• Title/Summary/Keyword: Binding property

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XPS Investigation and Field Emission Property of the Ar Plasma Processed Carbon Nanotube Films

  • Lee, Sun-Woo;Lee, Boong-Joo;Oda, Tetsuji
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.2
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    • pp.52-56
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    • 2008
  • Carbon nanotube films were fabricated by the catalytic CVD method. Plasma processed time effects on the field emission property were studied. The atomic structure was observed by using X-ray photoelectron spectroscopy (XPS). The surface composition changes were observed on the plasma processed CNT films. The O1s/C1s signal ratio and the Fls/Cls signal ratio changed from 1.1 % to 24.65 % and from 0 % to 3.1 % with plasma process time, respectively. We could guess it from these results that the Ar plasma process could change the surface composition effectively. In the case of the original-CNT film, no carbon shift was observed. In the case of the Ar plasma processed CNT films, however the oxygen related carbon shifts were observed. This oxygen related carbon shift at higher binding energy implies the increment of amount of the oxygen. It's possible that the increment of these bonds between carbon and oxygen results in the improvement of field emission performance.

Study of the Relation between Quality and Image of the WholeGarment Knit Structured Patterns for High Sensible knit Design (1) - On mechanical property to armhole connecting part (Machi) - (고감성 니트디자인을 위한 무봉제 니트 조직패턴의 성능과 이미지간의 연구 (1) - 암홀 접속부(마치)의 역학적 특성을 중심으로 -)

  • Lee, Yoo-Jin;Choi, Won-Jung
    • Journal of Fashion Business
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    • v.16 no.1
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    • pp.52-68
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    • 2012
  • To achieve the aim of this study, 9 different types of samples were made to examine mechanical property according to structured pattern and type of Machi of pullover armhole of WholeGarment(seamless knitwear). With respect to samples, from which comparisons are made and anaylzed among basic characteristics of material, tensile strength & elongation and residual elongation due to repeated extension of armhole connecting part, the following conclusions could be obtained. It's revealed that the tensile strength of Machi part as being armhole connecting part of samples is more affected by Machi type than pattern structure. Of Machi types, it showed stronger tensile strength in the order of Normal(Normal Machi)< Machi_B(unilateral Machi)

Crystal Molecular Orbital Calculation of the Lanthanum Nickel Oxide by Means of the Micro-Soft Fortran (마이크로-소프트 포트란을 이용한 복합 산화물 결정의 분자 궤도함수 계산)

  • Koo, Hyun-Joo;Lee, Kwang-Soon;Ahn, Woon-Sun
    • Journal of the Korean Chemical Society
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    • v.39 no.9
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    • pp.685-691
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    • 1995
  • EHMACC and EHPC programs written in VAX version to calculate the tight-binding extended Huckel method is converted into the micro-soft fortran available to PC. The band calculation of LaNiO3 unit cell and extended ($2{\times}2{\times}1$) cell with perovskite structure is made by the PC/386 and PC/486. The calculation is also made for the DOS and the COOP. It is supposed that the electronic property of $LaNiO_3$ is semiconductor along to the ${\Gamma}{\rightarrow}H,\;H{\rightarrow}N,\;and\;N{\rightarrow}{\Gamma}(2D)$ direction with band gap about 0u.35 eV, while metal property in ${\Gamma}{\rightarrow}P\;and\;P{\rightarrow}N(3D)$ direction. The oxygen atom property in $LaNiO_3$ is more effectively affected by oxygen atom position than defect of nickel atom.

