• 한국주거학회:학술대회논문집
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• 한국주거학회 2005년도 추계학술대회 논문집
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• pp.229-234
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• 2005

The purpose of this study is to analyze a Characteristics of block formation and commercialization of residential books commercial area along urban arteries on Teheran-ro in Seoul. 'Teheran-ro' is selected as a case site to analyze the characteristics of residential blocks commercial area along urban arteries. The study analyzes the characteristics of the street network and block formation in commercial area along arteries and rear residential blocks, and commercialization of residential blocks commercial area along urban arteries according to the characteristics of street network and block formation. The analysis about block formation progress about i ) a street network and block formation, ii ) the scale of blocks, iii) division of lots, iv) lots system. The analysis about commercialization of residential blocks commercial area progress about i) a street network and block formation, ii) a density of building, iii) a use of building

• Journal of Periodontal and Implant Science
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• 제38권sup2호
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• pp.325-334
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• 2008

Purpose: The carrier used as delivery agent for bone morphogenetic proteins(BMPs) should also act as a scaffold for new bone formation. Moreover, bone formation should be predictable in terms of the volume and shape. This study examined the osteogenic effect of macroporous biphasic calcium phosphate (MBCP) block combined with ePTFE membrane as a carrier for recombinant human bone morphogenetic proteins (rhBMP-2). In addition, the additive effect of ePTFE membrane on bone formation was evaluated. Materials and Methods: Eight-millimeter critical sized calvarial defects were created surgically in 28 male Sprague-Dawley rats. The animals were divided into 2 groups containing 14 animals each. The defects were treated with either rhBMP-2/MBCP block (rhBMP-2/MBCP group) or rhBMP-2/MBCP block/ePTFE membrane (rhBMP-2/MBCP/ePTFE group). A disc-shaped MBCP block (3 mm height and 8 mm diameter) was used as the carrier for the rhBMP-2 and ePTFE membrane was used to cover the rhBMP-2/MBCP block. The histologic and histometric parameters were used to evaluate the defects after 2- or 8-week healing period (7 animals/group/healing interval). Results: The level of bone formation in the defects of both groups was significantly higher at 8 weeks than that at 2 weeks (P < 0.05). The ePTFE membrane has no additional effect compared with the rhBMP-2/MBCP block only. However, at 8 weeks, rhBMP-2/MBCP/ePTFE group showed more even bone formation on the top of the MBCP block than the rhBMP-2/MBCP group. Conclusion: These results suggest that the ePTFE membrane has no additive effect on bone formation when a MBCP block is used as a carrier for rhBMP-2.

• 폴리머
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• 제24권6호
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• pp.854-859
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• 2000

N,N-dimethylamino ethyl methacrylate(DMAEMA)와 poly(ethylene glycol) (PEG)로 이루어진 블록 공중합체를 합성하였고, 그 구조를 FT-IR, DSC, 및 $^1$H-NMR로 확인하였다. 준비된 poly(DMAEMA))-PEG 블록 공중합체 수용액에 poly(ethyl acrylamide)(PEAAm)를 첨가하면 블록 공중합체의 DMAEMA와 poly(EAAm) 사이에서 일어나는 수소결합에 의해 나노복합체가 형성되었다. 나노복합체는 임계미셀농도 이상의 농도에서 이루어졌다.

• Journal of Periodontal and Implant Science
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• 제38권sup2호
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• pp.355-362
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• 2008

Purpose: The carrier for the delivery of bone morphogenetic proteins(BMPs) should also serve as a scaffold for new bone growth. In addition, predictable bone formation in terms of the volume and shape should be guaranteed. This study evaluated the ectopic bone formation of recombinant human BMP-2(rhBMP-2) using a micro macroporous biphasic calcium phosphate (MBCP: mixture of ${\beta}TCP$ and HA) block as a carrier in a rat subcutaneous assay model. Materials and Methods: Subcutaneous pockets were created on the back of 40 male Sprague-Dawley rats. In the pockets, rhBMP-2/MBCP and MBCP alone were implanted. The blocks were evaluated by histological and histometric parameters after a healing interval of 2 weeks (each 10 rats; MBCP and rhBMP-2/MBCP) or 8 weeks (each 10 rats; MBCP and rhBMP-2/MBCP). Results: The shape and volume of the block was maintained stable over the healing period. No histological bone forming activity was observed in the MBCP alone sites after 2 weeks and there was minimal new bone formation at 8 weeks. In the rhBMP-2/MBCP sites, new bone formation was evident in the macropores of the block. The new bone area at 8 weeks was greater than at 2 weeks. There was a further increase in the quantity of new bone with the more advanced stage of remodeling. Conclusions: A MBCP block could serve as a carrier system for predictable bone tissue engineering using rhBMPs.

