• Title/Summary/Keyword: Basis sets

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Factors Influencing Users' Word-of-Mouth Intention Regarding Mobile Apps : An Empirical Study

  • Chen, Yao;Shang, Yu-Fei
    • The Journal of Industrial Distribution & Business
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    • v.9 no.1
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    • pp.51-65
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    • 2018
  • Purpose - This paper aims to identify factors that influence the users' word-of-mouth intention (WOMI) regarding mobile apps, focussing on the impacts of technology acceptance model (TAM) and social network theory. Research design, data and methodology - Based on TAM, this study integrates social network theory into the research model. The 317 sets of data collected in a survey were tested against the model using SmartPLS. Results - Our findings suggest the following: 1) Personal innovativeness positively influences perceived usefulness (PU), perceived ease of use (PEU) and perceived enjoyment (PE); 2) PEU affects PU and PE; 3) Both PU and Satisfaction are directly correlated with WOMI. Although PEU and PE has no direct impact on WOMI, they may indirectly affect WOMI via Satisfaction, as PU, PEU and PE all positively influence satisfaction; 4) Network density and network centrality both play a mediating role in the relation between PEU and WOMI. Referral Reward Program have a positive moderating effect on the relation between PU and WOMI. Conclusions - The findings of this study illustrate the traits of Apps that can promote users' WOMI, as well as the characteristics of people who are more likely to participate in the word-of-mouth process. The findings provide a theoretical basis for app developers to make word-of-mouth a marketing strategy.

Effects of the Magnetic Part of The Breit Term on Bonding: Model Calculations with Small Diatomic Molecules

  • Ryu, Seol;Kyoung K. Baeck;Han, Yeong Gyu;Lee, Yun Seop
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.969-974
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    • 2001
  • Model calculations for small molecules Li2, F2, LiF and BF have been performed at the Dirac-Fock level of theory using Dirac-Coulomb and Dirac-Coulomb-Magnetic Hamiltonians with various basis sets. In order to understand what may happen when the relativity becomes significant, the value of c, speed of light, is varied from the true value of 137.036 a.u. to 105 (nonrelativistic case) and also to 50 and 20 a.u. (exaggerated relativistic cases). Qualitative trends are discussed with special emphasis on the effect of the magnetic part of the Breit interaction term. The known relativistic effects on bonding such as the bond length contraction or expansion are demonstrated in this model study. Total energy, $\pi-orbital$ splitting, bond length, bond dissociation energy and dipole moment are calculated, and shown to be modified in a uniform direction by the effect of the magnetic term. Inclusion of the magnetic term raises the total energy, increases the bond length, reduces the $\pi-orbital$ splitting, increases the bond dissociation energy, and mitigates the changes in dipole moment caused by the Dirac term.

Quantum Mechanical Study of van der Waals Complex. Ⅰ.The $H^2$ Dimer Using the DFT and the Multi-Coefficient G2/G3 Methods

  • Kim, Chang Sin;Kim, Sang Jun;Lee, Yong Sik;Kim, Yong Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.5
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    • pp.510-514
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    • 2000
  • Molecular hydrogen dimer, ($H_2)_2$ is a weakly bound van der Waals complex. The configuration of two hydrogen molecules and the potential well structure of the dimer have been the subjects of various studies among chemists and astrophysicists. In this study, we used DFT, MCG2, and MCG3 methods to determine the structure and energy of the molecular hydrogen dimer. We compared the results with previously reported ab initio method results. The ab initio results were also recalculated for comparison. All optimized geometries obtained from the MP2 and DFT methods are T-shaped. The H-H bond lengths for the dimer are almost the same as those of monomer. The center-to-center distance depeds on the levels of theory and the size of the basis sets. The bond lengths of the $H_2$ molecule from the MCG2 and MCG3 methods are shown to be in excellent agreement with the experimental value. The geometry of optimized dimer is T-shaped, and the well depths for the dimerization potential are very small, being 23 $cm-^1$ and 27 $cm-^1$ at the MCG2 and MCG3 levels, respectively. In general the MP2 level of theory predicts stronger van der Waals than the DFT, and agrees better with the MCG2 and MCG3 theories.

Performance-based earthquake engineering methodology for seismic analysis of nuclear cable tray system

  • Huang, Baofeng
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2396-2406
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    • 2021
  • The Pacific Earthquake Engineering Research (PEER) Center has been developing a performance-based earthquake engineering (PBEE) methodology, which is based on explicit determination of performance, e.g., monetary losses, in a probabilistic manner where uncertainties in earthquake ground motion, structural response, damage estimation, and losses are explicitly considered. To carry out the PEER PBEE procedure for a component of the nuclear power plant (NPP) such as the cable tray system, hazard curve and spectra were defined for two hazard levels of the ground motions, namely, operation basis earthquake, and safe shutdown earthquake. Accordingly, two sets of spectral compatible ground motions were selected for dynamic analysis of the cable tray system. In general, the PBEE analysis of the cable tray in NPP was introduced where the resulting floor motions from the time history analysis (THA) of the NPP structure should be used as the input motion to the cable tray. However, for simplicity, a finite element model of the cable tray was developed for THA under the effect of the selected ground motions. Based on the structural analysis results, fragility curves were generated in terms of specific engineering demand parameters. Loss analysis was performed considering monetary losses corresponding to the predefined damage states. Then, overall losses were evaluated for different damage groups using the PEER PBEE methodology.

