• 제목/요약/키워드: Bio-oxidation

검색결과 219건 처리시간 0.029초

마이크로 아크 산화 표면처리 기술을 활용한 치과도재 소부용 티타늄 인공치아 결합강도 연구 (A Study on the Bonding Strength of Titanium Artificial Teeth for Baking Dental Ceramics using Micro-arc Oxidation Surface Treatment Technology)

  • 송종법;박종민;김종순;정효경;최원식
    • 한국산업융합학회 논문집
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    • 제25권2_2호
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    • pp.309-314
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    • 2022
  • The bonding strength [ISO22674] test was conducted by firing a dedicated ceramic powder on the surface of the dental titanium material treated with micro-arc oxidation. In the test group, an average result value of 34.34 MPa was obtained, and in the control group, a result value of 21.53 MPa was obtained. The bonding strength of the test group was higher than that of the control group by 12.81 MPa, resulting in a 37% improvement in durability of the dental artificial tooth ceramic restoration.

Effects of Oxidation on the Order-disorder Transition in NiPt Alloy Nano Crystals

  • 서옥균;황재성;송다현;이지연;최정원;이수웅;강현철;노도영
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.253-253
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    • 2012
  • The effects of oxidation on the order-disorder transition in NiPt bimetallic alloy crystal have been investigated using in-situ synchrotron x-ray scattering technique. The temperature dependence of the crystal structure and the order parameter were measured during in-situ heating and cooling under vacuum and oxygen environments. The order-disorder transition temperature of NiPt alloy crystals in vacuum was between $615^{\circ}C$ and $627^{\circ}C$. On the other hand under oxygen environment, the transition temperature decreases by about $31^{\circ}C$ after the oxidation. The change of the transition temperature can be explained by the formation of NiO crust on the surface of NiPt crystal, which alters the composition of the Ni and Pt atoms. Since the transition temperature depends sensitively on the Ni-Pt composition, the transition temperature changes as Ni atoms diffuse out to form NiO.

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Glutathione suppresses lipid oxidation of Clanis bilineata larvae meat during frozen storage

  • WU, Shengjun
    • Entomological Research
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    • 제48권5호
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    • pp.453-456
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    • 2018
  • The lipids of Clanis bilineata larvae meat (CBLM) are susceptible to oxidation, and thus the commercial and consumption values of CBLM decrease during frozen storage. In the present study, peroxide values (PV), thiobarbituric acid-reactive substances (TBARS), free fatty acid (FFA) content, fatty acid composition, and likeness (palatability) score of CBLM were determined to investigate the effect of glutathione on the oxidation of CBLM lipids. Glutathione decreased the PV, TBARS, and FFA content, maintained fatty acid composition, and increased the likeness (palatability) score of the CBLM, indicating that glutathione can be used as a cryoprotectant to extend the shelf life of CBLM.

바이오디젤 및 바이오디젤 혼합연료의 산화특성 연구에 의한 사용 수명 예측 (Life Time Estimation of Biodiesel and Biodiesel Blend Fuel from the Oxidation Stability Analysis)

  • 정충섭;동종인;이영재
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.579-584
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    • 2007
  • 대두유로부터 생산된 바이오디젤과 바이오디젤 혼합 연료유를 대상으로 지방산메틸에스터 함량과 화학적 분석을 통해 산화 특성과 오일의 수명 예측 연구를 수행하였다. 바이오디젤, 경유, BD5, BD20은 산화가 진행될수록 산가(Acid number), 동점도(Kinematic Viscosity) 및 밀도(Density)는 증가하였다. 산가 측정결과의 활용에 의해 임의의 온도조건에서 정확한 사용수명을 예측하기 위하여 화학속도론에 의거하여 각각의 연료에 대한 사용수명식을 도출하였다. 도출된 사용수명식으로부터 바이오디젤이 가장 빠르게 산화가 진행되었고 바이오디젤 혼합량이 증가할수록 사용수명이 단축되는 것을 확인할 수 있었다.

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The Effect of Biodiesel and Ultra Low Sulfur Diesel Fuels on Emissions in 11,000 cc Heavy-Duty Diesel Engine

  • Baik, Doo-Sung;Han, Young-Chool
    • Journal of Mechanical Science and Technology
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    • 제19권3호
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    • pp.870-876
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    • 2005
  • It seems very difficult to comply with upcoming stringent emission standards in vehicles. To develop low emission engines, better quality of automotive fuels must be achieved. Since sulfur contents in diesel fuels are transformed to sulfate-laden particulate matters as a catalyst is applied, it is necessary to provide low sulfur fuels before any Pt-based oxidation catalysts are applied. In general, flash point, distillation $90\%$ and cetane index are improved but viscosity can be worse in the process of desulfurization of diesel fuel. Excessive reduction of sulfur may cause to degrade viscosity of fuels and engine performance in fuel injection systems. This research focused on the performance of an 11,000 cc diesel engine and emission characteristics by the introduction of ULSD, bio-diesel and a diesel oxidation catalyst, where the bio-diesel was used to improve viscosity of fuels in fuel injection systems as fuel additives or alternative fuels.