• 한국농촌건축학회논문집
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• 제5권2호
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• pp.10-19
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• 2003

The purpose of this study was to analyze the formation and change of road-block-lot of the old inner city in cheongju The result of this study are as follows; (I)Among others a system roads of in around the old castle in cheongju city is most of feature north and south direction of road. Lot system is organic relations of north and south direction of road. Therefore, urban tissue in around the old castle in cheongju city is established order road system keep on the change of expansion urban tissue. (2) Block type classified into non-division, 2division and over 3division. (3) The square block remains mostly in Cheongju old castle, two-division block was around south of castle. And block of the grid-form street system divided into over 3 division. Through the guideline about characteristic of block type, residential area should be developed as a characteristics area in the urban area.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 추계학술발표대회
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• pp.33.2-33.2
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• 2009

Block copolymer lithography has attracted great attention for emerging nanolithography since nanoscaleperiodic patterns can be easily obtained through self-assembly process without conventional top-down patterning process. Since the morphologies of self-assembled block copolymer patterns are strongly dependent on surface energy of a substrate, suitable surface modification is required. Until now, the surface modification has been studied by using random copolymer or self-assembled mono layers (SAMs). However, the research on surface modifications has been limited within several substrates such as Si-based materials. In present study, we investigated the formation of block copolymer on Au substrate by $O_2$ plasma treatment with the SAM of 3-(p-methoxy-phenyl)propyltrichloro-silane [MPTS, $CH_3OPh(CH_2)_3SiCl_3$]. After $O_2$ plasma treatment, the chemical bonding states of the surface were analyzed by X-ray photoelectron spectroscopy (XPS). The static contact angle measurement was performed to study the effects of $O_2$ plasma treatment on the formation of MPTS monolayer. The block copolymer nanotemplates formed on Au surface were analyzed by scanning electron microscopy. The results showed that the ordering of self-assembled block copolymer pattern and the formation of cylindrical nano hole arrays were enhanced dramatically by oxygen plasma treatment. Thus, the oxidation of gold surface by $O_2$ plasma treatment enables the MPTS to form the monolayer assembly leading to surface neutralization of gold substrates.

• 터널과지하공간
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• 제26권6호
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• pp.475-483
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• 2016

지하공동 굴착현장에서 관찰되는 절리분포 양상에 대한 자료를 기반으로 굴착과정에서 형성될 수 있는 사면체 블록의 형상, 규모 및 붕락 가능성을 절리 영속성을 고려하여 예측하는 수치해석 기법을 개발하였다. 절리 영속성 분석결과를 이용하여 절리면의 확장성에 따른 개착면에서의 표출정도 및 블록형성 가능성 해석을 수행하는 기능을 고안하여 기존에 개발된 결정론적 3차원 블록해석모델에 접목시켰다. 개선된 수치해석모델의 신뢰성을 고찰하기 위하여 실제 블록 붕락이 발생된 굴착현장에 대한 해석을 수행하였다. 조사된 절리분포 양상에 의거하여 대표 방향성을 설정하고 잠재적 블록 형성을 분석하여 붕락된 블록 형상에 부합된 해석 결과를 도출하였으며, 이에 근거하여 굴착과정에서의 붕락 진행 미캐니즘을 블록형상을 고려하여 고찰하였다.

• Bulletin of the Korean Chemical Society
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• 제25권3호
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• pp.351-356
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• 2004

Selected MPEG-b-PDLLA block copolymers have been synthesized by ring-opening polymerization with systematic variation of the chain lengths of the resident hydrophilic and hydrophobic blocks. The size and shape of the micelles that spontaneously form in solution are then controlled by the characteristics of the block copolymer template. All the materials prepared in this study showed the tunable pore size of 20-80 ${\AA}$ with the increase of hydrophobic chain lengths and up to 660 $m^2$/g of specific surface area. The formation mechanism of these nanoporous structures obtained by controlling the micelle size has been confirmed using both liquid and solid state $^{13}C\;and\;^{29}Si$ NMR techniques. This work verifies the formation mechanism of nanoporous structures in which the pore size and wall thickness are closely dependent on the size of hydrophobic cores and hydrophilic shells of the block copolymer templates.

• 한국지역지리학회지
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• 제10권1호
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• pp.206-214
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• 2004

본 연구의 목적은 정족산에 발달한 무제치 제2늪의 형성과정을 밝히는 것이다. 이를 위하여 꼭지와 곡지를 가로막은 암설지형의 형성과정을 분석하였다. 첫째, 무제치 제2늪이 발달한 곡지는 온난 습윤한 기후환경에서 절리를 따라 심층풍화 된 기반암의 풍화산물이 우세로 탈거되면서 만들어진 와지이다. 둘째, 무제치 제2늪은 플라이스토세의 최종빙기에 발달한 암괴류가 와지의 입구를 가로막음으로써 형성된 주변호소(marginal lake)가 사면에서 공급된 사력물질로 매립되면서 얕아져 수생식생이 자라게 되어 늪지로 변모하였다. 셋째, 제2늪은 늪지를 가로막은 암괴류 내의 세립 메트릭스 물질이 탈거됨으로써 점차 배수되어 육화되고 있다. 이를 지연시키기 위해서는 늪지를 가로막고 있는 암괴류 내의 빈 공간을 세립물질로 충진하여 배수를 억제하여야 한다.

• 한국전기전자재료학회논문지
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• 제34권2호
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• pp.130-135
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• 2021

Wrinkle patterns were fabricated on styrene-butadiene-styrene (SBS) block copolymer substrates using ion-beam (IB) irradiation with various intensities. The wavelength of the wrinkle pattern increased as the IB intensity was increased from 800 to 1,600 eV. IB irradiation-induced changes in the surface properties that were confirmed via physicochemical surface analyses. X-ray photoelectron spectroscopy analysis revealed chemical surface reformation due to the IB irradiation, resulting in C-O/C=O bonds after IB irradiation that were not reported before. These results indicate that the surface chemical modification caused by IB irradiation is strongly related to the surface modulus, which is important when fabricating wrinkle patterns. Furthermore, a strong IB irradiation induced a strong compressive strain; thus the size of the wrinkle pattern was increased.