• Title/Summary/Keyword: Block Assembly

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Self-assembly of Si-containing block copolymers for next-generation nanofabrication

  • Jeong, Yeon-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.22-23
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    • 2011
  • As device dimensions shrink, it is increasingly important to develop fabrication methods that can create sub-15 nm features of regular or arbitrary geometry in a rapid, parallel, and efficient process. This talk will discuss approaches based on self-assembling hybrid polymers containing Si. The thin films of those materials systems can generate well-ordered periodic arrays of dots or lines. For achieving, long-range ordering, it is helpful to use lithographically-defined templates, which are in general much larger than the length-scale of self-assembled nanostructures. For example, the self-assembly of polymer nanostructures can easily be templated using an array of nanoscale topographical elements that act as guiding templates or surrogates for one of two microdomains. The solvent-vapor-induced tunability of pattern dimension and morphology will be discussed as well. Those material systems can excellently serve for high-precision self-assembly that can provide good resolution, reliability, and controllability and be considered as an option for a future nanomanufacturing technology.

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Self-Assembly Modification of Perfluorosulfonic Acid Membranes for the Application to Direct Methanol Fuel Cells

  • Moon, Go-Young;Rhim, Ji-Won
    • Macromolecular Research
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    • v.16 no.6
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    • pp.524-531
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    • 2008
  • The mitigation or elimination of methanol crossover for perfluorosulfonic acid fuel cell membranes has been investigated extensively for direct methanol fuel cell applications with the aim of increasing the electrochemical performance and enhancing the utilization rate of methanol. Self-assembly modifications by applying an oppositely charged polyelectrolyte to Nafion membranes were attempted in order to block or reduce methanol crossover while maintaining the other advantageous properties of Nafion membranes. It was reported that anionic polyallylamine hydrochloride (PAH) was the most efficient polyelectrolyte in reducing methanol crossover, and considerable cell performance was obtained even at a methanol feed concentration of 10 M.

Development of Non-Scallop Block Joint Welding Method (논-스캘럽 블록 조인트 용접법 개발)

  • Kim, Ho-Kyeong;Ko, Dae-Eun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.9
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    • pp.5419-5424
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    • 2014
  • A weld scallop is a small quadrant or half circle type hole installed in the weld line cross area for easy welding operation. Many types of T-bars with a scallop can be welded in a block assembly stage in shipbuilding. The difficulties arise from the fact that scallops are to be filled by build-up welding after welding of the cross line is complete. In this study, a non-scallop block joint welding method was developed using special type CBM (ceramic backing material). The wedge shaped CBM was devised to insert a CBM into just the V groove of weld line cross area without weld scallop. A saw-toothed shape was adopted for easy cutting of the unnecessary part in the CBM fitting process. The applicability of the developed method was verified through welding experiments based on the yard welding conditions.

Implementation and performance evaluation of PIPO lightweight block ciphers on the web (웹상에서의 PIPO 경량 블록암호 구현 및 성능 평가)

  • Lim, Se-Jin;Kim, Won-Woong;Kang, Yea-Jun;Seo, Hwa-Jeong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.5
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    • pp.731-742
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    • 2022
  • PIPO is the latest domestic lightweight block cipher announced in ICISC'20, which is characterized by being lightweight to facilitate implementation on IoT with limited resources. In this paper, PIPO 64/128-bit and 64/256-bit were implemented using web-based languages such as Javascript and WebAsembly. Two methods of performance evaluation were conducted by implementing bitsice and TLU, and the performance was compared by implementing Looped written using for statements and Unrolled written for statements. It performs performance evaluations in various web browsers such as Google Chrome, Mozilla Firefox, Opera, and Microsoft Edge, as well as OS-specific environments such as Windows, Linux, Mac, iOS, and Android. In addition, a performance comparison was performed with PIPO implemented in C language. This can be used as an indicator for applying PIPO block cipher on the web.

Study on Erection Block Positioning Using Genetic Algorithm (유전자 알고리즘을 이용한 탑재블록 위치제어에 관한 연구)

  • Shin, Sung-Chul;Lee, Jae-Chul;Kim, Soo-Young
    • Journal of Ocean Engineering and Technology
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    • v.25 no.5
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    • pp.76-81
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    • 2011
  • In the shipbuilding industry, accuracy management is one of the keys for strengthening competitiveness. However, ship block errors are unavoidable in the block erection stage because of the deformation of the blocks. Currently, accuracy managers decide whether or not block corrections are needed, based on measured and designed point data. They adjust the locations of hull blocks so that the blocks are aligned with other assembly blocks based upon the experience of production engineers. This paper proposes an optimization process that can adjust the locations of ship blocks during the erection stage. A genetic algorithm is used for this optimization scheme. Finally, the feasibility of the proposed method is discussed using several case studies. We found that the proposed method can find the optimized re-alignment of erection blocks, as well as improve the productivity of the erection stage.