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Assessment of cell adhesion, cell surface hydrophobicity, autoaggregation, and lipopolysaccharide-binding properties of live and heat-killed Lactobacillus acidophilus CBT LA1 (락토바실러스 아시도필러스 CBT LA1 생균과 사균체의 세포부착력, 자가응집력, 소수성 상호작용력, LPS 결합력에 대한 평가)

  • Shin, Joo-Hyun;Lee, Joong-Su;Seo, Jae-Gu
    • Korean Journal of Microbiology
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    • v.51 no.3
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    • pp.241-248
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    • 2015
  • Although studies on probiotics have been performed mostly with viable microbes, the beneficial functions of dead or heat-killed form of probiotic strains have also been examined. In this study, live and heat-killed forms of Lactobacillus acidophilus CBT LA1 were investigated in vitro and in vivo to evaluate the properties necessary for gut barrier protection. Cell surface hydrophobicity (CSH), autoaggregation (AA), cell adhesion, and lipopolysaccharide (LPS)-binding properties were evaluated. In addition, the suppressive effect on LPS-induced interleukin (IL)-8 expression was investigated in HT-29 cells. To identify optimal conditions for CBT LA1 to adhere to HT-29 cells, CBT LA1 cells were heat-treated at 80, 85, 90, 95, 100, or $121^{\circ}C$ for 10 min; cells treated at $80^{\circ}C$ for 10 min showed the highest adhesion. Heat-killed bacteria at $80^{\circ}C$ showed higher levels of LPS-binding, CSH, AA, adhesion to HT-29, and suppression of IL-8 expression than did live CBT LA1. In vivo imaging was performed to evaluate the ability of live or heat-killed CBT LA1 to remove LPS from the intestine in a rat model of infection. At 16 h after infection, fluorescence from FITC-conjugated LPS had mostly disappeared from the intestine of the rats administered with live or heat-killed CBT LA1; the effect was greater with heat-killed CBT LA1 at $80^{\circ}C$. These results suggest that heat-killed CBT LA1 as well as its live form can be applied as a pharmabiotic for protection of the gut barrier.

Radial deformation and band-gap modulation of pressurized carbon nanotubes

  • Taira, Hisao;Shima, Hiroyuki;Umeno, Yoshitaka;Sato, Motohiro
    • Coupled systems mechanics
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    • v.2 no.2
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    • pp.147-157
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    • 2013
  • We numerically investigate the electronic band structure of carbon nanotubes (CNTs) under radial corrugation. Hydrostatic pressure application to CNTs leads to a circumferential wave-like deformation of their initially circular cross-sections, called radial corrugations. Tight-binding calculation was performed to determine the band gap energy as a function of the amplitude of the radial corrugation. We found that the band gap increased with increasing radial corrugation amplitude; then, the gap started to decline at a critical amplitude and finally vanished. This non-monotonic gap variation indicated the metal-semiconductor-metal transition of CNTs with increasing corrugation amplitude. Our results provide a better insight into the structure-property relation of CNTs, thus advancing the CNT-based device development.

The Origin of the Metal-insulator Transitions in Non-stoichiometric TlCu3-xS2 and α-BaCu2-xS2

  • Jung, Dong-woon;Choi, Hyun-Guk;Kim, Han-jin
    • Bulletin of the Korean Chemical Society
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    • v.27 no.3
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    • pp.363-367
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    • 2006
  • The structure-property relations of ternary copper chalcogenides, $TlCu_{3-x}S_2$ and $\alpha-BaCu_{2-x}S_2$ are examined. The density of states, band dispersions, and Fermi surfaces of these compounds are investigated to verify the reason of the metal-insulator transitions by extended Huckel tight-binding band calculations. The origin of the metalinsulator transitions of non-stoichiometric $TlCu_{3-x}S_2$ and $\alpha-BaCu_{2-x}S_2$ is thought to be the electronic instability induced by their Fermi surface nesting.

