• Resources Recycling
• /
• v.19 no.1
• /
• pp.33-39
• /
• 2010

The spheric sintered body with $6{\pm}2mm$ diameter was manufactured in a rotary kiln at $1125^{\circ}C$/15 min using green body formed by pelletizing the batch powder composing of coal bottom ash produced from power plant and dredged soil by 70:30, wt%. And the physical properties of sintered body (BD) were analyzed to confirm the possibility for applying to an absorbent to restore a contaminated soil. The sintered body had a giant pore above 100 ${\mu}m$ and a fine pore below 10 ${\mu}m$, and bulk density was 1.4. Also its specific surface area, porosity and void proportion were $12.0m^2/g$, 30.1% and 38.2% respectively. The crushed body (BD-C), produced by crushing a BD specimen into an irregular shape with a aspect ratio of about 2, was similar to BD specimen at bulk density and pore size distribution. But it had superior values of specific surface area, porosity and void proportion compared with BD specimen owing to a decreased apparent volume due to conversion of closed pore existed at interior of BD to open pore during a crushing process. The IEP of sintered body occurred at about pH=5, so the optimum pH condition of reacting aqueous solution could be known before bonding a microbe to the sintered body. Hence, the optimum void proportion and porosity of an absorbent can be obtained by appropriate mixing a BD with BD-C from the base data calculated in this study.

• Journal of Korean Society of Environmental Engineers
• /
• v.38 no.6
• /
• pp.329-333
• /
• 2016

Disinfection by electrolysis would be useful for small wastewater treatment plant, combined sewer overflow, ballast water, swimming pool, and fish farming, where the transport, storage, and the use of chlorine gas is limited. This study investigated the feasibility of the electrolysis of dilute hydrochloric acid (HCl) for disinfection. The effects of HCl concentration, voltage and reaction time on the generation of oxidizing agents, HOCl, $O_3$, and $H_2O_2$, were examined in a series of batch test. The highest current efficiency was 99.3% which was found at 2.2%, 3 V, and 5 min of HCl concentration, voltage, and reaction time, respectively. Continuous electrolysis at 2.2% HCl, 3 V, and 5 min of the hydraulic retention time showed 97.4% of the current efficiency. Addition of sodium chloride up to 20 g/L linearly increased the oxidizing agents production. 92.2% of total coliforms were removed by the contact with the electrolyzed water.

• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.10
• /
• pp.694-702
• /
• 2013

The purpose of this study is to evaluate a de-watering filtrate treatment and the possibility of securing biological treatment capacity by changing the structure of the secondary clarifier. Accordingly, the column test was conducted to determine the effect of polymer in the de-watering filtrate on sludge sedimentation. Also, the characteristics of de-watering filtrate processing was evaluated through batch test and continuous processing operation. The results showed that sludge settling velocity increased with higher polymer concentration, and that effluent SS concentration was found to decrease. Regarding processing characteristics of de-watering filtrate, the removal efficiency of TSS and TBOD5 increased as the length of secondary clarifier was longer. Also, comparing injections into anoxic tank and secondary clarifier, de-watering filtrate by continuous infusion treatment process showed stability in both conditions. Therefore, by modifying the structure of secondary clarifier, efficient processing of de-watering filtrate is expected to be possible and processing capacity of small sewage treatment plants is considered to be improved.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.24 no.3
• /
• pp.63-69
• /
• 2020

The volume of construction waste material from the entire waste material volume in Korea is approximately 47.3% to take the biggest ratio, and from them, the waste concrete takes up approximately 62.8% that recycling is an urgent issue to address. Therefore, the government recommends more diverse and broader facilitation of the recycled aggregate in order to promote recycling the construction waste materials. In addition, when using concrete recycled aggregate in building, building standard such as floor area ratio and building height are being mitigation. The standard is a condition that mitigation the floor area ratio by up to 15% when using up to 25% of concrete recycled aggregate. Therefore, this study reviewed the relaxation of construction of construction standards when using concrete recycled aggregate in order to actively recommend the use of concrete recycled aggregate. And using the recycled coarse aggregate among the recycled aggregate, the appropriate mixing time in the batch plant according to the substitution rate was derived. In addition, using recycled aggregate admixture in order to improve the drying shrinkage, did comparative analysis about physical and mechanical property of concrete.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.4
• /
• pp.584-591
• /
• 2017