바이오디젤 및 바이오디젤 혼합연료의 산화특성 연구에 의한 사용 수명 예측 (Life Time Estimation of Biodiesel and Biodiesel Blend Fuel from the Oxidation Stability Analysis)

  • 정충섭;이영재;동종인
    • 신재생에너지
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    • 제3권2호
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    • pp.17-23
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    • 2007
  • 대두유로부터 생산된 바이오디젤과 바이오디젤 혼합 연료유를 대상으로 지방산메틸에스터 함량과 화학적 분석을 통해 산화 특성과 오일의 수명 예측 연구를 수행하였다. 바이오디젤, 경유, BD5, BD20은 산화가 진행될수록 산가(Acid number), 동점도(Kinematic Viscosity) 및 밀도(Density)는 증가하였다. 산가 측정결과의 활용에 의해 임의의 온도조건에서 정확한 사용수명을 예측하기 위하여 화학속도론에 의거하여 각각의 연료에 대한 사용수명식을 도출하였다. 도출된 사용수명식으로부터 바이오디젤이 가장 빠르게 산화가 진행되었고 바이오디젤 혼합량이 증가할수록 사용수명이 단축되는 것을 확인할 수 있었다.

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Enhancement of NOx photo-oxidation by Fe-doped TiO2 nanoparticles

  • Martinez-Oviedo, Adriana;Ray, Schindra Kumar;Gyawali, Gobinda;Rodriguez-Gonzalez, Vicente;Lee, Soo Wohn
    • Journal of Ceramic Processing Research
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    • 제20권3호
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    • pp.222-230
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    • 2019
  • Microwave hydrothermal-assisted sol-gel method was employed to synthesize the Fe doped TiO2 photocatalyst. The morphological analysis suggests anatase phase nanoparticles of ~20 nm with an SBET area of 283.99 ㎡/g. The doping of Fe ions in TiO2 created oxygen vacancies and Ti3+ species as revealed through the XPS analysis. The reduction of the band gap (3.1 to 2.8 eV) is occurred by doping effect. The as-prepared photocatalyst was applied for removal of NOx under solar light irradiation. The doping of Fe in TiO2 facilitates 75 % of NOx oxidation efficiency which is more than two-fold enhancement than the TiO2 photocatalyst. The possible reason of enhancement is associated with high surface area, oxygen vacancy, and reduction of the band gap. Also, the low production of toxic intermediates, NO2 gas, is further confirmed by Combustion Ion Chromatography. The mechanism related NOx oxidation by the doped photocatalyst is explained in this study.

하수처리수 재이용을 위하여 Sym-bio공정과 용존 오존 부상공정을 이용한 하수처리의 효율 분석 (A Treatment Efficiency of Wastewater by using Sym-Bio Process and Dissolved Ozone flotation Process for Water Reuse)

  • 박찬규;박재한;이경희;안윤희;고광백;정현철
    • 한국물환경학회지
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    • 제24권1호
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    • pp.86-90
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    • 2008
  • Water reuse of effluent is limited, due to bacteria and chromaticity or turbidity which may result in low perception of water quality. Consequently, this study showed a method in the reuse of treated wastewater by a diversified treatment method, with separation of centralized reformation of aeration tank into pre-treatment with minimum installation of facilities, and post-treatment, applying advanced oxidation treatment. A pilot plant experiment was performed using Sym-Bio process adopting an NADH Sensor without modification of the exiting aeration tank. The Dissolved Ozone Flotation process, which is an advanced oxidation process, to treat the remaining organics, nutrients, chromaticity, turbidity and bacteria. As a result in the Sym-Bio process, the biological treatment, even on the condition of single stage reaction tank, the treatment efficiencies of BOD, $COD_{Mn}$, $COD_{Cr}$, SS and T-N were 96.6%, 84.6%, 88.25%, 95.1% and 71.0%, respectively, while that for T-P was 25.0%, which required further treatment. In the Dissolved Ozone Flotation process, the advanced oxidation treatment, the treatment efficiencies of BOD, $COD_{Mn}$, $COD_{Cr}$, SS, T-N, T-P, chromaticity, turbidity, bacteria, coliforms were 78.9%, 34.6%, 28.7%, 48.0%, 70.4%, 82.4%, 84.0%, 74.5%, 99.8% and 99.4%, respectively.

The Fate and Factors Determining Arsenic Mobility of Arsenic in Soil-A Review

  • Lee, Kyo Suk;Shim, Ho Young;Lee, Dong Sung;Chung, Doug Young
    • 한국토양비료학회지
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    • 제48권2호
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    • pp.73-80
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    • 2015
  • Arsenic which is found in several different chemical forms and oxidation states and causes acute and chronic adverse health effects is a toxic trace element widely distributed in soils and aquifers from both geologic and anthropogenic sources. Arsenic which has a mysterious ability to change color, behavior, reactivity, and toxicity has diverse chemical behavior in the natural environment. Arsenic which has stronger ability to readily change oxidation state than nitrogen and phosphorus due to a consequence of the electronic configuration of its valence orbitals with partially filled states capable of both electron donation and acceptance although the electronegativity of arsenic is greater than that of nitrogen and similar to that of phosphorus. Arsenate (V) is the thermodynamically stable form of As under aerobic condition and interacts strongly with solid matrix. However, it has been known that adsorption and oxidation reactions of arsenite (III) which is more soluble and mobile than As(V) in soils are two important factors affecting the fate and transport of arsenic in the environment. That is, the movement of As in soils and aquifers is highly dependent on the adsorption-desorption reactions in the solid phase. This article, however, focuses primarily on understanding the fate and speciation of As in soils and what fate arsenic will have after it is incorporated into soils.