• Title/Summary/Keyword: Bond order

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Characteristics of Welded Zone Using Solar Energy Concentration (태양광선을 이용한 용접부 특성)

  • Prasad, K.D.V.;Kim, I.S.;Sung, B.S.;Kim, B.C.
    • Journal of the Korean Solar Energy Society
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    • v.21 no.2
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    • pp.9-17
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    • 2001
  • In this paper the attempts made by the authors to explore the feasibility of utilising concentrated solar beam radiation for joining engineering thermoplastics such as Acrylonitrilc/Butadiene/Styrene (ABS), Polycarbonate(PC) and Polymethylmethacrylate(PMMA) are presented. In addition, to study the joining of the materials, necessary experimentation with applying primer was performed. Tensile tests were conducted to determine the bond strength achieved at the specimen joint interface. Microscopic examinations of the fractured joints were performed in order to analyse the overall bond quality. Finally, the results in terms of bond strength achieved at the joint interface and energy consumed in the process were compared with those obtained with similar thermoplastic joining technique utilising microwave energy. In conclusion some advantages and limitations were outlined and necessary improvements of the jointing technique were recommended.

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Effect of Bar Position on the Bond Characteristics of Deformed Bars in Recycled Aggregate Concrete (철근위치에 따른 순환골재 콘크리트와 이형철근의 부착특성)

  • Jang, Yong-Heon;Kim, Sun-Woo;Yun, Hyun-Do;Choi, Ki-Sun;You, Young-Chan;Kim, Keung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.71-72
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    • 2009
  • For practical application of recycled aggregate concrete, it is very important to study bond behavior of reinforcing bars in recycled aggregate concrete. Pull-out test was performed in order to investigate the bond behavior between recycled aggregate concrete and deformed bars.

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A Study on the Effect of the Thickness of Bond Coating on the Thermal Stresses of a Sprayed Thermal Barrier Coating (접착층의 두께가 용사 열차폐 코팅의 열응력에 미치는 영향에 관한 연구)

  • 김형남
    • Journal of Welding and Joining
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    • v.19 no.2
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    • pp.221-227
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    • 2001
  • Based on the principle of complementary energy, an analytical method is developed which focuses on the end effects for determining thermal stress distributions in a three-layered beam. This method gives the stress distributions which completely satisfy the stress-free boundary conditions. A numerical example is given in order to verify this method. The results show that the present analytical solutions have the values of stress in excellent agreement with the solutions derived by other investigators. Using this method, the effects of the thickness of bond coat on the thermal stresses of a typical sprayed thermal barrier coating, which consists of IN738LC substrate, MCrAIY bond coat and ZrO$_2$-8wt%Y$_2$O$_3$top coat, were investigated.

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Inhibitory Effect of Silkworm Urine on the Rat Intestinal Glycosidase (잠뇨의 흰쥐 소장내 glycosidase 저해활성)

  • 송주경;정성현
    • Biomolecules & Therapeutics
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    • v.6 no.3
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    • pp.242-246
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    • 1998
  • The inhibitory activities of Amberlite active fraction, which was obtained from methanol soluble fraction of freeze dried slikworm urine, on the rat intestinal glycosidase-catalyzed enzymatic reaction were examined in in viro and in vivo experiments. Amberlite active fraction showed significant inhibitory effects on the hydrolysis of o-glycosidic bond, especially $\alpha$-1,4 bond. On the other hand, the inhibition on the hydrolysis of $\beta$-glycosidic bond was very weak. Oral administration of Amberlite active fraction resulted in a dose-dependent decrease in the blood glucose after an oral maltose load, and postprandial hyperglycemia in carbohydrate-loaded mice was suppressed by Amberlite active fraction at 60 mgHg in decreasing order of maltose, starch, sucrose and lactose. 60 mg/kg of Amberlite active fraction lowered the blood glucose level markedly after 18, 35, and 60 min after an oral maltose load and the antihyperglycemic activity was maintained upto 90 min. In alloxan-induced hyperglycemic mice, Amberlite active fraction at a dose of 100 mg/kg also significantly lowered blood glucose after an oral maltose load, and its efficacy was almost equivalent to that of acarbowe.

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Necleophilic Substitution Reaction of Dansyl, Bansyl, Dabsyl Chloride (Dansyl, Bansyl, Dsbsyl Chloride의 친핵성 치환반응)

  • 김문식;채기수
    • The Korean Journal of Food And Nutrition
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    • v.5 no.1
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    • pp.23-32
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    • 1992
  • Kinetic studies of nucleophilic substitution reactions of dansyl, bansyl, dabsyl chlorides with pyridines have been investigated at $0^{\circ}C$ in a range of methanol-acetonitrile binary solvent mixtures. The order of magnitude for reactivity of substrates with pyridines in the same reaction condition is dabsyl chloride>dansyl chloride> bansyl chloride. The value of $\rho$n(-2.29~ -4.66) and $\beta$(0.537~0.901) associated with a change substituent in the nucleophile are large and indicate a relatively advanced bond formation in the transition state. Solvatochromic correlations were predicted the increase of bond formation transition state according to the increasing MeCN contents, showing the greater contribution of polarity polarizability ($\pi$*) than hydro-gen bond donar acidity($\alpha$). We conclude that the reactions of dansyl, bansyl, dabsyl chlorides with pyridines proceed via associative Sn2 type reaction mechanism.

