• Korean Journal of Materials Research
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• v.19 no.10
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• pp.517-521
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• 2009

Si-C composite with hollow spherical structure was synthesized using ultrasonic treatment of organosilica powder formed by hydrolysis of phenyltrimethoxysilane. The prepared powder was pyrolyzed at various temperatures ranging from 900 to 1300 $^{\circ}C$ under nitrogen atmosphere to obtain optimum conditions for Li-ion battery anode materials with high capacity and cyclability. The XRD and elemental analysis results show that the pyrolyzed Si/C composite at 1100 $^{\circ}C$ has low oxygen and nitrogen levels, which is desirable for increasing the electrochemical capacity and reducing the irreversible capacity of the first discharge. The solid Si-C composite electrode shows a first charge capacity of $\sim$500 mAhg$^{-1}$ and a capacity fade within 30 cycles of 0.93% per cycle. On the other hand, the electrochemical performance of the hollow Si-C composite electrode exhibits a reversible charge capacity of $\sim$540 mAhg$^{-1}$ with an excellent capacity retention of capacity loss 0.43% per cycle up to 30 cycles. The improved electrochemical properties are attributed to facile diffusion of Li ions into the hollow shell with nanoscale thickness. In addition, the empty core space provides a buffer zone to relieve the mechanical stresses incurred during Li insertion.

• Proceedings of the KIPE Conference
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• 2003.07a
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• pp.189-192
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• 2003

Electrical power in satellite system should persistently satisfy specified power requirement even though that happen the failure of solar array string or battery cell during the mission operation. In this study, the solar array and battery of GEO Communication Satellite with 3kW capacity are designed, and energy balance analysis according to power operation mode are performed to meet specified power capacity at the transfer orbit

• Proceedings of the KSR Conference
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• 2005.05a
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• pp.320-325
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• 2005

Power of fuel cell tram is supplied by only fuel cell system or hybrid system of fuel cell and battery/super capacity. Fuel cell is operated by hydrogen, which is fed directly from hydrogen tank or by reforming gasoline or methanol into hydrogen. Power system is preferred with hybrid of fuel cell and battery/super capacity since it improves total energy efficiency through interaction of hybrid components and restores energy regenerated by braking. Also, power supply system by fuel cell hybrid should be designed to output optimum energy efficiency depending on driving mode of fuel cell tram.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.317-323
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• 2006

Electric conductive material should be homogeneously mixed with sulfur in sulfur electrode fabrication of lithium/sulfur battery, because sulfur is electric insulator. In this paper electrochemical properties of Li/S battery was studied with various compositions of sulfur electrodes. When content of sulfur changed from 40 wt.% to 80 wt.%, the 60 wt.% sulfur electrode showed the maximum capacity of 1489 mAh/g-sulfur. Electrochemical properties of Li/S battery using 60 wt.% sulfur was also investigated with various carbon contents. The discharge capacity changed as a function of carbon contents. The optimum composition was 25 wt.% carbon for 60 wt.% sulfur electrode.

• Bulletin of the Korean Chemical Society
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• v.30 no.7
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• pp.1607-1610
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• 2009

The carbon-coated Si/Cu powder has been prepared by mechanical ball milling and hydrocarbon gas decomposition methods. The phase of Si/Cu powder was analyzed using X-ray diffraction (XRD), dispersive Raman spectroscopy, electron probe microanalysis (EPMA) and transmission electron microscope (TEM). The carbon-coated Si/Cu powders were used as anode active material for lithium-ion batteries. Their electrochemical properties were investigated by charge/discharge test using commercial LiCo$O_2$ cathode and lithium foil electrode, respectively. The surface phase of Si/Cu powders consisted of carbon phase like the carbon nanotubes (CNTs) with a spacing layer of 0.35 nm. The carbon-coated Si/Cu/graphite composite anode exhibited a higher capacity than commercial graphite anode. However, the cyclic efficiency and the capacity retention of the composite anode were lower compared with graphite anode as cycling proceeds. This effect may be attributed to some mass limitations in LiCo$O_2$ cathode materials during the cycling.

• Journal of IKEEE
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• v.18 no.1
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• pp.96-105
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• 2014

This paper proposes a battery lifetime enhancement method based on the nonlinear discharge charisteristics called recovery effect. In general, the stored energy in a battery is considered in the prediction of battery lifetime. However, due to the chemical reaction in a battery, more energy can be drawn from a battery when it is not continuously but intermittently discharged, which is called recovery effect. In the proposed method, several battery cells are alternately discharged, and some battery cells rest while maintaining the system power supply. This makes recovery effect of battery cells, which extends battery lifetime. In the experiment, battery lifetime increases about 7% in the alternating discharge of two battery cells, when compared with conventional parallel discharge.

• Smart Media Journal
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• v.12 no.11
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• pp.103-112
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• 2023

Recently, the need to prevent battery fires and accidents has emerged, as the use of lithium-ion batteries has increased. In order to prevent accidents, it is necessary to predict the state of health (SOH) and check the replacement timing of the battery with a lot of degradation. This paper proposes a model for predicting the degradation state of a battery by using four battery degradation indicators: maximum voltage arrival time, current change time, maximum temperature arrival time, and incremental capacity (IC) that can be obtained in the battery charging process, and LSTM using an attention mechanism. The performance of the proposed model was measured using the NASA battery data set, and the predictive performance was improved compared to that of the general LSTM model, especially in the SOH 90-70% section, which is close to the battery replacement cycle.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.6
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• pp.422-426
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• 2018

The lithium-ion battery pack of an electric vehicle (EV) deserves to be considered for an alternative use within smart-grid infrastructure. Despite the long automotive service life, EV batteries retain over 70~80% of their initial capacity. These battery packs must be managed for their reliability and safety. Therefore, a battery management system (BMS) should use specific algorithms to measure and estimate the status of the battery. Most importantly, the BMS of a grid-connected energy storage system (ESS) must ensure that the lithium-ion battery does not catch fire or explode due to an internal short from uncontrolled dendrite growth. In other words, the BMS of a lithium-ion battery pack should be capable of detecting the battery's status based on the electrochemical reaction continuously until the end of the battery's lifespan. In this paper, we propose a new protection algorithm for a dendritic lithium battery. The proposed algorithm has applied a parameter from battery pack aging results and has control power managing.

• The Transactions of the Korean Institute of Electrical Engineers D
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• v.49 no.8
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• pp.432-441
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• 2000

It is difficult to analyze the charging characteristics of the lead-acid battery, because of the influences by various non-linear and time-variant parameters. In this study, the charging characteristics of high capacity industrial lead-acid battery 630 Ah was investigated through experiments with respect to the variations of temperature and the aged state of battery during the charging process. The database of those characteristics is established from the results of experiments, and the fuzzy logic charging algorithm is suggested using them. The results of experiment shows that the industrial lead-acid batteries can be always fully charged within the saved charging time by the proposed charging control algorithm adapting to the variations of charging condition. This new charging concept will be useful for developing the advanced battery charger improving the efficiency of storing electricity.

• The Transactions of the Korean Institute of Power Electronics
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• v.23 no.2
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• pp.106-111
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• 2018

In this work, we propose techniques for estimating the SOC of Li-air battery. First, we describe and explain the operation principle of the Li-air battery. Energy density of the Li-air battery was compared with that of the Li-ion battery. The capacity and impedance value of the fully discharged voltage is analyzed, and the OCV value for SOC estimation is measured through the electrochemical characterization of the Li-air battery. Estimation value is obtained by SOC modeling through extended Kaman filter and is compared with the measurement value from the Coulomb counting method. Moreover, the performance of SOC estimation circuit is evaluated.