Metal removal from water has not been explained clearly by either adsorption onto the surface of absorbents or precipitation as metal hydroxides because those occur simultaneously to a certain extent. For a better understanding of the metal removal mechanisms, batch experiments were performed using soil calcined at $850^{\circ}C$ under various pH conditions for Cu, Pb, Zn, Cd, and Cr. The results showed that the metal removal efficiency with the exception of Cr decreased abruptly, even within 5 min, showing more than 90% removal. The pH of each reactant increased gradually from around 7 to 9 with time. The increases in metal removal at higher pH appear to be associated with metal hydroxides precipitation. Comparative experiments, which were carried out changing the pH by reacting with commercial activated carbon (CAC), natural yellow soil (NYS), and calcined yellow soil (CYS), showed that the pH of the CYS only increased with time. Calcination processes might lead to a change in the physical properties of the soil matrix resulting in a high pH when reacted with water. Apart from adsorption onto the surface of the absorbents, these results show that the adsorption and/or precipitation of hydroxides onto the surface of adsorbents also play important roles in regulating the dissolved metals under alkaline conditions.

• Korean Journal of Soil Science and Fertilizer
• /
• v.48 no.5
• /
• pp.469-476
• /
• 2015

Button mushroom compost (BMC) was prepared by fermenting the mixture of waste button mushroom bed collected from Boryeong area in South Korea (4): sawdust (8) : pig and fowl manure (1) for 40 days at $30^{\circ}C$. The BMC compromised diverse microorganisms including aerobic bacteria $8.1{\times}10^6cfu\;g^{-1}$, Gram negative bacteria $1.7{\times}10^7cfu\;g^{-1}$, genus Bacillus $6.4{\times}10^6cfu\;g^{-1}$, genus Pseudomonas $1.5{\times}10^4cfu\;g^{-1}$, actinomycetes $1.0{\times}10^4cfu\;g^{-1}$, and fungi $3.5{\times}10^3cfu\;g^{-1}$. BMC was used as a microbial inoculant for estimating the mobilization of heavy metals in soil or plant. When metal solubilization potential of BMC was assessed in a batch experiment, the inoculation of BMC was shown to increase the concentrations of water soluble Co, Pb, Cd, and Zn by 29, 26, 27, and 43% respectively, than those of non-inoculated soils. BMC-assisted growth promotion and metal uptake in sunflower (Helianthus annuus) was also evaluated in a pot experiment. In comparison with non-inoculated seedlings, the inoculation led to increase the growth of H. annuus by 17, 15, 18, and 21% respectively in Co, Pb, Cd, and Zn contaminated soils. Moreover, enhanced accumulation of Co, Pb, Cd, and Zn in the shoot and root systems was observed in inoculated plants, where metal translocation from root to the above-ground tissues was also found to be enhanced by the BMC. The apparent results suggested that the BMC could effectively be employed in enhancing phytoextraction from the soils contaminated with heavy metals such as Co, Pb, Cd, and Zn.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.17 no.1
• /
• pp.59-73
• /
• 2019

A decontamination technology for radioactive liquid wastes was newly developed and hypothetically applied to the liquid waste management system (LWMS) of the nuclear power plant (NPP) to evaluate its decontamination efficacy for the purpose of the fundamental reduction of spent resins. The basic principle of the developed technology is to convert major radionuclide ions in the liquid wastes into inorganic crystal minerals via chemical or biological techniques. In a laboratory batch experiment, the biological method selectively removed more than 80% of cesium within 24 hours, and the chemical method removed more than 95% of cesium. Other major nuclides (Co, Ni, Fe, Cr, Mn, Eu), which are commonly present in nuclear radioactive liquid wastes, were effectively scavenged by more than 99%. We have designed a module including the new technology that could be hypothetically installed between the reverse osmosis (R/O) package and the organic ion-exchange resin in the LWMS of the APR1400 reactor. From a technical evaluation for the virtual installation, we found that more than 90% of major radionuclides in the radioactive liquid wastes were selectively removed, resulting in a large volume reduction of spent resins. This means that if the new technology is commercialized in the future, it could possibly provide drastic cost reduction and significant extension of the life of resins in the management of spent resins, consequently leading to delay the saturation time of the Wolsong repository.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.31 no.3
• /
• pp.55-64
• /
• 2023

