• Proceedings of the KIEE Conference
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• 2005.07b
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• pp.1534-1536
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• 2005

A DC-DC converter is being widely used for various household appliances and for industry applications. The DC-DC converter is powered from single battery, and the voltage is varied according to the purpose. In the vehicle, various accessories whose electric power is different are being used. Thus, plural number of DC-DC converter should be provided, so these situations bring complicated circuits, and accordingly, higher cost. Under such backgrounds, in this paper, we propose a novel buck-boost chopper circuit with simply configuration which can supply to two or more different output loads. The propose chewer circuit can control output voltages by controlling duty ratio by using typically two switching devices, which is composed by single boost-switch and single buck-switch. The output voltage can be controlled widely. A few modified circuits developed from the fundamental circuit are represented including the general multi-load circuit. And all this merits and appropriateness was proved by computer simulation and experience.

• Membrane Journal
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• v.20 no.3
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• pp.259-266
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• 2010

Porous poly(propylene) supported gel polymer electrolytes (GPE) were synthesized by thermal polymerization of DEGDMA [Di(ethylene glycol) dimethacrylate] in electrolyte solutions (1 M solution of $LiPF_6$ in EC/DEC 1 : 1 mixture) at $70^{\circ}C$. AC impedance spectroscopy and cyclic voltammetry were used to evaluate its ionic conductivity and electrochemical stability window of the GPE membranes. Lithium ion battery (LIB) cells were also fabricated with $LiNi_{0.8}Co_{0.2}O_2$/graphite and GPE membranes via thermal polymerization process. Through the thermal polymerization, self sustaining GPE membranes with sufficient ionic conductivities (over $10^{-3}\;S/cm$) and electrochemical stabilities. The LIB cell with 5% monomer showed the best rate-capability and cycleability.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.31 no.10C
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• pp.1011-1022
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• 2006

WSN(Wireless Sensor Network) performs to detect and collect environmental information for one purpose. The WSN is composed of a sink node and several sensor nodes and has a constraint in an aspect of energy consumption caused by limited battery resource. So many required mechanisms in WSN should consider the remaining energy condition. To deploy WSN, tile collected information is required to protect from an adversary over the network in many cases. The security mechanism should be provided for collecting the information over the network. we propose asynchronized key management considering energy efficiency over WSN. The proposed key management is focused on independence and difference of the keys used to deliver the information over several routes over the network, so disclosure of any key does not results in exposure of total key information over the overall WSN. Also, we use hash function to update key information for energy efficiency Periodically. We define the insecurity for requested security Properties and Proof that the security properties are guaranteed. Also, we evaluate and analyze the energy efficiency for the proposed mechanism.

• Journal of the Korean Electrochemical Society
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• v.19 no.4
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• pp.123-128
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• 2016

In this study, poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP)-based gel polymer electrolyte incorporating nano-size $Al_2O_3$ ceramic particle was prepared by electrospinning. The gel polymer electrolyte (GPE) incorporated with $Al_2O_3$ ceramic particle showed higher ionic conductivity of $9.5{\times}10^{-2}Scm^{-1}$ than pure PVdF-HFP GPE without ceramic particle and improved the electrochemical stability up to 5.2 V. The GPEs were assembled with $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ (NMC) cathode for electrochemical test. The GPE batteries at 0.1 C-rate delivered $168.2mAh\;g^{-1}$ for pure GPE and $189.6mAh\;g^{-1}$ for hybrid GPE, respectively. Therefore, the incorporation of high dielectric constant ceramic particle will be good strategy to enhance the stability and electrochemical properties of lithium ion gel polymer batteries.

• Applied Chemistry for Engineering
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• v.33 no.5
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• pp.459-465
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• 2022

A pitch coating method was proposed for the purpose of improving the electrochemical properties of natural graphite. The synthesis conditions of pitch coating were optimized via measuring electrochemical properties of pitch-coated graphite anodes. As the synthesis temperature increased, the thermal stability was improved in addition to an increase in the softening point and residual carbon weight. However, the synthesis temperature of 430 ℃ resulted in the synthesis of a large amount of NI (NMP Insoluble) due to excessive condensation reaction. As the surface uniformity and coating thickness increased due to high thermal stability, the initial coulombic efficiency and rate capability of the pitch-coated graphite were improved. However, the graphite coated with the pitch containing excessive NI showed lower electrochemical properties than the uncoated graphite. NI had low dispersibility and formed spheres after heat treatment, so it formed the heterogeneous and thicker SEI layer. The optimum conditions for forming a uniform surface and an appropriate coating layer were investigated.

• Journal of Korean Society for Geospatial Information Science
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• v.23 no.3
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• pp.69-75
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• 2015

Road facilities for safe driving were designed for drivers to distinguish them during day and night, but they cannot play their role when the weather becomes worse. Recently, the road facilities have been designed by using electric and electronic technology so that they can be displayed well at a long distance, but they should be replaced very often due to their frequent breakdown. So, there are many problems in traffic calming and maintenance. In this study, to solve the above problems, semi-permanent LED beacon light was installed in the area where traffic accident are frequent, and monitoring system was developed so that the LED beacon light can be maintenanced by connecting with system. For the above installation and development, system was based on window operating system and it was developed for worker to operate it by using P.C. through connecting with wireless local area network. The result of this study led to analyzing state information on the battery of field-installed LED beacon light in real time, and manegement to effectively by predicting their life cycle.

