• Journal of Sensor Science and Technology
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• v.26 no.6
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• pp.379-385
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• 2017

In this study, an amperometric non-enzymatic glucose sensor was developed on the surface of a glassy carbon electrode by simply drop-casting the synthesized homogeneous suspension of hexagonal boron nitride (h-BN) nanosheets with a copper metal-organic framework (Cu-MOF) composite. Comprehensive analytical methods, including field-emission scanning electron microscopy (FE-SEM), Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), cyclic voltammetry, electrochemical impedance spectroscopy, and amperometry, were used to investigate the surface and electrochemical characteristics of the h-BN-Cu-MOF composite. The FE-SEM, FT-IR, and XRD results showed that the h-BN-Cu-MOF composite was formed successfully and exhibited a good porous structure. The electrochemical results showed a sensor sensitivity of $18.1{\mu}A{\mu}M^{-1}cm^{-2}$ with a dynamic linearity range of $10-900{\mu}M$ glucose and a detection limit of $5.5{\mu}M$ glucose with a rapid turnaround time (less than 2 min). Additionally, the developed sensor exhibited satisfactory anti-interference ability against dopamine, ascorbic acid, uric acid, urea, and nitrate, and thus, can be applied to the design and development of non-enzymatic glucose sensors.

• Journal of the Korean Society of Safety
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• v.20 no.4 s.72
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• pp.63-70
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• 2005

It has been used so many kinds of architectural materials and interior products in current building construction, and use of composite architectural materials is increasing with the development of chemical technology. As the green architecture has become the center of public interest, much effort is conducted in advanced countries on the LCA point of view, such as restriction of architectural materials that emitting pollution substances, developing of Non-Toxic architectural materials, and recycling of used materials, etc. with the cooperation of related organizations, material manufacture companies, and construction companies. Because the kinds of materials to be used in building constructions are so various, there might be some possibility of personal and subjective choice at the time of materials selection resulting the missing the requirements of building components and the choice of harmful materials to human. One way to resolve the material problem is to present the green architectural materials which coincide with the quality performance at service and not harmful to man and nature. At this point of view, this study aims to develop the material classification model by investigating the major labelling system about green architectural materials in both domestic and abroad and to implement an efficient material selection system by making a powerful database of environmental standard and quality basis of building requirements.

• Korean Journal of Metals and Materials
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• v.50 no.5
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• pp.401-406
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• 2012

When viewed using a magnetic resonance imaging (MRI) system, invasive materials inside the human body, in many cases, severely distort the MR image of human tissues. The degree of the MR image distortion increases in proportion not only to the difference in the susceptibility between the invasive material and the human tissue, but also to the intensity of the magnetic field induced by the MRI system. In this study, by blending paramagnetic Ti particles with diamagnetic graphite, we synthesized $Ti_{100-x}C_x$ composites that can reduce the artifact in the MR image under the high-strength magnetic field. Of the developed composites, $Ti_{70}C_{30}$ showed the magnetic susceptibility of ${\chi}=67.6{\times}10^{-6}$, which corresponds to 30% of those of commercially available Ti alloys, the lowest reported in the literature. The level of the MR image distortion in the vicinity of the $Ti_{70}C_{30}$ composite insert was nearly negligible even under the high magnetic field of 4.7 T. In this paper, we reported on a methodology of designing new structural materials for bio-applications, their synthesis, experimental confirmation and measurement of MR images.

• Journal of the Korea Institute of Building Construction
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• v.19 no.1
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• pp.19-29
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• 2019

In this study, a revised oil leakage evaluation method for assessing oil leakage stability of asphalt mastics used in upper slabs of below-grade residential parking lots was developed and presented. In order to verify the reliability and reproducibility of leakage results, the parameters the revised evaluation was carried out for three products with actual leakage history, and it was confirmed the leaks could be reproduced whereas the existing methods could not. To quantitatively verify the reproducibility, the filler content of the leaked samples was derived and the maximum filler content was 64% lower than that of the normal sample. The same results was found with the samples from the actual leakage site, thus verifying the reliability of the revised evaluation method.

• Bulletin of the Korean Chemical Society
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• v.33 no.4
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• pp.1297-1302
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• 2012

The interaction between carbon monoxide (CO) and a cobalt-salen complex (Co(salen)) was studied and applied to detect CO. The metal complex doped PEDOT:PSS film exhibited good sensitivity to CO and differentiate CO from other gases. The response of the composite to CO was reversible (RSD < 5%) change in resistance upon removal of CO gas from the test chamber. The effects of adding Co(salen) in the probe film on the response of the sensor were investigated using AFM, XPS, and FT-IR spectroscopy. The sensitivity of the sensor increased as the Co(salen) concentration enhanced as it increased from 0.0 to 1.5 wt. %, where the highest sensitivity ($%{\Delta}R/R_o$) of $-25.0{\pm}0.05%$ was achieved with 1.0 wt. % Co(salen). The sensor containing probe exhibited a linear response ($R^2$ = 0.983) in the range of 0.5 to 10.0% CO (v/v) $N_2$, and the detection limit was 1.74% CO (v/v) in $N_2$.