This batch experiment was conducted to investigate the patterns of major plant nutrients in the leachates from the soil that was incorporated with rice hull biochar adjusted pH with dry fish powder utilizing rice hull biochar for loading the soil microorganisms. The rice hull biochar adjusted pH between 6.0 and 7.0, and the mixture ratio of rice hull biochar and dry fish powder was 4:6. The treatments consisted of three; the soil incorporated with rice hull biochar non-adjusted pH with dry fish powder as control (RB + DF), the soil incorporated with rice hull biochar adjusted pH by pyroligneous acid solution and dry fish powder (RBP+DF), and the soil incorporated with rice hull biochar adjusted pH by citric acid solution and dry fish powder (RBC+DF). NH₄-N, NO₃-N, PO₄-P, and K concentrations in the leachates were analyzed during incubation. The accumulated NH₄-N and PO₄-P concentrations in the leachates from the RBC+DF treatment were the highest during leaching periods. The highest accumulated NO₃-N and K concentrations in the leachates from the RBP+DF treatment were observed. It observed that NH₄-N and PO₄-P were more released in the adjusted citric acid solution, but NO₃-N and K were less released than those in the pyroligneous acid solution due to their low absorption capacity. Furthermore, it is necessary to investigate crop growth responses to the soil incorporated with adjusted pH rice hull biochar and dry fish powder for loading soil microorganisms.

• Journal of Korean Society of Environmental Engineers
• /
• v.36 no.8
• /
• pp.561-569
• /
• 2014

This study was carried out to get the characteristics of anaerobic digestion for chemical/biological sludge produced from municipal sewage treatment plant for phosphorus. Anaerobic mesophilic batch tests showed that the ultimate biodegradability of waste activated sludge showed 31%, PACl sludge 24%, Alum sludge 26%, respectively. At the S/I 1.0, 75% of total biodegradable volatile solids (TBVS) of waste activated sludge was degraded with an initial rapid decay coefficient, k1 of $0.1129day^{-1}$ and 74% of TBVS of PACl sludge with k1 of $0.0998day^{-1}$, and 76% of TBVS of Alum sludge with k1 of $0.1091day^{-1}$ for 20 days. During the operation of SCFMRs, the 3 reactor (Control, PACl, Alum) pH maintained 6.7~7.0 and the reactor alkalinity maintained 1,800~ 2,200 mg/L as $CaCO_3$. The average biogas production rates of SCFMRs fed with PACl sludge and Alum sludge were 0.089 v/v-d and 0.091 v/v-d, respectively, which was 27~28% lower than that of the control (0.124 v/v-d) at an HRT (hydraulic retention times) of 20 days. And the methane content during the operation ranged 70~76% in 3 reactor. The average TVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 19.6% and 19.9%, respectively, at an HRT of 20 days, which showed 4% lower than that of the control (23.8%). The average BVS removal efficiency of SCFMRs fed with PACl sludge and Alum sludge were 25.8% and 26.9%, respectively, at an HRT of 20 days, which was 8~9% lower than that of the control (34.5%).

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.1
• /
• pp.85-92
• /
• 2005

The performance of a novel fermentation process, adopting a sludge blanket type configuration for higher hydrolysis/acidogenesis of the municipal primary sludge, was investigated under batch and semi-continuous conditions with various pH and temperature conditions. This acid elutriation slurry reactor provided higher system performance with a short HRT (5 days) and higher acidogenic effluent quality under pH 9 and thermophilic ($55^{\circ}C$) conditions. The hydrolysis of the sludge was revealed to be significantly dependent on seasonal effects for sludge characteristics but with little impact on acidogenesis. Based on the rainy season at the optimum conditions, VFA production and recovery fraction ($VFA_{COD}/COD$) were $0.18\;g\;VFA_{COD}\;g^{-1}\;VSS_{COD}$ and 63%. As byproducts, nitrogen and phosphorus releasing were $0.006\;g\;N\;g^{-1}\;VSS_{COD}$ and $0.003\;g\;P\;g^{-1}\;VSS_{COD}$, respectively. For the mass balance in a full-scale plant($Q=158,880\;m^3\;day^{-1}$) based on the rainy season, the VFA and non-VFA(as COD) production were $3,110\;kg\;VFA_{COD}\;day^{-1}$ and $1,800\;kg\;COD\;day^{-1}$, resulting in an increase of organics of $31\;mg\;COD\;L^{-1}$ and $20\;mg\;VFA_{COD}\;L^{-1}$ and nutrients of $0.7\;mg\;N\;L^{-1}$ and $0.3\;mg\;P\;L^{-1}$ in the influent sewage. The economical benefit from this process application was estimated to be about $67 per $1,000m^3$ of sewage except for energy requirements and also, better benefits can be expected during the dry season. Also, the results revealed that the process has various additional advantages such as pathogen-free stabilized solids production, excellent solids control and economical benefits.