• 제목/요약/키워드: Benzotriazole

검색결과 57건 처리시간 0.026초

합성절연유의 전기적 특성에 미치는 BTA의 영향 (The Influence of the BTA on Electrical Properties of Synthetic Fluids)

  • 신종열;신현택;홍진웅
    • 한국전기전자재료학회논문지
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    • 제11권2호
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    • pp.162-166
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    • 1998
  • Synthetic fluid, class 7 group 2, as an insulating and cooling material is selected as. specimen, arid it is studied for the physical and electrical properties. Also, Benzotriazole(following as BT A) known as a suppressant of streaming electrification is added to it, and the change of physical and electrical properties by addition of BT A is investigated. From the spectrum of FT-IR, it is confirmed that the absorption peak in wavenumbers $3400{\sim}3450[cm^{-1}]$ is small or disappears when BTA is added. AC breakdown strength and volume resistivity of each specimen are investigated. It is considered that the effective content of BTA is about 10[ppm] for the suppression of electrification in this experiment.

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유동대전 억제제가 첨가된 변압기유의 전기전도 특성 (The Electrical Conduction Characteristics of Transformer Oils added the Anti-static Agent for Streaming Electrification)

  • 이용우;이태훈;오세영;이종필;차광훈;홍진웅
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1213-1215
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    • 1997
  • In order to investigate the electrical characteristics due to the BTA(Benzotriazole) additive in the transformer, the electrical characteristics of the transformer oils contained benzotriazole as an anti-static agent for streaming electrification is studied by measuring the electric conduction. As a result of the electrical conduction characteristics, it is confirmed that the conduction current of virgin specimen is more higher than that of specimen contained the BT A 10[ppm] over 35[$^{\circ}C$], but that of specimen contained the BT A 10[ppm] over 50[$^{\circ}C$] is increased.

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Synthesis and Biological Activities of Novel Arylazopyrazolones Substituted with Thiazolyhydrazone

  • Shah, Purvesh J.
    • 대한화학회지
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    • 제58권1호
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    • pp.57-61
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    • 2014
  • The 4-(1H)-benzotriazoyl methyl amino benzoate 3 was prepared by Mannich reaction of benzotriazole 1, ethyl-paminobenzoate 2 and formaldehyde. The prepared compound 3 then react with hydrazine hydrate results in the 4-(1H)-benzotriazoyl methyl amino benzoyl hydrazide 4. This compound on condensation with pre-prepared different ethyl 2-(2-(4-(4-substituted phenyl)thiazol-2-yl)hydrazono)-3-oxobutanoates 6a-d, furnished 1-(4-((1H-benzo[d] [1,2,3] triazol-1-yl)methyl amino) benzoyl)-4-(2-(4-(4-substituted phenyl)thiazol-2-yl) hydrazono)-3-methyl-1H-pyrazol-5(4H)-one 7a-d. All the compounds 7a-d was characterized by spectral studies. The compounds showed significant antimicrobial activity against various bacteria and fungi.

열화된 광유와 식물성절연유에서 온도, 벤조트리아졸의 유동대전 영향 (Influence of Temperature and Benzotriazole on the Flow Electrification by aging Mineral, Vegetable Oil)

  • 최순호;정중일;허창수
    • 전기학회논문지
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    • 제60권2호
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    • pp.338-343
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    • 2011
  • In this paper, the FT-IR, conductivity and flow electrification phenomena of Vegetable oils were discussed. Vegetable oil has high flash point and eco-friendly properties compared to conventional mineral oil. Accelerated aging transformer oil samples produced in the oven at 140[$^{\circ}C$] for 500 hours, 1000 hours, 1500 hours, 2000 hours. Serial device to measure the flow electrification phenomena was designed and fabricated. Pico ammeter and the Labview data measurements were utilized. The effects of Temperature and antistatic agent on fluid flow electrification were investigated. Both Mineral and vegetable oil showed similar trends for temperature change. The polarity reversal occurred in mineral oil with antistatic agent above 10 ~ 30[ppm] and in vegetable oil with antistatic agent above 5[ppm].

