• 한국세라믹학회지
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• 제28권9호
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• pp.667-674
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• 1991

In this study, Kaolin was carbonized at 1300~175$0^{\circ}C$ and its constituent mineral change was investigated. Carbonized kaolin at 1$650^{\circ}C$ was mixed with metallic silicon, formed and nitrified at 135$0^{\circ}C$ in N2-NH3 atmosphere. Properties of this product such as porosity, bulk density, MOR, nitrization rate and oxidation resistence were measured, and its mineralogical changes were investigated by XRD. The results were as follows; 1) $\beta$-SiC was initially synthesized at 150$0^{\circ}C$, and its amount was continuously increased with reaction temperature to 1$700^{\circ}C$. 2) At 1$600^{\circ}C$, mullite was rapidly decomposed and the amounts of $\beta$-SiC and $\alpha$-Al2O3 were increased simultaneously. 3) By adding alkali to kaolin, the decomposition temperature of mullite was dropped approximately 10$0^{\circ}C$, but the amount of $\alpha$-SiC was increased. 4) The highest values of their nitrization rate and MOR were obtained at the specimen of 35 wt% metallic silicon in nitrization reaction. 5) It seems that increment of $\alpha$-Si3N4 and $\alpha$-Al2O3 phase during nitrization was due to the decomposition of Al4SiC4 existed in carbonized kaolin. 6) Si3N4 bonded SiC-Al2O3 composite were fabricated from kaolin at relatively low temperature (135$0^{\circ}C$).

• 한국분말재료학회지
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• 제8권3호
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• pp.163-167
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• 2001

A bulk porous $CaZrO_3/MgO$ composite with plantinum nano-dispersion was synthesized in air atmosphere through the combination of several in situ reactions, including the pyrolysis of $PtO_2$. A mixture of $CaMg(CO_3)_2$(dolomite), $ZrO_2$, $PtO_2$ and LiF (0.5 wt%, as an additive) was cold isostatically pressed at 200 MPa and sintered at $1100^{\circ}C$ for 2 h. The porous $CaZrO_3/MgO/Pt$ composite ($CaZrO_3/MgO$ : Pt=99 : 1 in volume) had a uniformly open-porous structure (porosity: 56%) with three-dimensional (3-D) network and a narrow pore-size distribution, similarly to the porous $CaZrO_3/MgO$ composites reported before. Catalytic Properties (viz., NO direct decomposition and NO reduction by $C_2H_4$) of the $CaZrO_3/MgO/Pt$ composite were investigated up to $900^{\circ}C$. In the absence of oxygen, the NO conversion rate reached ~52% for the direct decomposition and ~100% for the reduction by $C_2H_4$, respectively. The results suggest the possibility of the porous composite as a multifunctional filter, i.e., simultaneous hot gas-filtering and $de-NO_x$ in one component.

• 한국재료학회지
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• 제19권4호
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• pp.220-223
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• 2009

Lithium dihydrogen phosphate ($LiH_2PO_4$) powder was purchased from Aldrich Chemical Co. From the scanning electron microscope (SEM) observation, these polycrystals have dimensions in the range of $25-250{\mu}m$. The electrical conductivity was measured at a measuring frequency of 1 kHz on heating polycrystalline lithium dihydrogen phosphate ($LiH_2PO_4$) from room temperature to 493 K. Two anomalies appeared at 451 K ($T_{p1}$) and 469 K ($T_{p2}$). The electrical conductivity reached the magnitude of the superprotonic phases: $3{\times}10^{-2}{\Omega}^{-1}cm^{-1}$ at 451 K ($T_{p1}$) and $1.2{\times}10{\Omega}^{-1}cm^{-1}$ at 469 K ($T_{p2}$). It is uncertain whether the superprotonic phase transformations are due to polymorphic transitions in the bulk, surface transitions, or chemical reactions (thermal decomposition) at the surface. Considering several previous thermal studies (differential scanning calorimetry and thermogravimetry), our experimental results seem to be related to the last case: chemical reactions (thermal decomposition) at the surface with the progressive solid-state polymerization.

