• Analytical Science and Technology
• /
• v.30 no.4
• /
• pp.174-181
• /
• 2017

Bio-liquid is a liquid by-product of the hydrothermal carbonization (HTC) reaction, converting wet biomass into solid hydrochar, bio-liquid, and bio-gas. Since bio-liquid contains various compounds, it requires efficient sampling method to extract the target compounds from bio-liquid. In this research, fatty acid methyl ester (FAME) in bio-liquid was extracted based on hollow fiber supported liquid phase microextraction (HF-LPME) and determined by Gas Chromatography-Flame Ionization Detector (GC-FID) and Gas Chromatography/Mass Spectrometry (GC/MS). The well-known major components of biodiesel, including methyl myristate, palmitate, methyl palmitoleate, methyl stearate, methyl oleate, and methyl linoleate had been selected as standard materials for FAME analysis using HF-LPME. Physicochemical properties of bio-liquid was measured that the acidity was 3.30 (${\pm}0.01$) and the moisture content was 100.84 (${\pm}3.02$)%. The optimization of HF-LPME method had been investigated by varying the experimental parameters such as extraction solvent, extraction time, stirring speed, and the length of HF at the fixed concentration of NaCl salt. As a result, optimal conditions of HF-LPME for FAMEs were; n-octanol for extraction solvent, 30 min for extraction time, 1200 rpm for stirring speed, 20 mm for the HF length, and 0.5 w/v% for the concentration of NaCl. Validation of HF-LPME was performed with limit of detection (LOD), limit of quantitation (LOQ), dynamic range, reproducibility, and recovery. The results obtained from this study indicated that HF-LPME was suitable for the preconcentration method and the quantitative analysis to characterize FAMEs in bio-liquid generated from food waste via HTC reaction.

• Analytical Science and Technology
• /
• v.31 no.3
• /
• pp.112-121
• /
• 2018

The hydrothermal carbonization method has received great attention because of the conversion process from biomass. The reaction produces various products in hydrochar, bio-liquid, and gas. Even though its yield cannot be ignored in amount, it is difficult to find research papers on bio-liquid generated from the hydrothermal carbonization reaction of biomass. In particular, the heterogeneity of feedstock composition may make the characterization of bio-liquid different and difficult. In this study, bio-liquid from the hydrothermal carbonization reaction of food wastes at $230^{\circ}C$ for 4 h was investigated. Among various products, fatty acid methyl esters were analyzed using two different extraction methods: liquid-liquid extraction and column chromatography. Different elutions with various solvents enabled us to categorize the various components. The eluents and fractions obtained from two different extraction methods were analyzed by gas chromatography with a mass spectrometer (GC/MS). The composition of the bio-liquid in each fraction was characterized, and seven fatty acid methyl esters were identified using the library installed in GC/MS device.

• Korean Journal of Environmental Agriculture
• /
• v.41 no.4
• /
• pp.236-244
• /
• 2022

BACKGROUND: Liquid fertilizers can provide nutrients to crops effectively and quickly. Amino acid liquid fertilizers produced by decomposing the residues of rendered livestock carcasses are expected to be effective in improving the productivity and quality of crops. METHODS AND RESULTS: The treatment conditions for maize cultivation were control (Cn), inorganic fertilizer (IF), inorganic fertilizer and rendering residue liquid fertilizer (IF+RALF), compost (CP), compost and rendering residue liquid fertilizer (CP+RALF). Crop productivity, sugar content, and nutrient uptake were investigated after maize harvest in the field applied with liquid fertilizers. Maize yields ranged from 87.6-158 g/plant, and the yield increased by 7.9% and 12.9% in IF+RALF IF+RALF and CP+RALF than in IF and CP, respectively. The maize sugar content increased in the range of 0.1-0.5 brix % by rendering residue liquid fertilizer (RALF) fertilization, and the sugar content was the highest in CP+RALF. There was no significant change in soil chemical properties of the soil due to liquid fertilizer treatment. CONCLUSION(S): RALF increased yield and sugar content in maize cultivation, and fertilization with organic fertilizers was more effective for maize cultivation than inorganic fertilizers. Residues of rendered livestock carcass can be recycled as amino acid fertilizers, which can be effectively used for crop production and quality improvement.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.10
• /
• pp.1517-1520
• /
• 2003

• Korean Journal of Soil Science and Fertilizer
• /
• v.50 no.5
• /
• pp.462-471
• /
• 2017

A more efficient use of nutrients from organic sources can benefit both farmers and water quality in agriculture. In this paper we reviewed information related to the regulations and guidelines of a swine liquid fertilizer to propose an establishment scheme for the official standards of swine manure slurry as a liquid fertilizer for organic farming. According to the law of establishment and designation of official standard of fertilizers, the liquid fertilizer made with pig liquid manure belongs to the byproduct fertilizer as of one of organic fertilizer. However, the official standards for byproduct fertilizers including the liquid fertilizer set by the Rural Development Administration (RDA), especially for a liquid swine manure fertilizer, should be revised to meet the goals of laws pursuing the environmentally sound agriculture, especially for organic farming because the terms and relevant standards need additional specific standards alike the standards such as impurities and parameter for declaration in EU. Therefore, it is suggested that official standards for byproduct fertilizers should be revised with respect to nutrient, salt content as of SAR and Na content instead of NaCl. Also we need to develop the maximum limit of heavy metals in soil to which the liquid fertilizer can be applied, as well as application rate depending on EC of the liquid fertilizer.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.33 no.4
• /
• pp.227-230
• /
• 2007

