• Title/Summary/Keyword: Buffer Solution

Search Result 1,000, Processing Time 0.025 seconds

Hydroxyapatite Formation on Fluoride Bioactive Glasses coated on Alumina (알루미나에 코팅된 불화물 생체유리에의 수산화 아파타이트 형성)

  • 안현수;이은성;김철영
    • Journal of the Korean Ceramic Society
    • /
    • v.36 no.10
    • /
    • pp.1087-1093
    • /
    • 1999
  • Bioglass which is one of the surface active bionmaterials has a good biocompatibility but a poor mechanical strength, In the present work therefore two types of fluoride-containing bioglasses were coated on an alumina to improve mechanical strength. Crystallization of the coating layer and the hydroxyapatite formation on the bioactive glass coatings in tris-buffer solution were studied. When bioactive glass coated alumina was heat-treated Na2CaSi3O8 crystal was formed on the layer at lower temperature while wollastonite(CaSIO3) was obtained at higher temperature. Hydroxyapatite forming rate on the coating layer with Na2CaSi3O8 crystal was delayed with SiO2 contents in glass composition. However the hydroxyapatite was developed in 20minutes regardless SiO2 contents when the coating layer crystallized into wollastonite. More amount of P3+ ions were leached out of the coating layer with wollastonite than that with Na2CaSi3O8 crystal while Na+ and Ca2+ ions were leached out more easily from the Na2CaSi3O8 crystal containing coating layer.

  • PDF

Effects of Methacrylamide Treatment on Silk Fibers I. Effects of Reaction Conditions on Weight Increase of Silk Fibers (견섬유에 대한 메타크릴아미드의 처리효과 I. 반응조건에 따른 견섬유의 무게 증가)

  • 신태섭;남중희
    • Journal of Sericultural and Entomological Science
    • /
    • v.33 no.2
    • /
    • pp.82-86
    • /
    • 1991
  • The treatments of methacrylamide on silk fibers were studied in aqueous solution using potassium persulfate as an initiator, and suitable conditions of reaction were determined for weighing of silk fibers. The results obtained were summarized as follows ; The weight of MAA-treated silk fibers increased with monomer concentration. The adequate concentration of potassium persulfate was found to be 1.7%. Maximum weight increase was shown at initial pH 3.8 of reaction liquor controlled by buffer solution.

  • PDF

Solution of the Drum-Buffer-Rope Constraint Scheduling Problems incorporated by MRP/JIT - (MRP와 JIT에 부합하는 DBR 제약일정계획문제 해법)

  • 김진규
    • Journal of Korean Society of Industrial and Systems Engineering
    • /
    • v.23 no.59
    • /
    • pp.21-36
    • /
    • 2000
  • The drum-buffer-rope(DBR) system is a finite scheduling mechanism that balances the flow of the production system. DBR controls the flow of materials through the plant in order to produce products in accordance with market demand, with a minimum of manufacturing lead time, inventory, and operating expenses. This paper integrates the best of MRP push system and JIT pull system with DBR system, efficiently adapts these logics to capacity constraint resources, and contributes to the evolution of synchronous manufacturing. The purpose of this paper is, thus, threefold. The first objective is to identify the frame of theory of constraints(TOC) and the logic of DBR scheduling. The second objective is to formulate the DBR constraint scheduling problems(DBRCSP) in a job shop environments. Finally, the paper is to suggest the solution procedure of DBRCSP for embedding TOC into MRP/JIT along with an numerical expression. In addition, illustrative numerical example is given.

  • PDF

Dyeing Properties of Silk Fabric Dyed with Black Soybean Extracts (흑두 추출물에 의한 견직물의 염색성)

  • Ryu Jung Min;Jeon Young Sil;Kim In Hoi;Nam Sung Woo
    • Textile Coloration and Finishing
    • /
    • v.17 no.5 s.84
    • /
    • pp.20-25
    • /
    • 2005
  • The colorants were extracted from black soybean using a buffer solution. Dyeing properties and the fastness of silk fabric dyed with black soybean extracts were investigated. K/S values of dyed fabric were increased with concentration of black soybean extracts. Magnesium sulfate, nickel sulfate and calcium chloride as mordants are used to obtain reddish purple color. Optimum dyeing temperature of black soybean extracts was $30^{\circ}C$. Fastness were generally good except for light fastness which was extremely poor.

A Study on Pattern Formation of Ultra Definition Display Panel Applying Phosphoric Acid (인산을 적용한 Ultra Definition 디스플레이 패널의 패턴 형성에 관한 연구)

  • Kim, Min-Su;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
    • /
    • v.13 no.3
    • /
    • pp.13-19
    • /
    • 2014
  • Phosphoric acid was used as etching agent instead of conventional peroxide - based chemicals for forming pattern of ultra definition display. Etchant was synthesized by mixing etching agent, oxidation agent, buffer solution, and additive into solvent, deionized water. Thicknesses of copper, main metal of ultra definition display, for etching, were 10,000 and $30,000{{\AA}}$. Etch stop of good low skew for proper pattern formation has been occurred at the content ratio of phosphoric acid 60 - 64%, nitric acid 4 - 5%, additive(potassium acetate) 1 - 3%. Buffer solution(acetic acid) decreased the metal contact angle $63.07^{\circ}$ to $42.49^{\circ}$ for benefiting pattern formation. Content variations on four components (phosphoric acid, nitric acid, acetic acid, potassium acetic acid) of the etchant with storage time were within 3 wt% after 24 hrs of etching work.

