• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.153-153
• /
• 2016

Polyoxymethylene copolymer (POM-C) is an attractive and widely used engineering thermoplastic across many industrial sectors owing to outstanding physical, mechanical, self-lubricating and chemical properties. In this research work, the POM-C blocks were irradiated with 1 MeV electron beam energy in five doses (100, 200, 300, 500 and 700 KGy) in vacuum condition at room temperature. The tribological and physico-chemical properties of electron beam irradiated POM-C blocks have been analyzed using Pin on disk tribometer, Raman spectroscopy, SEM-EDS, Optical microscopy, 3D Nano surface profiler system and Contact angle analyzer. Electron beam irradiation at a dose of 100 kGy resulted in a decrease of the friction coefficient and wear loss of POM-C block due to well suited cross-linking, carbonization, free radicals formation and energetic electrons-atoms collisions (physical interaction). It also shows lowest surface roughness and highest water contact angle among all unirradiated and irradiated POM-C blocks. The irradiation doses at 200, 300, 500 and 700 kGy resulted in increase of the friction coefficient as compared to unirradiated POM-C block due to severe chain scission, chemical and physical structural degradation. The electron beam irradiation transferred the wear of unirradiated POM-C block from the abrasive wear, adhesive wear and scraping to mild scraping for the 1 MeV, 100 kGy irradiated POM-C block which is concluded from SEM-EDS and Optical microscopic observations. The degree of improvement for tribological attribute relies on the electron beam irradiation condition (energy and dose rate).

• Macromolecular Research
• /
• v.15 no.7
• /
• pp.688-692
• /
• 2007

The hydrogen-bonding induced alternating multilayer thin films of dendrimers and block copolymer micelles were demonstrated. The block copolymer micelles derived from amphiphilic poly(2-ethyl-2-oxazoline)block-$poly({\varepsilon}-carprolactone)$ (PEtOz-PCL) in aqueous phase have a core-shell structure with a mean hydrodynamic diameter of 26 nm. The hydrogen bonding between the PEtOz outer shell of micelle and the carboxyl unit of poly(amidoamine) dendrimer of generation 4.5 (PAMAM-4.5G) at pH 3 was utilized as a driving force for the layerby-layer alternating deposition. The multilayer thin film was fabricated on the poly(methyl methacrylate) (PMMA) thin film spin-coated on silicon wafer or glass substrate by the alternate dipping of PEtOz-PCL micelles and PAMAM dendrimers in aqueous solution at pH 3. The formation of multilayer thin film was characterized by using ellipsometry, UV-vis spectroscopy, and atomic force microscopy. The PEtOz outer shell of PEtOz-PCL micelle provided the pH-responsive hydrogen bonding sites with peripheral carboxylic acids of PAM AM dendrimer. The multilayer thin film was reversibly removed after dipping in aqueous solution at $pH{\geq}5.6$ due to dissociation of the hydrogen bonding between PEtOz shell of PEtOz-PCL micelle and peripheral carboxyl units of PAMAM dendrimer.

• Journal of The Geomorphological Association of Korea
• /
• v.27 no.2
• /
• pp.1-17
• /
• 2020

This study evaluated a debris landform distribution potential area map in the southwest region of the Korean peninsula. A GIS spatial integration technique and logistic regression method were used to produce a distribution potential area map. Seven topographic and environmental factors were considered for analysis and 28 different data set were combined and used to get most effective results. Moreover, in an accuracy assessment, the extracted results of the Distribution Potential area were evaluated by conducting a cross-validation module. Block stream showed the highest accuracy in the combination No. 6, and that DEM (digital elevation model) and TWI (topographic wetness index) have relatively high influences on the production of the Block stream Distribution Potential area map. Talus showed the highest accuracy in the combination No. 13. We also found that slope, TWI and geology have relatively high influences on the production of the Talus Distribution Potential area map. In addition, fieldwork confirmed the accuracy of the input data that were used in this study, and the slope and geology were also similar. It was also determined that these input data were relatively accurate. In the case of angularity, the block stream was composed of sub-rounded and sub-angular systems and Talus showed differences according to the terrain formation. Although the results of the rebound strain measurement using a Schmidt's hammer did not shown any difference in topographic conditions, it is determined that the rebound strain results reflected the underlying geological setting.