• 한국항만경제학회지
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• 제27권2호
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• pp.217-240
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• 2011

이 연구는 VAR 모형을 이용하여 국제유가가 BDI, 선형에 따라 BCI, BPI 등 3개의 운임 지수에 각각 어떠한 영향을 미치는지와 VECM모형을 이용하여 케이프사이즈와 파나막스 시장 간의 파급효과를 분석하였다. 첫째, VAR모형을 이용하여 국제유가의 변화가 BCI에 미치는 효과는 시차 1기의 경우 통계적으로 정(+)의 유의적인 효과를 갖고, BPI의 경우에는 시차 3기의 경우에만 음(-)의 유의적인 효과를 갖고, BDI 운임지수에 미치는 효과는 시차 1기의 경우 통계적으로 정(+)의 유의적인 효과를 갖는 것으로 나타났다. 충격반응함수 분석의 결과는 국제유가의 충격으로부터 BDI의 반응은 약 3개월 정도 지속적으로 상승하다가 이후로는 감소하는 것으로 나타났다. 둘째, VECM모형을 이용하여 케이프사이즈와 파나막스 시장 간의 파급효과를 분석한 결과는 BCI와 BPI 운임지수 간에 장기적인 균형관계로부터의 이탈이 발생하는 경우 BPI 운임지수가 감소하는 방향으로 조정되었다. 또한 동태적인 상관관계의 경우 시차 1기의 케이프사이즈 시장에서의 운임이 상승하면 금기의 파나막스 시장에서의 운임이 상승하는 것으로 나타났다. BCI와 BPI 운임지수간의 동학적인 충격반응함수의 분석으로부터 BCI 운임지수의 충격으로부터 BPI 운임지수의 반응은 약 3개월 정도 가파르게 상승하다가 5개월 이후로는 변화가 없는 것으로 나타났고, BPI 운임지수의 충격에 대한 BCI 운임지수의 충격반응의 정도는 매우 작게 나타났으며, 약 3개월 정도 완만하게 상승하다가 이후로 거의 변화가 없는 것으로 나타났다.

• 공업화학
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• 제9권6호
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• pp.846-851
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• 1998

w/o 에멀젼 내에서 균일용액침전반응을 진행시켜 산화아연 미세 입자를 제조하는 실험적 연구를 수행하였다. 질산아연 수용액에 hexamethylene tetramine (HMTA)을 침전제로 첨가한 침전액은 유화제 Span 80에 의해 kerosine과 안정한 w/o 에멀젼을 형성하였다. 얻어진 w/o 에멀젼을 HMTA 분해온도 이상($85^{\circ}C$)으로 가열하여 w/o 에멀젼 내에서 균일용액 침전반응을 진행시키면 산화아연 입자들이 제조되는 것을 확인하였다. 이렇게 제조된 산화아연 입자들은 이중분산 (bi-modal distribution)을 갖는 영역이 존재하기도 하였으나, 균일용액침전법에 비하여 높은 초기 아연농도와 높은 수율에서도 입자가 작고 입도분포가 비교적 좁은 산화아연 입자들을 얻을 수 있었다.

• 한국대기환경학회지
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• 제6권1호
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• pp.11-21
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• 1990

To quantitatively estimate the effect of yellow sand(loess) fromt he Northern China, various soil sources having similar chemical compositions to yellow sands should be separated and identified. After that, mass contribution for yellow sand can be calculated. The study showed that it was impossible to solve this problem by the traditional bulk analyses. However, particle-by-particle analysis by a CCSEM (computer controlled scanning electron microscope) gave enormous potentials to solve it. To perform this study, seven soil source data analyzed by CCSEM were obtained from Texas, U.S.A. Initially, each soil date was classified into two groups, coarse and fine particle groups since the particle number distribution showed a minimum occurring at 5.2$\mu$m of aerodynamic diameter. Particles in each group were then classified into one of the 283 homogeneous particle classes by the universal classification rule which had been built by an expert system in the early study. Further, mass fractions and their uncertainties for each class in each source were calculated by the Jackknife method, and then source profile matrix for the 7 soil sources was created. To use the profile matrix in the study of source contribution, it is necessary to test the degree of collinearity among sources. The profiles were tested by the singular value decomposition method. As a result, each soil source characterized by artificially created variables was totally independent each other and is ready to use in source contribution studies as a receptor model.

