• Journal of Electrochemical Science and Technology
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• 제1권1호
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• pp.39-44
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• 2010

1.5 V and 3.0 V-class film-type primary batteries were designed for radio frequency identification (RFID) tag. Efficient fabrication processes such as screen-printings of conducting layer ($25{\mu}m$), active material layer ($40{\mu}m$ for anode and $80{\mu}m$ for cathode), and electrolyte/separator/electrolyte layer ($100{\mu}m$), were adopted to give better performances of the 1.5 V-class film-type Leclanch$\acute{e}$ primary battery for battery-assisted passive (BAP) RFID tag. Lithium (Li) metal is used as an anode material in a 3.0 V-class film-type $MnO_2||$Li primary battery to increase the operating voltage and discharge capacity for application to active sensor tags of a radio frequency identification system. The fabricated 3.0 V-class film-type Li primary battery passes several safety tests and achieves a discharge capacity of more than 9 mAh $cm^{-2}$.

• 전력전자학회논문지
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• 제2권1호
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• pp.33-38
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• 1997

전기자동차용 배터리 충전회로에는 일반적으로 다양한 전력용 반도체 스위칭 소자들이 사용되고 있다. 따라서 사용소자의 비선형성에 기인하는 고조파 발생과 큰 피크전류, 낮은 역률 등으로 부근에 있는 전력시스템에 과도기전류나 파형 왜곡 현상을 발생한다. 그리하여 최근에는 기존의 정류회로에서 무시되었던 역율제어, 선 전류의 피크치 억제, 고조파 발생문제 등이 보다 중요하게 되었다. 따라서 본 연구에서는 기존의 문제점들을 해결하기 위해 전압 상승특성을 개선하고 역율이 0.97이상인 고역율 배터리 충전기용 콘버어터 회로를 제안하고자 한다. 제안된 시스템은 정류된 직류전압을 고주파 인버어터에서 교류 공진파로 변환하고, 고주파 트랜스를 통과한 전압을 다시 정류하여 직류전압으로 변환한다. 특히, 이러한 콘버어터의 사용효과는 역율제어에 의해서 크게 개선될 수 있는데, 납축전지를 이용한 실험을 통해 그 타당성을 입증하고자 한다.

• 해양환경안전학회지
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• 제27권6호
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• pp.856-866
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• 2021

대기오염물질 감축에 대한 국제적인 인식이 높아짐에 따라 친환경 선박에 대한 수요가 증가하고 있어 각국에서 전기추진선박 개발을 활발하게 수행하고 있다. 현재 전기추진선박에 대해서는 주로 전기추진시스템 및 전동기 연구를 주로 수행하고 있으며, 선박 관점에서 전기추진시스템 및 배터리의 탑재를 고려한 국내 연안 차도선 개념설계 연구는 수행된 바가 없다. 본 연구에서는 배터리 차량 기반의 이동식 전원공급시스템을 주전원으로 하는 순수전기추진차도선의 개념설계 과정에서의 주요 고려사항에 대하여 검토하였다. 100척 이상의 국내 연안차도선의 제원을 분석하여, 요구사항 만족을 위한 선박의 주요제원 선정과 이동식 배터리 차량 탑재를 고려한 비손상, 손상 복원성능 검토를 수행하였고, 개념설계 과정에서 발생하는 문제의 원인분석을 통해 해결방안을 모색하였다.