• The KIPS Transactions:PartC
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• v.13C no.5 s.108
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• pp.541-548
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• 2006

Sensor network is a network for realizing the ubiquitous computing circumstances, which aggregates data by means of observation or detection deployed at the inaccessible places with the capacities of sensing and communication. To realize this circumstance, data which sensor nodes gathered from sensor networks are delivered to users, in which it is required to encrypt the data for the guarantee of secure communications. Therefore, it is needed to design key management scheme for encoding appropriate to the sensor nodes which feature continual data transfer, limited capacity of computation and storage and battery usage. We propose a key management scheme which is appropriate to sensor networks organizing hierarchical architecture. Because sensor nodes send data to their parent node, we can reduce routing energy. We assume that sensor nodes have different security levels by their levels in hierarchy. Our key management scheme provides different key establishment protocols according to the security levels of the sensor nodes. We reduce the number of sensor nodes which share the same key for encryption so that we reduce the damage by key exposure. Also, we propose key update protocols which take different terms for each level to update established keys efficiently for secure data encoding.

• Environmental Engineering Research
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• v.25 no.1
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• pp.88-95
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• 2020

An investigation of rare metals recovery from LiNi_xCo_yMn_zO₂ cathode material of the end-of-life lithium-ion batteries is presented. To determine the influence of reductant on the leach process, the cathode material (containing Li 7.6%, Co 20.4%, Mn 19.4%, and Ni 19.3%) was leached in H₂SO₄ solutions either with or without H₂O₂. The optimal process parameters with respect to acid concentration, addition dosage of H₂O₂, temperature, and the leaching time were found to be 2.0 M H₂SO₄, 4 vol.% H₂O₂, 70℃, and 150 min, respectively. The yield of metal values in the leach liquor was > 99%. The leach liquor was subsequently treated by precipitation techniques to recover nickel as Ni(C₄H₇N₂O₂)₂ and lithium as Li₂CO₃ with stoichiometric ratios of 2:1 and 1.2:1 of dimethylglyoxime:Ni and Na₂CO₃:Li, respectively. Cobalt was recovered by solvent extraction following a 3-stage process using Na-Cyanex 272 at pH_eq ~5.0 with an organic-to-aqueous phase ratio (O/A) of 2/3. The loaded organic phase was stripped with 2.0 M H₂SO₄ at an O/A ratio of 8/1 to yield a solution of 114 g/L CoSO₄; finally recovered CoSO₄.xH₂O by crystallization. The process economics were analyzed and found to be viable with a margin of $476 per ton of the cathode material.

• Journal of the Korean Electrochemical Society
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• v.17 no.1
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• pp.49-56
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• 2014

As an electrolyte additive, the effects of lithium bis(oxalate)borate (LiBOB) on the electrochemical properties of a carbon-coated silicon monoxide (C-coated SiO) negative electrode are investigated. The used electrolyte is 1.3M $LiPF_6$ that is dissolved in ethylene carbonate (EC), fluoroethylene carbonate (FEC), and diethyl carbonate (DEC) (5:25:70 v/v/v) with or without 0.5 wt. % LiBOB. In the LiBOB-free electrolyte, the film resistance is not so high in the initial period of cycling that lithiation is facilitated to generate the crystalline $Li_{15}Si_4$ phase. Due to repeated volume change that is caused by such a deep charge/discharge, cracks form in the active material to cause a resistance increase, which eventually leads to capacity fading. When LiBOB is added into the electrolyte, however, more resistive surface film is generated by decomposition of LiBOB in the initial period. The crystalline $Li_{15}Si_4$ phase does not form, such that the volume change and crack formation are greatly mitigated. Consequently, the C-coated SiO electrode exhibits a better cycle performance in the later cycles. At an elevated temperature ($45^{\circ}C$), wherein the effect of film resistance is less critical, the alloy ($Li_{15}Si_4$ phase) formation is comparable for the LiBOB-free and added cell to give a similar cycle performance.

• Resources Recycling
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• v.28 no.5
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• pp.51-59
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• 2019

This study focused on the synthesis of the nickel hydroxide using ammonium sulfate in leaching solution from waste nickel-cadmium batteries. The effect of pH, temperature and the input amount of ammonium sulfate in leaching solution was investigated. The ammonium nickel sulfate with high purity was obtained in acidic leaching solution and the solution temperature of $60^{\circ}C$. The suitable molar ratio of the input amount of ammonium sulfate to nickel in solution is 2:1. The impurity about 1.4 at.% of Cd was included in the nickel hydroxide precipitates when ammonium nickel sulfate was used. At the process using sodium sulfide which precipitates the cadmium in solution, nickel and iron compounds were precipitated together.