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A Study on the Bond Strength of Coated Rebar in Concrete (콘크리트중 코팅철근의 부착응력에 대한 기초적 연구)

  • 문한영;김성수;류재석;김성섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.10a
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    • pp.127-132
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    • 1996
  • Recently in the country a corrosion of steel is accelerated due to using of sea sand including salts, and critical problem on the durability of concrete structure is occured. Thus a control of steel corrosion is very important in the stability of structure. Coated steel is in use with a method of steps of steel corrosion in U.S,A. Japan etc, and as well in domestic case the manufactured coating steel of three types is on the market. Those are Epoxy coated steel, Zinc-strength, concrete specimen size, bar diameter, which can affect bond characteristics between steel and concrete in order to know their relative bond characteristics.

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Bond capacity with absorption of recycled coarse aggregate in RC beams (순환 굵은 골재 흡수율에 따른 RC보의 부착 성능에 대한 실험적 연구)

  • Lee, Hyun-Ah;Lim, Ji-Youg;Lee, Jung-Mi;Park, Cho-Bum;Ryu, Deck-Huyn;Kim, Kil-Hee
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.97-100
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    • 2008
  • In order to recycled wast concrete which is occurred from demolition of the old building, it is effective that the recycled aggregate used as structural concrete aggregate. For used recycled aggregate with structural concrete, the structural capacity must be confirmed. This Study investigated bond capacity which follows in difference of absorption of the aggregate between rebar and concrete. Test results show that there are not a difference of bond strength and slip behavior according to absorption ratio of natural and recycled coarse aggregate.

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Structures of Two-dimensional Ring Polymer Solutions using Bond Fluctuation Model

  • Shin, Donghan;Lee, Eunsang;Jung, YounJoon
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.155-162
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    • 2016
  • This study attempts to reveal structures of two-dimensional ring polymer solutions in various polymer concentrations ranging from dilute to concentrated regime. Polymer sizes, single molecule structure factors, bond correlation functions and monomer density distribution functions from center of mass are given in order to clarify the polymer structures. Our study shows that a ring in dilute solution maintain pseudo-circular structure with self-avoiding walk (SAW) statistics, and it seems to be composed of two connecting SAW linear chains. In semidilute solutions, ring polymers are not entangled with each other and adopt collapsed configurations. Such assumption of collapsed structures in the semidilute regime gives an overlap concentration of ${\varphi}^*{\sim}N^{-1/2}$ where N is degree of polymerization. By normalizing the polymer concentration by these overlap concentration, we find universal behaviors of polymer sizes and structure factors regardless of N.

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Comparison of Structural Types of L-Alanine Pentamer by Quantum Chemical Calculation

  • Kobayashi, Minoru;Sim, Jae Ho
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.425-430
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    • 2022
  • L-alanine (LA, as an amino acid residue) pentamer model was used to investigate changes in the dihedral angle, intramolecular hydrogen bonding and formation energies during structural optimization. LA pentamers having four conformation types [𝛽: 𝜑/𝜓=t-/t+, 𝛼: 𝜑/𝜓=g-/g-, PPII: 𝜑/𝜓=g-/t+ and P-like: 𝜑/𝜓= g-/g+] were carried out by quantum chemical calculations (QCC) [B3LYP/6-31G(d,p)]. In LA, 𝛽, 𝛼, and P-like types did not change by optimization, having an intra-molecular hydrogen bond: NH⋯OC (H-bond), and PPII types in the absence of H-bond were transformed into P-like at the designated 𝜓 of 140°, and to 𝛽 at that of 160° or 175°. P-like and 𝛼 were about 0.5 kcal/mol/mu more stable than 𝛽. In order to understand the processes of the transformations, the changes of 𝜑/𝜓, distances of NH-OC (dNH/CO) and formation energies (𝜟E, kcal/mol/mu) were examined.

Development of Solar Energy Concentration for Plastic Joining

  • Yarlagadda, P.;Kim, I.S.
    • International Journal of Korean Welding Society
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    • v.2 no.1
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    • pp.57-61
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    • 2002
  • This paper presents development of a SEC(Solar Energy Concentration) utilizing the concentrated solar beam radiation for joining engineering thermoplastics such as Acrylonitrile/Butadiene/Styrene(ABS), Polycarbonate(PC) and Polymethylmethacrylate (PMMA). In addition, to study the joining of the materials, necessary experimentation with applying primer was performed. Tensile tests were conducted to determine the bond strength achieved at the specimen Joint interface. Microscopic examinations of the fractured joints were performed in order to analyze the overall bond quality. Finally, the results in terms of bond strength achieved at the joint interface and energy consumed in the process was compared with those obtained with similar thermoplastic joining technique utilizing microwave energy.

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