• Journal of Electrochemical Science and Technology
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• 제13권1호
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• pp.78-89
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• 2022

ANODE-free Li-metal batteries (AFLMBs) operating with Li of cathode material have attracted enormous attention due to their exceptional energy density originating from anode-free structure in the confined cell volume. However, uncontrolled dendritic growth of lithium on a copper current collector can limit its practical application as it causes fatal issues for stable cycling such as dead Li formation, unstable solid electrolyte interphase, electrolyte exhaustion, and internal short-circuit. To overcome this limitation, here, we report a novel dual-salt electrolyte comprising of 0.2 M LiPF₆ + 3.8 M lithium bis(fluorosulfonyl)imide in a carbonate/ester co-solvent with 5 wt% fluoroethylene carbonate, 2 wt% vinylene carbonate, and 0.2 wt% LiNO₃ additives. Because the dual-salt electrolyte facilitates uniform/dense Li deposition on the current collector and can form robust/ionic conductive LiF-based SEI layer on the deposited Li, a Li/Li symmetrical cell exhibits improved cycling performance and low polarization for over 200 h operation. Furthermore, the anode-free LiFePO₄/Cu cells in the carbonate electrolyte shows significantly enhanced cycling stability compared to the counterparts consisting of different salt ratios. This study shows an importance of electrolyte design guiding uniform Li deposition and forming stable SEI layer for AFLMBs.

• 한국산업정보학회논문지
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• 제29권2호
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• pp.153-167
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• 2024

DMAIC는 배터리 제조 관련 엔지니어들에게 가장 친숙한 문제해결방법론이나, 배터리 생산시스템 개발자의 다양한 과제에 대한 무분별한 적용으로 과제 지연, 성과 미흡 및 부분 최적화 등 지속적인 문제 발생이 되고 있는 실정이다. 배터리 생산시스템 개발자 과제를 효과적으로 대응할 수 있는"DMAIC 방법론의 최적화 모델"을 확보하고자 3단계 연구모형을 활용하여 생산시스템 개발자 과제 방법론의 요구특성을 도출하고, DMAIC의 적합성을 분석하여 부족한 부분을 보완하여 최적화 모델링을 실시하였다. 본 연구 결과물인 "시스템 구조적 7단계 방법론"을 활용하여 개발자 과제에 적용해 봄으로서 DMAIC 방법론을 보다 적합성을 높일 수 있다는 점을 확인하였다. 하나의 방법론으로 보다 학습이 용이하고 다양한 산업별 특성에 맞춰 차별화 운영을 할 수 있도록 하여 향후 다양한 산업분야에 적용 가능할 것으로 기대된다.

• 한국전기전자재료학회논문지
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• 제35권6호
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• pp.631-638
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• 2022

Microgrid, which enables the production and consumption of electricity to be done independently on a small scale, has been studied on one of the solutions of reinforcement for flexibility of electronic system. This study examined the application effect of new microgrid by applying hybrid battery in electric power storage device. We designed the system to highlight the advantage of each battery and complement the disadvantage by using hybrid system with Lithium-ion battery and interval Redox flow battery. It runs with lithium-ion battery during the initial startup while the Redox flow battery operates for a long time at the end of excessive period, and it enables a discharge of Lithium-ion and Redox flow battery at the same time when the load has a large output. We chose Maldives as a subject of this study for organizing and optimizing independent microgrid. Maldives is the country to accomplish 100% domestic electricity in South Asia, but the whole electric power is supplied through diesel generation imported fossil fuel. We organized and optimized microgrid for energy independence on Malahini island to solve Maldives energy cost problem and global energy environment matters. We analyzed the daily power supply and accumulated the power supply from September 18, 2018~February 11, 2019. The accumulated power supply was about 120.4 MWh and the daily power supply was about 800~1000 kWh. Based on the collected information, we divided the cases into three models which are only diesel generator, solar generator as well as diesel generator, and solar+ESS+diesel generator. We analyzed the amount of oil consumption compared to the cost of construction and power output. The result showed that solar+ESS+diesel generator was most economically feasible. As well, we obtained that our considering hybrid battery system reduced the fuel consumption for diesel power generation about 10~15%.