내식 방지용 고분자 나노복합재료에 관한 연구 (A Study on the Polymer Nanocomposite for Corrosion Protection)

  • 유성구;박세형;박찬섭;차종현;서길수
    • 공업화학
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    • 제16권2호
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    • pp.212-216
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    • 2005
  • 아연도금 강판의 부식을 방지하기 위하여, 방청제로서 사용하고 있는 벤조트리아졸을 유기화제로 사용하여 이를 Na-montmorillonite (Na-MMT)에 삽입시켰다. 이것을 XRD로 관찰한 결과 벤조트리아졸의 삽입으로 인하여 MMT의 층간 거리가 증가하였음을 보여주고 있다. 그리고 코팅액으로 사용하기 위하여 벤조트리아졸이 삽입된 MMT를 이용하여 수용성 poly(ethylene-co-acrylic acid) (PEA) 나노복합재료를 제조하였다. 나노복합재료는 PEA 매트릭스에 실리케이트가 단일층으로 잘분산되어 있는 박리형 나노복합재료임을 보여주고 있다. 이것을 인용하여 아연도금강판에 코팅하여 염소분무 시험한 결과 금속의 내식성을 현저히 증가시켰다. 이러한 결과는 PEA 매트릭스에 균일하게 분산되어 있는 실리케이트 층에 의한 산소투과도 감소와 방청제의 효과에 의한 것이다.

Cu CMP에서의 연마 균일성에 관한 기계적 해석 (Mechanical Analysis on Uniformity in Copper Chemical Mechanical Planarization)

  • 이현섭;박범영;정해도;김형재
    • 한국전기전자재료학회논문지
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    • 제20권1호
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    • pp.74-79
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    • 2007
  • Most studies on copper Chemical Mechanical Planarization (CMP) have focused on material removal and its mechanisms. Although many studies have been conducted on the mechanism of Cu CMP, a study on uniformity in Cu CMP is still unknown. Since the aim of CMP is global and local planarization, the approach to various factors related to uniformity in Cu CMP is essential to elucidate the Cu CMP mechanism as well. The main purpose of the experiment reported here was to investigate and mechanically analyze the roles of slurry components in the formation of the uniformity in Cu CMP. In this paper, Cu CMP was performed using citric acid($C_{6}H_{8}O_{7}$), hydrogen peroxide($H_{2}O_{2}$), colloidal silica, and benzotriazole($BTA,\;C_{6}H_{4}N_{3}H$) as a complexing agent, an oxidizer, an abrasive, and a corrosion inhibitor, respectively. All the results of this study showed that within-wafer non-uniformity(WIWNU) of Cu CMP could be controlled by the contents of slurry components.

Cu CMP중 BTA에 의한 Particle의 흡착에 관한 연구 (Effect of Corrosion inhibitor, Benzotriazole (BTA), on Particle Adhesion in Cu CMP)

  • 송재훈;홍의관;김태곤;박진구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.366-367
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    • 2005
  • The effect of benzotriazole (BTA) on the adhesion force of silica and pad particle on Cu/TEOS wafer surfaces was investigated with and without the addition of BTA. Cu-BTA had the isoelectric point (IEP) at around pH 4$\sim$8. Pad particles were more positive zeta potentials than silica. The adhesion force initially decreased of silica and pad particle on Cu surfaces when BTA was added. However, the more BTA was added, the more adhesion force gradually increased with the increase of BTA concentrations. Then the adhesion force of pad particle was higher than silica. And TEOS didn't resulted increasing adhesion force like Cu when BTA was added in DI water.

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스프링클러 구리배관의 공식 파손 억제 (Inhibition of Pitting Corrosion Failure of Copper Tubes in Wet Sprinkler Systems)

  • 서상희;서영준;이종혁;권혁상
    • Corrosion Science and Technology
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    • 제19권2호
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    • pp.89-99
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    • 2020
  • The inhibition of pitting corrosion failure of copper sprinkler tubes in wet sprinkler systems was studied. First, an apparatus and technology for removing air in the sprinkler tubes by vacuum pumping and then filling the tubes with water were developed. Using this apparatus and technology, three methods for inhibiting the pitting corrosion of the copper sprinkler tubes installed in several apartment complexes were tested. The first one was filling the sprinkler tubes with water bubbled by high-pressure nitrogen gas to reduce the dissolved oxygen concentration to lower than 2 ppm. In the second method, the dissolved oxygen concentration of water was further reduced to lower than 0.01 ppm by sodium sulfite. In the third method, the sprinkler tubes were filled with benzotriazole (BTAH) dissolved in water. The third method was the most effective, reducing the failure frequency of the sprinkler tubes due to pitting corrosion by more than 80%. X-ray photoelectron spectroscopy analyses confirmed that a Cu-BTA layer was well coated on the inside surface of the corrosion pit, protecting it from corrosion. A potentiodynamic polarization test showed that BTAH should be very effective in reducing the corrosion rate of copper in the acidic environment of the corrosion pit.