Effect of Modifiers in Bioglass on the Glass Properties and the Formation of Apatite (Bioglass내의 수식체가 유리의 물성 및 아파타이트 형성에 미치는 영향)

  • 길철영;이호필
    • Journal of the Korean Ceramic Society
    • /
    • v.29 no.8
    • /
    • pp.623-629
    • /
    • 1992
  • The possible use of bioglass as implant materials is due to its biocompatibility to human body. Even if many animal studies for the bioglasses have been performed, their compositional dependences of structures and physical properties are not fully understood. In the present work, physical property measurements such as density and thermal expansion coefficient were carried out for the bioglasses, with substitution of CaO for Na2O in bioglass composition (46.1%SiO2, 24.4%Na2O, 26.9%CaO, 2.6%P2O5:mol%). Hydroxyapatite formation on the glass surface was also examined after reacted in Tris-buffer solution. As CaO was substituted for Na2O, the bond strength between nonbridging oxygen and modifier became stronger to make glass structure rigid, and resulted in increase in density and decrease in thermal expansion coefficient. When the bioglasses were reacted in Tris-buffer solution, hydroxyapatite was formed on the bioglass surface for all prepared glasses in 2 hours, independently on CaO content, and the thickness of hydroxyapatite layer was decreased a little, while the thickness of SiO2 rich layer was decreased sharply with CaO content.

  • PDF

A Determination on Optimal Configuration of Flexible Manufacturing System (유연생산시스템의 최적구성 결정)

  • 장진익;김원중
    • Journal of Korean Society of Industrial and Systems Engineering
    • /
    • v.24 no.67
    • /
    • pp.19-26
    • /
    • 2001
  • A design issue for a flexible manufacturing system is to find the number of each resource type which assures a given production ratio with a minimal cost. The FMS is modeled as a closed queueing network with a local buffer of limited capacity. An efficient method to determine this optical configuration is presented. The proposed method consists of three steps : 1) determine a lower configuration, 2) derive a heuristic solution, 3) find the optimal solution. The derived heuristic solutions are close to the optical solution.

  • PDF

L-Ascorbic Acid-2-Phosphate Mg염의 합성 및 응용

  • 양창모
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.13 no.1
    • /
    • pp.29-35
    • /
    • 1987
  • Purely synthesized L-ascorbic acid 2 phosphate Mg salt (1 AsA PMg) improved the weak point of ascorbic acid which is easily decomposed in water solution. This compound is hydrolyzed with phosphatase of skin to corresponding ascorbic acid giving Vitamine C activities. The buffer solution of potassium acetate 0.5% and citric acid 0.005% and the sodium sulfite respectively showed good stabilizing effect of the AsA PMg solution. Compared to the other ascorbic acid derivatives the good solubility of AsA PMg gives broad application to cosmetic field.

  • PDF

Studies on Solvent Sublation of Trace Heavy Metals by Continuous Flow System as Ternary Complexes of 1,10-Phenanthroline and Thiocyanate Ion

  • Kim, Young-Sang;Choi, Yoon-Seok;Lee, Won
    • Bulletin of the Korean Chemical Society
    • /
    • v.24 no.12
    • /
    • pp.1775-1780
    • /
    • 2003
  • A continuous flow system has been developed to determine trace Cu(II), Mn(II), Ni(II) and Zn(II) in a large volume of water samples by a solvent sublation technique. The mixed solution of 1,10-phenanthroline(phen) and thiocyanate ion was used as ligands for the formation of their ternary complexes. The continuous system was constructed in this laboratory with a peristaltic pump, a mini shaker, three mixing bottles and a flotation cell by connecting each part with a polyethylene tube. The flotation conditions such as the flow rate of sample solution and the injection rates of ligand, buffer and surfactant solutions have been investigated to obtain the best sublation efficiencies. Each solution flowed into the flotation cell through each polyethylene tube by the peristaltic pumps. The ternary complexes were floated and extracted into MIBK in a flotation cell of 2 L by bubbling a nitrogen gas. The absorbances of extracted analytes in MIBK were directly measured by graphite furnace-AAS. The concentrations of 1,10-phenanthroline and thiocyanate ion were $2.6\;{\times}\;10^{-3}$ M and $2.3\;{\times}\;10^{-2}$ M in the mixed solution, respectively. The pH of sample solution was adjusted to 5.0 with a buffer solution and 1%(m/v) sodium lauryl sulphate solution was added as a surfactant to support the effective flotation of the complexes. The $N_2$ gas was bubbled at 30 mL/min for 90 minutes for 20 L of sample. Reproducible results of less than 10% RSD and recoveries of 80-120% could be obtained in real samples.