The multi-lamellar and liquid crystal structures have drawn great public attention in the functional cosmetic and skin-related medicinal areas recently. The structure of an emulsion containing aqueous phase as a binding water and fixed oil phase components forming an association compound of the multi-lamellar structure can reconstruct the intercellular lipid lamellar structure in the stratum corneum and restore barrier function of the skin. In this study, we investigated the beneficial effect of bio-mimic liquid crystal emulsions (BLCE) containing higher fatty alcohol, lecithin, and cholesterol on the skin barrier function, and evaluated its cytotoxicity.

• The Korean journal of helicobacter and upper gastrointestinal research
• /
• v.18 no.3
• /
• pp.150-156
• /
• 2018

Precision medicine stands for 4Ps - precise, preventive, participatory, and personal; in which "precision" is important because the current modern medicine starts from "trial and error," and "one does not fit all". Current targeted therapies for cancer have changed treatment approaches and led the precision medicine; however, clinical use of liquid biopsy, using blood or other liquid specimens to characterize circulating tumor cells (CTC) or tumor genes instead of biopsies of tumor tissues, still awaits availability of more information regarding non-invasive cancer detection and characterization, prediction of treatment response, monitoring the disease course and relapse possibilities, identification of mechanisms of drug resistance, and newer pathogenesis. In this review, we will introduce the basic concept of CTC, circulating cell free DNA, and exosomes and their possible application for gastric cancer relevant with Helicobacter pylori infection.

• Korean Journal of Agricultural Science
• /
• v.43 no.3
• /
• pp.424-431
• /
• 2016

The nutrients in livestock manure produced during fermentation processes in public livestock recycling centers are used as fertilizers. However, the large amounts of swine manure produced in intensive livestock farms can be a nonpoint source of pollution. In this experiment, we investigated the chemical properties, inorganic components, and heavy metal contents in 101 samples of liquid swine manure collected from 28 public livestock recycling centers throughout the nation. Results showed that the average pH of the samples was alkaline (pH range 5.18 to 9.54), and their maximum EC was $53.2dS\;m^{-1}$. The amounts of total nitrogen and total phosphorus were in the range of 1000 - 2000 and $200-800mg\;L^{-1}$ while potassium, which constituted 47% of the total inorganic ions recovered from the liquid swine manure, amounted to $1500mg\;L^{-1}$. The most distinctive heavy metals recovered from the liquid swine manure were copper and zinc although the amounts of both heavy metals were much lesser than those of the standards as livestock liquid fertilizer set by the Rural Development Administration. On the other hand, the amount of nitrogen decreased rapidly with an increasing fermentation period from immature to mature, assumed to be lost as volatile compounds, such as ammonia, which are the major odor components during the fermentation process.

• Journal of the Korean Applied Science and Technology
• /
• v.28 no.4
• /
• pp.431-437
• /
• 2011

Transparent liquid crystal gels with high oil content by fatty acid soap were investigated. The solubilization efficiency of the mineral oil was dependent on the process. The process of dropping water part into the solution of oil and surfactant was more efficient than the process of dropping water part into the surfactant solution and after that dropping oil. The fatty acid soap could not solubilize the high oil content, but under the certain range, addition of CDE (Coconut Diethanolamide), Arlacel 165 (Glyceryl Stearate/PEG-100 Stearate) and cetostearyl alcohol helped solubilize the high content oil. Also, the glycerin and water content had influence on the solubilization. Especially, higher oil content gel showed elastic feature.

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.2
• /
• pp.149-155
• /
• 2012

This study was conducted to investigate the effect of liquid pig manure application on soil chemical properties in rice - Chinese milkvetch rotation. Field experiment was designed with APLM 0 (Chinese milkvetch + Liquid pig manure $0L\;m^{-2}$), APLM 50 (Chinese milkvetch + Liquid pig manure $1.8L\;m^{-2}$), APLM 75 (Chinese milkvetch + Liquid pig manure $2.7L\;m^{-2}$) and APLM 100 (Chinese milkvetch + Liquid pig manure $3.6L\;m^{-2}$), respectively. The concentration of O.M, T-N, Avail. $P_2O_5$, K, Ca and Mg at different liquid pig manure levels in soil were generally high in the order of APLM 100 > APLM 75 > APLM 50 > APLM 0. Especially, T-N concentration of soil in APLM 100 was 1.4 times higher than APLM 0. The yield of rice in APLM 100 was $636kg\;10a^{-1}$ (increasing yield 5.3%) compared with APLM 0 in rice-Chinese milkvetch crop rotation. Therefore, application of liquid pig manure was useful in rice - Chinese milkvetch crop rotation.