• Journal of Microbiology and Biotechnology
• /
• v.22 no.3
• /
• pp.385-389
• /
• 2012

The application of microorganisms in the field of construction material is rapidly increasing worldwide; however, almost all studies that were investigated were bacterial sources with mineral-producing activity and not with organic substances. The difference in the efficiency of using bacteria as an organic agent is that it could improve the durability of cement material. This study aimed to assess the use of biofilm-forming microorganisms as binding agents to increase the compressive strength of cement-sand material. We isolated 13 alkaliphilic biofilmforming bacteria (ABB) from a cement tetrapod block in the West Sea, Korea. Using 16S RNA sequence analysis, the ABB were partially identified as Bacillus algicola KNUC501 and Exiguobacterium marinum KNUC513. KNUC513 was selected for further study following analysis of pH and biofilm formation. Cement-sand mortar cubes containing KNUC513 exhibited greater compressive strength than mineral-forming bacteria (Sporosarcina pasteurii and Arthrobacter crystallopoietes KNUC403). To determine the biofilm effect, Dnase I was used to suppress the biofilm formation of KNUC513. Field emission scanning electron microscopy image revealed the direct involvement of organic-inorganic substance in cement-sand mortar.

• Journal of the Korean Magnetics Society
• /
• v.5 no.4
• /
• pp.275-280
• /
• 1995

The sites for $Fe^{+3}$ are partly substituted by $Co^{+2}$ and $Ti^{+4}$ cations to control coercivity of Ba-ferrite particles for use in high density magnetic recording. The substituted $Co^{+2}$ cation has very much different effects on magnetic properties and particle characteristics from that $Ti^{+4}$ cation has. The decrease in the coercivity with the $Co^{+2}$ substitution is attributed to the formation of excessive spinel-block(S-block) in pure Ba-ferrite crystal, while saturation magnetization is increased and the distributions of coercivity and particle size become broad. The substitution with the $Ti^{+4}$ decreases the sauration magnetization, but has less effect on a change in coercivity than the $Co^{+2}$. The $Ti^{+4}$ acts as a nucleation agent in amorphous phase of formulated compound, and consequently particle size and aspect ratio are decreased. Furthermore, the enhancement of substitution of the $Co^{+2}$ for the $Fe^{+3}$ sites in rhombohedral-block(R-block) by the $Ti^{+4}$ retards the nucleation of spinel phase of Ba-ferrite, which results in uniform magnetic properties of Ba-ferrite particles. It is suggested that the contents of the cations to be substituted for the $Fe^{+3}$ sites are optimized on the bases of magnetic properties and particle characteristics rather than on the base of electrical charge balance.

• Economic and Environmental Geology
• /
• v.52 no.5
• /
• pp.347-356
• /
• 2019

Various studies regarding the sedimentary environment, depositional age, provenance, and metamorphic history have been carried out on the Taean Formation in the western part of Gyeonggi Massif, since the unique detrital zircon age pattern was revealed. This review paper introduces the previous researches on the Taean Formation and discusses the depositional age and provenance. The Taean Formation was traditionally regarded as a Precambrian stratigraphic unit, but recently it is interpreted to be a middle or upper Paleozoic formation due to the occurrence of large amounts of Early to Middle Paleozoic detrital zircons. The Taean Formation consists of metasandstone, argillaceous schist, and phyllite which are mainly made up of quartz and mica. The protoliths are interpreted as turbidites deposited in deep sea fan environment. The Taean Formation has been interpreted to be deposited between the Devonian to Triassic ages given the age differences between detrital zircons and intrusive rocks. There are two opinions that the deposition age is close to the Devonian or the Permian period. The provenance of this formation is supposed to be South China block, Chinese collisional belt, or Gyeonggi Massif. Given the available detrital zircon ages of the Taean Formation and other Korean (meta)sedimentary rocks, the Taean Formation shares major source rocks with Yeoncheon Group and Pibanryeong Unit of the Okcheon Supergroup, but their source regions are not entirely consistent. Considering the existing hypotheses about the depositional timing and provenance, we put weight on the possibility that the Taean Formation was deposited between Permian and Early Triassic periods. However, further studies on the stratigraphy and sedimentary petrology are needed to clarify its definition and to elucidate the provenance.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
• /
• 2004.05a
• /
• pp.96-100
• /
• 2004

