an occupational exposure to hydrogen sulfide gas in 51-year-old man. While cleaning the sewage of pigs. he became unconscious. When he arrived in the emergency department, he had irritability and confused mentality. The typical smell of rotten eggs on clothing and exhaled air were enough to be considered to be exposed to hydrogen sulfide. Hyperbaric oxygen therapy was performed. He had a recovery to normal function.

• Proceedings of the KIEE Conference
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• 1998.11c
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• pp.950-952
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• 1998

DC Arc Plasma was applied in order to convert of hydrocabon fuels (Methane) to hydrogen, which has higher available energy. Plasma can generate very high temperatures with a high degree of control, using electricity. Plasma can be used to produce the pure hydrogen fuel, and has rapid response time. In addition, the use of plasma could provide for a greater variety of operating modes including the posibility of virtual elimination of $CO_2$ production by pyrolytic operation and could obtain byproduct (Carbonblack).