• Advances in concrete construction
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• v.10 no.5
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• pp.393-402
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• 2020

The given research focuses on examining the effect of relatively humidity (RH) and curing temperature on the hydrates as well as the porosity of calcium sulfoaluminate (CSA) cement pastes. Numerous tests, which consist of mercury intrusion porosimetry (MIP), thermosgravi metric (TG) and X-ray diffraction (XRD) were conducted. Various characterization techniques which include, scanning electron microscopy, Fourier transform microscopy along with X-ray diffraction evaluations were conducted on the samples to examine phase formation and crystallinity, morphology and microstructure along with bond formations and functional groups, respectively. During long-term study, the performance of concrete which consisted of limestone and flash-calcined was close to those from standard Portland cement concrete. Traditional classifications and methods of corrosion were widely used for the assessment of steel in concrete which may get employed to concrete which contains LC3 to recalibrate the range of polarization resistance for passitivity condition. For example, there is up to 79.5% and 146% respective flexural and compressive strengths. Moreover, they developed more advance electrical and thermo-mechanical performance with a substantial reduction in absorption of water of close to 400%. These advantages allow this research crucial to evaluate how these methods can be applied. Additionally, the research evaluates developed and more advanced cement preservation and repair techniques. The conclusion suggests concerted efforts by various stakeholders such as policy makers to enable low-carbon rates.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.1
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• pp.35-44
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• 2015

Two main parameters were examined such as CSA content and polymer-binder ratio to find effects on the strength, water absorption, chloride ion penetration depth, carbonation depth, length change and chemical resistance of polymer-modified mortar with CSA and EVA polymer powder (EVAPP). As results, compressive, flexural, tensile, adhesive strengths, and length change of the polymer-modified mortar with CSA and EVAPP increases with increasing CSA content and polymer-binder ratio, although the water absorption, chloride ion penetration depth, and carbonation depth decrease with increasing polymer-binder ratio and CSA content, and also the chemical resistance decreases. Such strength and durability development is attributed to the high tensile strength of EVA polymer and the improved bond between cement hydrates and aggregates because of the addition of EVAPP and CSA.

• Tunnel and Underground Space
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• v.25 no.3
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• pp.293-302
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• 2015

Thin Spray-on Liner (TSL) has been considered as a new rock support to replace shotcrete as well as wire mesh. However, the development of its original production technology is highly in demand since it is not open to the public. Therefore, two kinds of powder-type TSL prototypes were developed as the first development stage. Then, their mechanical properties were experimentally compared with those of a two-component foreign TSL material including both of liquid and powder components. From a series of experiments, the first TSL prototype mixing condition satisfied every TSL performance requirements specified by EFNRAC (2008), and showed much higher tensile and bond strengths than those of the two-component foreign TSL, even though the other TSL prototype cannot be used as a support member since its elongation at break is much lower than its corresponding EFNARC (2008) performance criterion. In addition, a further study to increase the ductility of the first TSL prototype might be necessary to guarantee its higher applicability to field conditions.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1161-1168
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• 1999

The redox property of oxide materials of the 3rd period transition metals(Cr~Zn), V, Mo, and W was studied with temperature-programmed reduction/temperature-programmed oxidation(TPR/TPO) experiment. The peak temperatures of TPO spectra were equal to or lower than those of TPR spectra. And the peak shapes of TPO spectra were broader than those of TPR ones. The activation energies of TPR/TPO for the oxides of the 3rd period transition metals showed in the range of 33~149 kJ/mol, while for the oxides of V, Mo, and W, they showed relatively higher values. The change of activation energies of TPR/TPO with various metal oxides showed a similar trend to the change of their metal-oxygen bond strengths. The change of activation energies of o-xylene oxidation for various metal oxides was proportional to the difference (${\Delta}E_a$) between the activation energy of TPR and that of TPO. From these results, we concluded that the oxidation of o-xylene over various metal oxide catalysts follows the Mars-van Krevelen mechanism including the surface reduction-oxidation of the metal oxide itself.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.6
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• pp.87-94
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• 2007

Reuse of recycled aggregate from demolished concrete structure is beneficial and necessary from the viewpoint of environmental preservation and effective utilization of resources. The most important mechanical properties of recycled aggregate concrete (RAC) are the compressive strength, the tensile and the flexural strengths, the bond strength and the elastic modulus of such concrete. In particular, the stress-strain relation and fracture process of RAC in compression is especially important in theoretical and numerical analysis as well as engineering design of RAC structures. In this paper, to clarify the characteristics of fracture process in RAC, acoustic emission(AE) method is applied to detect micro-cracking in concrete under compression. From AE parameters, it is found that cracking and fracture behaviors in recycled aggregate concrete fairly differ from that of normal and recycled sand concrete.

• Bulletin of the Korean Chemical Society
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• v.27 no.4
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• pp.508-514
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• 2006

In this study, we have performed ab initio computer simulations to investigate the conformational and complexation characteristics of the trimethyl ether of p-tert-butylmonodeoxycalix[4]arene (6) with a potassium ion. The structures of different conformers of 6 and their potassium complexes were optimized by using ab initio RHF/6-31G and B3LYP/6-31G(d,p) methods. The relative stability of the various conformers of the uncomplexed 6 is in following order: cone (most stable) > 1-partial-cone ~ 2i-partial-cone > 2-partial-cone ~ 1,3-alternate > 3i-partial-cone. However, the relative stability of the conformational complexes of 6 with $K^+$ is in the following order: 2-partial cone ~ 1,3-alternate > cone > 3-partial cone > 1-partial cone (least stable). The highest binding strengths of 2-partial-cone and 1,3-alternate complexes originate from two strong cation-$\pi$ interactions and two strong cation-oxygen interactions in the complex of 6+$K^+$. Due to the cation-$\pi$ interactions, the calculated C-C bond distances in the arenes of the $K^+$-complexes are about 0.0048 $\AA$ longer than the values of their isolated hosts.