• Composites Research
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• v.36 no.5
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• pp.297-302
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• 2023

There are several methods for shaping foams, but the most commonly used methods involve the use of resin mixed with a foaming agent, which is then foamed under high temperature and pressure in the case of compression foaming, or foamed under high temperature without applying pressure in the case of atmospheric foaming. The polymers used for foaming require design and analysis of optimal foaming conditions in order to achieve foaming under ambient pressure. Environmentally friendly bio-based polymers face challenges when it comes to foaming on their own, which has led to ongoing research in blending them with resins capable of traditional foam production. This study investigates changes in the characteristics of bio-based polymer-EVA blend foams based on variations in the content of bio-based polymers and explores the optimal foaming conditions according to crosslinking. The correlation between foaming characteristics and mechanical properties of the foams was examined. Through this research, we gained insights into how the content of bio-based polymers affects the properties of foams containing bio-based polymers and identified differences between ambient pressure and high-pressure foaming processes. Additionally, the feasibility of commercializing bio-based polymer-EVA composite foams was confirmed.

• The Journal of the Convergence on Culture Technology
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• v.8 no.5
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• pp.749-754
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• 2022

High adhesion and water resistance of the skin surface are required for wearable and skin-attachable electronic patches in various medical applications. In this study, we report a stretchable electronic patch that mimics the drainable structure pattern of the hexagonal channels of frog's pads and the sucker of an octopus based on carbon-based conductive polymer composite materials. The hexagonal channel structure that mimics the pads of frogs drains water and improves adhesion through crack arresting effect, and the suction structure that mimics an octopus sucker shows high adhesion on wet surfaces. In addition, the high-adhesive electronic patch has excellent adhesion to various surfaces such as silicone wafer (max. 4.06 N/cm²) and skin replica surface (max. 1.84 N/cm²) in dry and wet conditions. The high skin-adhesive electronic patch made of a polymer composite material based on a polymer matrix and carbon particles can reliably detect electrocardiogram (ECG) in dry and humid environments. The proposed electronic patch presents potential applications for wearable and skin-attachable electronic devices for detecting various biosignals.

• Elastomers and Composites
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• v.56 no.3
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• pp.136-151
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• 2021

Biomass lignin, a waste produced during the paper and bio-ethanol production process, is a cheap material that is available in large quantities. Thus, the interest in the valorization of biomass lignin has been increasing in industrial and academic areas. Over the years, lignin has been predominantly burnt as fuel to run pulping plants. However, less than 2% of the available lignin has been utilized for producing specialty chemicals, such as dispersants, adhesives, surfactants, and other value-added products. The development of value-added lignin-derived co-products should help make second generation biorefineries and the paper industry more profitable by valorizing lignin. Another possible approach towards value-added applications is using lignin as a component in plastics. However, blending lignin with polymers is not simple because the polarity of lignin molecules results in strong self-interactions. Therefore, achieving in-depth insights on lignin characteristics and structure will help in accelerating the development of lignin-based products. Considering the multipurpose characteristics of lignin for producing value-added products, this review will shed light on the potential applications of lignin and lignin-based derivatives on polymeric composite production. Moreover, the challenges in lignin valorization will be addressed.

• KSBB Journal
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• v.26 no.5
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• pp.422-426
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• 2011

Alginate bead has been supplemented with various polymers to control permeability and to enhance mechanical strength. In this report, fibroin-reinforced alginate hydrogel was prepared, in which spatial localization of fibroin molecules was investigated. Confocal laser scanning microscopy revealed that fibroin molecules formed a fibrous network in the alginate-fibroin beads, which was expected to enhance mechanical strength as same as in many composite materials. Uniaxial compression test showed that fibroin-reinforced alginate beads had increased mechanical strength only after methanol treatment that caused ${\beta}$-sheet formation among fibroin molecules. Simultaneous curing and dialysis of alginate beads were carried out to remove excesscalcium but to retain fibroin in the dialysis chamber, which fabricated beads without internal fibrous fluorescent stains. Fibroin molecules were only found beneath the surface of the beads. The fibroin-diffused shell was further processed to form a thick wall after drying or was mobilizedto the centre of the bead by methanol treatment. Accordingly, the structure analyses provide processing methods of fibroin to form a wall or center clumps, which could be applied to design controlled delivery device.

• 한국태양에너지학회:학술대회논문집
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• 2012.03a
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• pp.410-413
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• 2012

A traditional fabrication method is very difficult to make small robots using embedded sensors, actuators and connectors. Fortunately, Shape Deposition Manufacturing can provide an alternative method, and it has many benefits. Firstly, the weight of robot can be lighter, as it can be consisted of composite materials. Secondly, SDM can make simple robot structures because this approach does not need to use connectors and fasteners. Lastly, SDM gives stiffness and flexibility at the specific parts. Therefore, in this paper, we present a design of 3 segment legs organized by SDM, what the SDM approach is, and compare SDM method with 3 segment prototype legs which uses a traditional approach and made by DGIST.