In the ship building industry various problems of erection is counterfeited due to formation of bottle necks in the block erection flow pattern This kind of problems cause accumulated problems in real-time erection right on the floor, When such a problem is approached, a support data of the entire erection sequence should be available, Here planning is done by reasoning about the future events in order to verify the existence of a reasonable series of actions to accomplish a goal. This technique helps in achieving benefits like handling search complications, in resolving goal conflicts and anticipation of bottleneck formation well in advance to take necessary countermeasures and boosts the decision support system, The data is being evaluated and an anticipatory function is to be developed This function is quite relevant in day to day planning operation. The system updates database with rearrangement of off-critical blocks in the erection sequence diagram, As a result of such a system, planners can foresee months ahead and can effectively make decisions regarding the control of loads on the man, machine and work flow pattern, culminating to an efficient load management. Such a foreseeing concept helps us in eliminating backtracking related adjustment which is less efficient compared to the look-ahead concept. An attempt is made to develop a computer program to update the database of block arrangement pattern based on heuristic formulation.

• Journal of the Korean association of regional geographers
• /
• v.15 no.2
• /
• pp.204-214
• /
• 2009

The purpose of this paper is to elucidate the formation processes of Hwaeumneup in Cheonseong Mountain which was designated as Wetland Conservation Area in 2002, and to offer data essential to sustainable management of wetland. According to wetland core samples and carbon dating of humus, grassland of Hwaeumneup Wetland Reservation resulted from slash-and-burn agriculture in no reference with climatic changes of last glacial period. And Hwaeumneup is a alpine wetland that is formed as rain water over Cheonseong Mountain crest area infiltrates into bedrock, springs out along joint line below main ridge, and dampens gentle grassland. It needs to support dense vegetation of southwestern ridge of Wetland Reservation in order to sustain water volumn of Hwaeumneup wetland, and to keep from breakdown of block dam at downstream fringe of wetland. And it needs to measure and analyse micro-topography and hydrology changes in Hwaeumneup Wetland Reservation through periodic monitoring.

• Elastomers and Composites
• /
• v.56 no.3
• /
• pp.179-186
• /
• 2021

Carbon-based nanofillers, including nanodiamond (ND) and carbon nanotubes (CNTs), have been employed in epoxy matrixes for improving the toughness, using the tow prepreg method, of epoxy compounds for high pressure tanks. The reinforcing performance was compared with those of commercially available toughening fillers, including carboxyl-terminated butadiene acrylonitrile (CTBN) and block copolymers, such as poly(methyl methacrylate)-b-poly(butyl acrylate)-b-poly(methyl methacrylate) (BA-b-MMA). CTNB improved the mechanical performance at a relatively high filler loading of ~5 phr. Nanosized BA-b-MMA showed improved performance at a lower filler loading of ~2 phr. However, the mechanical properties deteriorated at a higher loading of ~5 phr because of the formation of larger aggregates. ND showed no significant improvement in mechanical properties because of aggregate formation. In contrast, surface-treated ND with epoxidized hydroxyl-terminated polybutadiene considerably improved the mechanical properties, notably the impact strength, because of more uniform dispersion of particles in the epoxy matrix. CNTs noticeably improved the flexural strength and impact strength at a filler loading of 0.5 phr. However, the improvements were lost with further addition of fillers because of CNT aggregation.

• Tunnel and Underground Space
• /
• v.29 no.5
• /
• pp.332-345
• /
• 2019

Maximum dip vector of individual joint plane, which can be uniquely defined on the hemispherical projection plane, has been established by considering its dip and dip direction. A new stereographic projection method for the rock slope analysis which employs the maximum dip vector can intuitively predict the failure modes of rock slope. Since the maximum dip vector is uniquely projected on the maximum dip point of the great circle, the sliding direction of discontinuity plane can be recognized directly. By utilizing the maximum dip vector of discontinuity both the plane sliding and toppling directions of corresponding blocks can be discerned intuitively. Especially, by allocating the area of high dip maximum dip vector which can form the flanks of sliding block the potentiality for the formation of virtual sliding block has been estimated. Also, the potentiality of forming the triangular-sectioned sliding block has been determined by considering the dip angle of joint plane the dip direction of which is nearly opposite to that of the slope face. Safety factors of the different-shaped blocks of triangular section has been estimated and compared to the safety factor of the most hazardous block of rectangular section. For the wedge analysis the direction of crossline of two intersecting joint planes, which has same attribute of the maximum dip vector, is used so that wedge failures zone can be superimposed on the stereographic projection surface in which plane and toppling failure areas are already lineated. In addition the maximum dip vector zone of wedge top face has been delineated to extract the wedge top face-forming joint planes the orientation of which provides the vital information for the analysis of mechanical behavior of wedge block.