The Effects of Composition, Solvent Selectivity, and Additive on the Morphology of Hybrid Nano Thin Films Composed of Self-Assembled Block Copolymer and Titanium Dioxide (자기조립 블록공중합체와 이산화티타늄으로 구성된 하이브리드 나노 박막의 모폴로지에 미치는 고분자의 조성, 용매의 선택성 및 첨가제의 영향)

  • Jang, Yoon-Hee;Cha, Min-Ah;Kim, Dong-Ha
    • Polymer(Korea)
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    • v.32 no.5
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    • pp.465-469
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    • 2008
  • Hybrid thin films composed of block copolymer(BCP) and $TiO_2$ with various morphologies on the nanoscale were fabricated using self-assembly of block copolymer combined with sol-gel process. The factors governing morphology changes considered in this study are block copolymer composition, selectivity of solvent and the inclusion of an additive. We also investigated the efficiency of photoluminescence for selected films with different morphologies. Micelle or nanowire structure can be derived from the self-assembly of poly (styrene-block-4-vinyl pyridine) (PS-b-P4VP) depending on the relative selectivity of the solvent for the two blocks, and the titanium tetraisopropoxide ($Ti{OCH (CH_3)_2}_4$, TTIP) is coordinated with nitrogen in P4VP block. Addition of a third component 3-pentadecylphenol into the BCP/sol-gel mixture solution induces morphology change as a result of the change of relative volume fraction of the BCP. We confirmed that the efficiency of $TiO_2$ fluorescence changes for films depending on morphologies.

A Scheduling System based on DBMS for Shipbuilding (DATABASE 기반의 조선업 일정계획 시스템 구축)

  • Lee, Dong-Uk;Kim, Shun-Kyum;Lee, Ho-Yoon;Park, Sung-Kyu;Lee, Dae-Hyeong;Wang, Gi-Nam
    • Korean Journal of Computational Design and Engineering
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    • v.17 no.1
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    • pp.26-34
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    • 2012
  • Assembly scheduling in shipbuilding is responsible for determine assembly process orders and departmental production schedule for the block, the basic composite unit of ships. It is necessary much more information to decide production scheduling as the characteristic of shipbuilding which has been more complex and more various and also, a lot of waste of time and of human power is generated in the course of data processing. The target shipbuilding manufacturer of this study use empirical techniques, based on the user's discretion, to compile and to apply data which are scattered in DB storages separately. Because of that reason, the user should not only be performed identification and screening operations but also modification and verification for vast amounts of data, so it is hard to keep the consistency of the data and also the operation time is not constant. Accordingly, the object in this study is by presenting an efficient DB framework to reduce wasting time and man-hour at experienced-oriented process, abate user's manual operations and support an efficient scheduling in assembly processes.

Preparation of Polymeric Self-Assembly and Its Application to Biomaterials

  • Cho, Chong-Su;Park, In-Kyu;Nah, Jae-Woon;Toshihiro Akaike
    • Macromolecular Research
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    • v.11 no.1
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    • pp.2-8
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    • 2003
  • The self-assembly of polymers can lead to supramolecular systems and is related to the their functions of material and life sciences. In this article, self-assembly of Langmuir-Blodgett (LB) films, polymer micelles, and polymeric nanoparticles, and their biomedical applications are described. LB surfaces with a well-ordered and layered structure adhered more cells including platelet, hepatocyte, and fibroblast than the cast surfaces with microphase-separated domains. Extensive morphologic changes were observed in LB surface-adhered cells compared to the cast films. Amphiphilic block copolymers, consisting of poly(${\gamma}$-benzyl L-glutamate) (PBLG) as the hydrophobic part and poly(ethylene oxide) (PEO) [or poly(N-isopropylacrylamide) (PNIPAAm)] as the hydrophilic one, can self-assemble in water to form nanoparticles presumed to be composed of the hydrophilic shell and hydrophobic core. The release characteristics of hydrophobic drugs from these polymeric nanoparticles were dependent on the drug loading contents and chain length of the hydrophobic part of the copolymers. Achiral hydrophobic merocyanine dyes (MDs) were self-assembled in copolymeric nanoparticles, which provided a chiral microenvironment as red-shifted aggregates, and the circular dichroism (CD) of MD was induced in the self-assembled copolymeric nanoparticles.

Acetic Acid Recovers Microtubule Disassembly Caused by Clostridium difficile Toxin A in Human Colonocytes through Increased Tubulin Acetylation (C. difficile 톡신이 야기하는 대장상피세포 미세소관 변형에 대한 초산의 억제 효능)

  • Yoon, I Na;Kim, Ho
    • Journal of Life Science
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    • v.28 no.8
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    • pp.885-891
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    • 2018
  • Clostridium difficile (C. difficile) toxin A is known to cause acute gut inflammation in humans and animals by triggering cytoskeletal disorganization in gut epithelial cells. In human colonocytes, toxin A blocks microtubule assembly by directly increasing the enzymatic activity of histone deacetylase-6 (HDAC-6), a tubulin-specific deacetylase, thereby markedly decreasing tubulin acetylation, which is essential for microtubule assembly. Microtubule assembly dysfunction-associated alterations (i.e., toxin A-exposed gut epithelial cells) are believed to trigger barrier dysfunction and gut inflammation downstream. We recently showed that potassium acetate blocked toxin A-induced microtubule disassembly by inhibiting HDAC-6. Herein, we tested whether acetic acid (AA), another small acetyl residue-containing agent, could block toxin A-induced tubulin deacetylation and subsequent microtubule assembly. Our results revealed that AA treatment increased tubulin acetylation and enhanced microtubule assembly in an HT29 human colonocyte cell line. AA also clearly increased tubulin acetylation in murine colonic explants. Interestingly, the AA treatment also alleviated toxin A-induced tubulin deacetylation and microtubule disassembly, and MTT assays revealed that AA reduced toxin A-induced cell toxicity. Collectively, these results suggest that AA can block the ability of toxin A to cause microtubule disassembly-triggered cytoskeletal disorganization by blocking toxin A-mediated deacetylation of tubulin.