• 한국전기전자재료학회논문지
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• 제13권11호
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• pp.969-975
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• 2000

Laser direct writing of micro-patterned copper lines has been achieved by pyrolytic decomposition of copper formate films (Cu(HCOO)$_2$.4$H_2O$), as a metallo-organic precursor, using a focused CW Ar$^{+}$ laser beam (λ=514nm) on PCB boards and glass substrates. The linewidth and thickness of the lines wee investigated as a functin of laser power and scan speed. The profiles of the lines were measured by scanning electron microscope (SEM), surface profiler ($\alpha$-step) and atomic force measured by scanning electron microscope (SEM), surface profiler ($\alpha$-step) and atomic force microscopy (AFM). The electrical resistivities of the patterned lines were also investigated as a function of laser parameters using probe station and semiconductor analyzer. We compared resistivities of the patterned copper lines with these of the Cu bulk. Resistivities decreased due to changes in morphology and porosity of the deposit, which were about 3.8 $\mu$$\Omega$cm and 12$\mu$$\Omega$cm on PCB and glass substrates after annealing at 30$0^{\circ}C$ for 5 minutes.s.

• 한국분말재료학회지
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• 제28권4호
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• pp.342-351
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• 2021

Because of its unique properties, tungsten is a strategic and rare metal used in various industrial applications. However, the world's annual production of tungsten is only 84000 t. Ammonium paratungstate (APT), which is used as the main intermediate in industrial tungsten production, is usually obtained from tungsten concentrates of wolframite and scheelite by hydrometallurgical treatment. Intermediates such as tungsten trioxide, tungsten blue oxide, tungstic acid, and ammonium metatungstate can be derived from APT by thermal decomposition or chemical attack. Tungsten metal powder is produced through the hydrogen reduction of high-purity tungsten oxides, and tungsten carbide powder is produced by the reaction of tungsten powder and carbon black powder at 1300-1700℃ in a hydrogen atmosphere. Tungsten scrap can be divided into hard and soft scrap based on shape (bulk or powder). It can also be divided into new scrap generated during the production of tungsten-bearing goods and old scrap collected at the end of life. Recycling technologies for tungsten can be divided into four main groups: direct, chemical, and semi-direct recycling, and melting metallurgy. In this review, the current status of tungsten smelting and recycling technologies is discussed.

• 한국재료학회지
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• 제32권1호
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• pp.1-8
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• 2022

In this investigation, Bi₂MoO₆ deposited graphene nanocomposite (BMG) was synthesized using a simple microwave assisted hydrothermal synthesis method. The synthesized BMG nanocomposite was characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy with energy dispersive X-ray analysis, and photocurrent analysis. The study revealed that the catalysts prepared have high crystalline nature, enhanced light responsive property, high catalytic activity, and good stability. XRD results of BMG composite exhibit a koechlinite phase of Bi₂MoO₆. The surface property is shown by SEM and TEM, which confirmed a homogenous composition in the bulk particles of Bi₂MoO₆ and nanosheets of graphene. The catalytic behavior was investigated by the decomposition of Rhodamine B as a standard dye. The results exhibit excellent yields of product derivatives at mild conditions under ultrasonic/visible light-medium. Approximately 1.6-times-enhanced sono-photocatalytic activity was observed by introduction of Bi₂MoO₆ on graphene nanosheet compared with control sample P25 during 50 min test.

• 한국수소및신에너지학회논문집
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• 제34권2호
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• pp.169-177
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• 2023

Phase stability diagrams were constructed for magnesium alanate (Mg(AlH₄)₂) nanoparticles to investigate the reversible hydrogen storage reaction by using density functional theory. Our findings indicate that bulk Mg(AlH₄)₂ shows favorable hydrogen release, but unfavorable hydrogen uptake (adsorption) reactions. However, for Mg(AlH₄)₂ nanoparticles, it was observed that hydrogen release and recharge can be achieved by controlling the particle size and temperature. Furthermore, by predicting the decomposition phase diagram of Mg(AlH₄)₂ nanoparticles with varying hydrogen partial pressure, it was discovered that reversible dehydrogenation reactions can occur even in relatively large nanoparticles by controlling the hydrogen partial pressure.