Electrochemical Immunosensor Using the Modification of an Amine-functionalized Indium Tin Oxide Electrode with Carboxylated Single-walled Carbon Nanotubes

  • Aziz, Md.Abdul;Yang, Hae-Sik
    • Bulletin of the Korean Chemical Society
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    • v.28 no.7
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    • pp.1171-1174
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    • 2007
  • We have developed an electrochemical immunosensor that combines the electrocatalytic property of carbon nanotube and the low background current of indium tin oxide (ITO) electrode. A partial monolayer of carboxylated single-walled carbon nanotube (CCNT) is covalently formed on an ITO electrode modified with amine-terminated phosphonic acid. Nonspecifically adsorbed avidin on the hydrophobic sidewalls of CCNT is used to immobilize biotinylated antibody and to reduce the nonspecific binding to CCNT. The biotinylated antimouse IgG bound on avidin and the antimouse IgG conjugated with alkaline phosphatase (ALP) sandwiches a target mouse IgG. ALP catalyzes the conversion of p-aminophenyl phosphate monohydrate into p-aminophenol, which is electrocatalytically oxidized to p-quinone imine on CCNT surface. Moderate electrocatalytic electrode obtained with the combination of CCNT and ITO allows low detection limit (0.1 ng/ mL).

A Study on the Early-Age Strength Property of Concrete Using Liquid Admixture (액상형 조강제를 사용한 콘크리트의 초기강도 특성에 관한 연구)

  • Song, Tae-Hyeob;Lee, Sea-Hyun;Ryu, Deug-Hyun;Park, Cho-Bum
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.469-472
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    • 2006
  • Amount used of admixture fare is increasing for concrete economic efficiency and ability security. Security of economic efficiency and ability can expect by use of this admixture fare but is displaying a lot of problems on early age strength hold by hydrate delay relatively. Specially, in the case of construction site, concrete strength can speak that interrelation is high with mold removal of forms time. Therefore, is economical and need examination of plan that can secure robber within 3 days using admixture fare such as fly ash and blast furnace slage differential speech to secure function. In this study, adding liquid admixture within 1% of a binding agent quantity to examine these problem with physical characteristic after hardening ago specially, strength change at standard and air dry curing of observed change in priority. Air dried and water curing total strength enhancement effects appeared by thing which is in case of add test result liquid admixture by below 1% and strength deputy by passage of age could know is not big.

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Autonomous, Scalable, and Resilient Overlay Infrastructure

  • Shami, Khaldoon;Magoni, Damien;Lorenz, Pascal
    • Journal of Communications and Networks
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    • v.8 no.4
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    • pp.378-390
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    • 2006
  • Many distributed applications build overlays on top of the Internet. Several unsolved issues at the network layer can explain this trend to implement network services such as multicast, mobility, and security at the application layer. On one hand, overlays creating basic topologies are usually limited in flexibility and scalability. On the other hand, overlays creating complex topologies require some form of application level addressing, routing, and naming mechanisms. Our aim is to design an efficient and robust addressing, routing, and naming infrastructure for these complex overlays. Our only assumption is that they are deployed over the Internet topology. Applications that use our middleware will be relieved from managing their own overlay topologies. Our infrastructure is based on the separation of the naming and the addressing planes and provides a convergence plane for the current heterogeneous Internet environment. To implement this property, we have designed a scalable distributed k-resilient name to address binding system. This paper describes the design of our overlay infrastructure and presents performance results concerning its routing scalability, its path inflation efficiency and its resilience to network dynamics.

Ab initio calculation of half-metallic ferrocene-based nanowire

  • Kim, Seongmin;Park, Changhwi
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.425-429
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    • 2014
  • Half-metallic nanostructure is highly applicable in the field of Spintronics and electronic device technology. We examine the electronic properties of a ferrocene-based nanowire as a possible candidate for a half-metallic nanostructure using VASP and SIESTA. Ferrocene-based nanowire shows high stability in both binding energy simulation and molecular dynamics (MD) simulation. The density of states (DOS) and the projected DOS of the ferrocene-based nanowire indicate that one-dimensional clustering of ferrocene molecules can be explained because of p-d orbital hybridization between iron and carbon. Half-metallic property and energy dispersion at the Fermi level due to one-dimensional structure is also observed from the DOS results.

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