• Journal of the Korea Concrete Institute
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• v.14 no.4
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• pp.608-614
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• 2002

The effects of slag content and polymer-binder ratio on the strength properties of autoclaved SBR-modified concretes using ground granulated blast-furnace slag(slag) and a styrene-butadiene rubber (SBR) latex are examined. As a result, the compressive and tensile strengths of the autoclaved SBR-modified concretes using slag increase with increasing slag content, and reach a maximum at a slag content 40％, and increase with increasing polymer-binder ratio. In particular, the autoclaved SBR-modified concretes with a slag content of 40％ provide about three times higher tensile strength than unmodified concretes. Such high strength development is attributed to the high tensile strength of SBR polymer and the improved bond between cement hydrates and aggregates because of the addition of SBR latex.

• Journal of the korean academy of Pediatric Dentistry
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• v.24 no.4
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• pp.805-812
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• 1997

Despite dentistry's attempts to improve the dental health of the public and to minimize the effects of caries, many children still present with extensive destruction of primary anterior teeth. One of dentistry's most challenging tasks is to repair these teeth with restoration which are durable, retentive, and esthetic. Esthetic restoration can often be achieved with polycarbonate crowns, strip crowns, conventional S-S crowns, open-faced S-S crowns, commercially veneered S-S crowns. But, all of these have limitation. Advances in restorative materials and metal-bonding procedures have made possible new restorative techniques that combine the advantages of S-S crowns with the cosmetics of composite restoration methods. The described technique of bonding composite to trimmed and fitted S-S crowns offers many advantages over other techniques currently used to restore primary anterior teeth. 1. If S-S crowns are accurate trimmed and contoured, good retention of crowns is achieved. 2. The patient time required is similar to that of conventional S-S crowns. 3. Good esthetics and high bond strengths are achieved. 4. It is possible to use this veneering technique intraorally on crowns that have fractured veneers.

• Structural Engineering and Mechanics
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• v.85 no.3
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• pp.337-351
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• 2023

In this paper, the shear behavior of soft filling in rectangular-hollow concrete specimens was simulated using the 2D particle flow code (PFC2D). The laboratory-measured properties were used to calibrate some PFC2D micro-properties for modeling the behavior of geo-materials. The dimensions of prepared and modeled samples were 100 mm×100 mm. Some disc type narrow bands were removed from the central part of the model and different lengths of bridge areas (i.e., the distance between internal tips of two joints) with lengths of 30 mm, 50 mm, and 70 mm were produced. Then, the middle of the rectangular hollow was filled with cement material. Three filling sizes with dimensions of 5 mm×5 mm, 10 mm×5 mm, and 15 mm×5 mm were provided for different modeled samples. The parallel bond model was used to calibrate and re-produce these modeled specimens. Therefore, totally, 9 different types of samples were designed for the shear tests in PFC2D. The shear load was gradually applied to the model under a constant loading condition of 3 MPa (σc/3). The loading was continued till shear failure occur in the modeled concrete specimens. It has been shown that both tensile and shear cracks may occur in the fillings. The shear cracks mainly initiated from the crack (joint) tips and coalesced with another one. The shear displacements and shear strengths were both increased as the filling dimensions increased (for the case of a bridge area with a particular fixed length).

• Advances in concrete construction
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• v.15 no.6
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• pp.359-376
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• 2023

Ultra-high-performance concrete (UHPC) has become an attractive cast-in-place repairing material for existing engineering structures. The present study aims to investigate age-dependent high-early-strength UHPC (HESUHPC) material properties (i.e., compressive strength, elastic modulus, flexural strength, and tensile strength) as well as interfacial shear properties of HESUHPC-normal strength concrete (NSC) composites cured at different season temperatures (i.e., summer, autumn, and winter). The typical temperatures were kept for at least seven days in different seasons from weather forecasting to guarantee an approximately consistent curing and testing condition (i.e., temperature and relative humidity) for specimens at different ages. The HESUHPC material properties are tested through standardized testing methods, and the interfacial bond performance is tested through a bi-surface shear testing method. The test results quantify the positive development of HESUHPC material properties at the early age, and the increasing amplitude decreases from summer to winter. Three-day mechanical properties in winter (with the lowest curing temperature) still gain more than 60% of the 28-day mechanical properties, and the impact of season temperatures becomes small at the later age. The HESUHPC shrinkage mainly occurs at the early age, and the final shrinkage value is not significant. The HESUHPC-NSC interface exhibits sound shear performance, the interface in most specimens does not fail, and most interfacial shear strengths are higher than the NSC-NSC composite. The HESUHPC-NSC composites at the shear failure do not exhibit a large relative slip and present a significant brittleness at the failure. The typical failures are characterized by thin-layer NSC debonding near the interface, and NSC pure shear failure. Two load-slip development patterns, and two types of main crack location are identified for the HESUHPC-NSC composites tested in different ages and seasons. In addition, shear capacity of the HESUHPC-NSC composite develops rapidly at the early age, and the increasing amplitude decreases as the season temperature decreases. This study will promote the HESUHPC application in practical engineering as a cast-in-place repairing material subjected to different natural environments.