• 한국재료학회지
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• 제21권1호
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• pp.21-27
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• 2011

A nano-porous structure of tin oxide was prepared using an anodic oxidation process and the sample's electrochemical properties were evaluated for application as an anode in a rechargeable lithium battery. Microscopic images of the as-anodized sample indicated that it has a nano-porous structure with an average pore size of several tens of nanometers and a pore wall size of about 10 nanometers; the structural/compositional analyses proved that it is amorphous stannous oxide (SnO). The powder form of the as-anodized specimen was satisfactorily lithiated and delithiated as the anode in a lithium battery. Furthermore, it showed high initial reversible capacity and superior rate performance when compared to previous fabrication attempts. Its excellent electrode performance is probably due to the effective alleviation of strain arising from a cycling-induced large volume change and the short diffusion length of lithium through the nano-structured sample. To further enhance the rate performance, the attempt was made to create porous tin oxide film on copper substrate by anodizing the electrodeposited tin. Nevertheless, the full anodization of tin film on a copper substrate led to the mechanical disintegration of the anodic tin oxide, due most likely to the vigorous gas evolution and the surface oxidation of copper substrate. The adhesion of anodic tin oxide to the substrate, together with the initial reversibility and cycling stability, needs to be further improved for its application to high-power electrode materials in lithium batteries.

• 전기화학회지
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• 제11권3호
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• pp.211-222
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• 2008

휴대용 전자기기의 전원으로 채용되어 상업적으로도 성공을 거두고 있는 리튬이차전지는 HEV(Hybrid Electric Vehicle)와 같은 비IT용 전원으로서도 중요성을 더하고 있다. 리튬이차전지는 리튬금속을 사용함에 따라서 초래되는 안전성을 문제를 탄소계음극을 채용하고 이에 따른 안전기구를 확보함에 의해 상용화 되었다고 할 수 있다. 이와 같이 전지에 있어 전극소재의 개발은 핵심기술이라 할 수 있으며, 점차 그 응용처가 확대되어 가고 있는 리튬이차전지의 전극소재 개발은 전지 산업뿐만 아니라 타 산업에 미치는 영향은 크다고 할 수 있다. 여기서는 리튬이차전지가 상용화되어 온 이후 채용되어온 음극과 개발중인 음극 후보에 대해 그 장단점을 분석해 보고자 한다.

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1651-1655
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• 2013

Anion exchange membranes for a vanadium redox flow battery (VRB) were prepared by pore-filling on a PE substrate with the copolymerization of vinylbenzyl chloride (VBC) and glycidyl methacrylate (GMA). The ion exchange capacity, water uptake and weight gain ratio were increased with a similar tendency up to 65% of GMA content, indicating that the monomer improved the pore-filling degree and membrane properties. The vanadium ion permeability and open-circuit voltage were also investigated. The permeability of the VG65 membrane was only $1.23{\times}10^{-7}\;cm^2\;min^{-1}$ compared to $17.9{\times}10^{-7}\;cm^2\;min^{-1}$ for Nafion 117 and $1.8{\times}10^{-7}\;cm^2\;min^{-1}$ for AMV. Consequently, a VRB single cell using the prepared membrane showed higher energy efficiency (over 80%) of up to 100 cycles compared to the commercial membranes, Nafion 117 (ca. 58%) and AMV (ca. 70%).

• 전기학회논문지
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• 제59권4호
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• pp.814-819
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• 2010

This study proposes the antenna circuit design for the transmitting wireless power, the development of the RF non-contact type Dosimeter. That is, the study designed the optimization and numerical analysis of the antenna circuit for the antenna design of 13.56MHz over the frequency bands for transmitting wireless power. We studied the needed items in the existing RF type Dosimeter with battery to implement the wireless power non-contact Dosimeter within the battery. We compared to the real measurement value as calculating the value of the inductance and capacitance through the numerical analysis for the antenna LC resonance using the theory of the electromagnetic induction method. This method to drive low power is designed to simplify the circuit and to improve the efficiency of the rectifier. We convince our research contributes not only to understand the simplified circuit and miniaturization, but also to help the design and application technology of the wireless power transmit system which is received power supply with wireless.