• Bulletin of the Korean Chemical Society
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• v.22 no.3
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• pp.261-262
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• 2001

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.293-293
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• 2006

Self-assembled nanostructures of block copolymer thin films have gathered significant attention due to their potential applications as templates for nanofabrication. However the lack of a robust strategy to control the structure formation in thin film geometries has been considered a major obstacle for the practical application. In this presentation 'epitaxial self-assembly' will be introduced as a successful strategy to control the self-assembled nanostructure of block copolymer. Chemically patterned surfaces prepared by advanced lithographic techniques successfully registered nanodomains in block copolymer thin film without any single defect over an arbitrarily large area.

• Journal of the Korean Applied Science and Technology
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• v.18 no.2
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• pp.118-126
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• 2001

Micelle formation and adsorption at the $Ti0_{2}$ interface of a series of polystyrene-polythylene oxide(PS-PEO) block copolymer in aqueous solution was studied using fluorescence probing and small-angle X-ray methods. Further, the stability of aqueous $Ti0_{2}$ dispersion in the presence of copolymer was investigated by microelectrophoresis, optical density and sedimentation measurements. The dissolution of pyrene as fluorescent probe in aqueous surfactant solution leads to a slow decrease of the $I_{1}/I_{3}$ ratio, as the copolymer concentration increase; $I_{1}$ and $I_{3}$ are respectively the intensities of the first and third vibrionic peaks in the pyrene fluorescence emission. The behaviour was due to the characteristics of the copolymers and/or to the copolymer association efficiency in water. Moreover, the adsorption at the plateau level increases with decreasing PEO until chain length. The zeta potential of $TiO_{2}$ particles decreases with increasing copolymer concentration and reaches a plateau value. Finally, stabilization using block copolymers was more effective with samples having higher weight fractions of PS block.

• Journal of Biomedical Engineering Research
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• v.8 no.2
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• pp.199-204
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• 1987

ABA type block copolymers composed of r benzyle L-glutamate as the A component and poly(ethylene glycol) as the B components were obtained. Platelet adhesion on their sunfaces was investigated by a column elusion method to examine the effects of microdomain and secondary structure. The number of platelets adhered from whole blood and plasma rich platelet was smaller for the block copolymer systems than for the homopolymers. In the block copolymer system, the number of platelets adrered on their surfaces increased with increasing the content of PEG, that is, with decreasing of a-helix of block copolymers. A thick thrombus formation on the PBLG homopolymer was observed than block copolymer by scanning electron micrographs. The platelets adhesion increased with increasing the critical surface tension of the block copolymer.

• Land and Housing Review
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• v.11 no.3
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• pp.1-9
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• 2020

This study fulfills an empirical analysis how the physical factors affect the formation of housing price with the block unit. Block unit houses are a type of housing that pursues comfort and convenience in that the characteristics of individual houses and apartment houses are mixed. Existing studies have focused only on the physical characteristics of various planning elements such as block-type residential complexes. Nevertheless, it is not known whether the physical characteristics of block-type residential complexes reflect the preferences of actual consumers. In addition, there are no sufficient studies on how to evaluate them from the market side. In this study, block-level detached housing sites the target complexes with 10 or more households built between 2002 and 2019. The target areas for analysis are 163 complexes in Paju, Namyangju, Goyang, Suwon, Yongin, Ansan, Gimpo, Incheon, Seongnam, Hwaseong and Gwangju, Gyeonggi-do. The physical elements that make up the unit housing were classified through factor analysis. Finally, regression analysis was conducted to establish the basis determining the price-forming factors. As a result of the analysis, the factors that influenced the price were the site area and the number of community facilities. The variable with negative influence was the distance from Seoul. Based on the results of this study, it can be said that the influence on price formation in various areas was confirmed by presenting the relationship between the facility composition and price of a detached house.

• Journal of Korean Institute of Industrial Engineers
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• v.17 no.1
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• pp.75-82
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• 1991

This research is concerned with Machine-Part Group Formation(MPGF) methodology for Flexible Manufacturing Systems(FMS). The purpose of the research is to develop a new heuristic algorithm for effectively solving MPGF problem. The new algorithm is proposed and evaluated by 100 machine-part incidence matrices generated. The performance measures are (1) grouping ability of mutually exclusive block-diagonal form. (2) number of unit group and exceptional elements, and (3) grouping time. The new heuristic algorithm has the following characteristics to effectively conduct MPGF : (a) The mathematical model is presented for rapid forming the proper number of unit groups and grouping mutually exclusive block-diagonal form, (b) The simple and effective mathematical analysis method of Rank Order Clustering(ROC) algorithm is applied to minimize intra-group journeys in each group and exceptional elements in the whole group. The results are compared with those from Expert System(ES) algorithm and ROC algorithm. The results show that the new algorithm always gives the group of mutually exclusive block-diagonal form and better results(85%) than ES algorithm and ROC algorithm.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.85-85
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• 2006

The micellization behavior and the metal-nanoparticle formation in PDEAEMA-b-PHEGMA double hydrophilic block copolymers are investigated. The hydrophobic PDEAEMA block is pH-sensitive: at low pH it can be protonated and it becomes hydrophilic, leading to molecular solubility, whereas at higher pH micelles are formed; the behavior is studied by DLS, NMR and AFM. In these micellar nanoreactors, metal nanorystals nucleate and grow upon reduction with sizes in the range of a few nm's as observed by TEM and XRD. Similarly, metal nanocrystals can be formed within pH-sensitive microgels (${\sim}250nm$ in diameter), synthesized by emulsion copolymerization of DEAEMA, which also exhibit reversible swelling properties in water by adjusting the pH.

• Bulletin of the Korean Chemical Society
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• v.21 no.4
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• pp.383-388
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• 2000

Multiblock copolymers consisting of poly( g-benzyl L-glutamate) (PBLG) as the hydrophobic part and poly(ethylene oxide) (PEO) as the hydrophilic part (GEG) were synthesized and characterized. GEG polymeric micelles were prepared by the dialysis technique. Particle size distributions based on intensity,volume, and number-average were 22.6 $\pm$ 11.9 nm, 23.5 $\pm$ 4.6 nm, and 23.7 $\pm$ 37 nm, respectively. It was observed that par-ticle size and size distribution of GEG polymeric micelles changed significantly with the choice of initial sol-vent. Transmission electron micrographs (TEM) showed the polymeric micelles to be spherically shaped, with sizes ranging from 20 nm to 40 nm in diameter. Fluorescence spectroscopy measurements suggested that GEG block copolymers wereassociated in water to form polymeric micelles, and the critical micelle concentrations (CMC) value of the block copolymers was 0.0094 g/L. Further evidenceof micelle formation of GEG block copolymers and limited mobility of the PBLG chain in the core ohe micelle was obtained with 1 H NMR in D2O.

• Economic and Environmental Geology
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• v.26 no.3
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• pp.383-393
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• 1993

Paleomagnetic data have been obtained from the Lower Triassic Tonggo formation which is exposed in the E-W trending Baekunsan syncline comprising the Pyongan Supergroup in eastern Korea. Two ancient components of magnetization are recovered in this formation by detailed thermal demagnetization: a post-folding component and a pre-folding component The post-folding component ($D/I=58.8/55.5^{\circ}$) is normally magnetized and appears to acquire in the Cretaceous Normal Superchron. It is a magnetic signature of the Daebo Orogeny and has been rotated clockwise since this magnetization has been acquired, in common with the main synclinal axis. The pre-folding component ($D/I=1.1/19.4^{\circ}$, Paleopole at $306.1^{\circ}E$, $63.2^{\circ}N$) passes fold and reversal tests and is inferred to be a post-depositional or early chemical diagenetic remanence of Lower-Middle Triassic age. This paleopole corresponds only with the Lower Triassic poles from the North China Block: it is removed from the contemporary poles from the South China Block. If the result of this study is corrected for the clockwise rotation deduced from the Cretaceous overprint, the enhanced agreement with the Lower Triassic poles from the North China block can be achieved. Therefore, a first order correlation between the Korean Peninsula and North China at least since Lower Triassic times is identified in this study.

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.291-292
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• 2003

Amphiphilic block copolymer는 self-assembly특성을 가지고 있기 때문에 선택된 용매 속에서 nanoscale-domain 즉 micelle을 형성할 수 있다. 이러한 특성은 기타 불용성 물질을 가용화하고 colloidal particle을 안정화시키거나 micro-emulsion을 형성할 수 있어 pharmaceutics, drug delivery system등 영역, 그리고 emulsion stabilizer, thickener, dispersion agent등으로 사용될 수 있다. (중략)