A DFT Study for the Reaction Pathway(s) of Polycyclic Aromatic Hydrocarbons I: Phenanthrene Degradation with two OH Radicals (다고리 방향족 탄화수소의 반응 경로에 대한 DFT 연구 I: 2개의 OH 라디칼에 의한 페난트렌의 분해 반응)

  • Lee, Min-Joo;Lee, Byung-Dae
    • Journal of the Korean Chemical Society
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    • v.65 no.1
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    • pp.9-14
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    • 2021
  • In this study, the DFT calculation was performed using the B3LYP/6-31G(d,p) basis sets for the reaction process in which phenanthrene decomposes due to the chain reaction of two OH radicals on phenanthrene in the gaseous state of 298 K at 1 atm. As a result of the calculation, even when two OH radicals act on phenanthrene in a chain, the reaction for producing phenanthren-9-ol is predicted to be more advantageous than the reaction for producing phenanthren-1-ol. On the other hand, it was predicted that the OH addition process at room temperature would be advantageous for the priority of the OH addition and H abstraction process.

Critical Wedging Coefficient in Frictional Elastic System Considering Separation State (분리 상태를 고려한 탄성마찰시스템의 임계 쐐기 계수)

  • Kim, Sangkyu;Jang, Yong Hoon
    • Tribology and Lubricants
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    • v.36 no.6
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    • pp.324-331
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    • 2020
  • Wedging in a frictional elastic system is defined if the state of stick exists after the external loading on the system is removed. This paper presents a method to determine the critical coefficient of wedging for an elastic frictional system by considering the separation state. Wedging is always possible if the coefficient of friction exceeds a critical value known as the critical wedging coefficient. This method requires two concepts: a necessary and sufficient condition for wedging, which can be interpreted as positive spanning sets of constraint vectors existing in the wedged system, and the minimal positive basis that enables a minimum wedging coefficient. The algorithm based on the positive spanning concept is repeatedly executed after eliminating nodes from the contact stiffness matrix, for which the separation states are impending. The simulation results show that once a node enters the separation state, it never returns to the contact state again and the critical wedging coefficient reduces during repeated algorithm execution. The benefit of this method is that the computation time permits handling models with large numbers of contact nodes. The algorithm can also numerically find the critical wedging coefficient, thereby contributing to fastening and assembly performance improvements in mechanical systems.

Three Phase Drive Transfer Algorithm for Fault Tolerance Control of Six-Phase PMSM (6상 영구자석 동기전동기의 고장대응운전을 위한 3상 구동시스템 전환 알고리즘)

  • Kim, Seong-Hoon;Jang, Won-Jin;Cho, Kwan-Yuhl;Kim, Hag-Wone
    • The Transactions of the Korean Institute of Power Electronics
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    • v.26 no.4
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    • pp.256-262
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    • 2021
  • Six-phase motors can be used in industrial applications, such as an electric vehicle, due to their high reliability and low current magnitude per phase. An asymmetrical PMSM with two sets of three-phase windings is a commonly used structure for six-phase motors, with each winding set demonstrating a phase difference of 30°. Although the asymmetrical PMSM presents low torque ripples, its dynamic torque response deteriorates due to coupled components in the two three-phase windings. The decoupled VSD control is applied to eliminate the coupling effect. Load ratio control of two inverters for the six-phase PMSM is proposed in this study. DQ currents are controlled on the basis of two synchronous reference frames, and the six-phase drive system can be changed to a three-phase drive system when one inverter presents fault conditions. The operation and effectiveness of the proposed algorithm is verified through simulation and experiments. The six-phase drive system is transferred to a three-phase drive system by changing the current reference of the second DQ reference frame. Moreover, control of both torque and speed exhibits satisfactory performance before and after the mode change.

Slangs and Short forms of Malay Twitter Sentiment Analysis using Supervised Machine Learning

  • Yin, Cheng Jet;Ayop, Zakiah;Anawar, Syarulnaziah;Othman, Nur Fadzilah;Zainudin, Norulzahrah Mohd
    • International Journal of Computer Science & Network Security
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    • v.21 no.11
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    • pp.294-300
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    • 2021
  • The current society relies upon social media on an everyday basis, which contributes to finding which of the following supervised machine learning algorithms used in sentiment analysis have higher accuracy in detecting Malay internet slang and short forms which can be offensive to a person. This paper is to determine which of the algorithms chosen in supervised machine learning with higher accuracy in detecting internet slang and short forms. To analyze the results of the supervised machine learning classifiers, we have chosen two types of datasets, one is political topic-based, and another same set but is mixed with 50 tweets per targeted keyword. The datasets are then manually labelled positive and negative, before separating the 275 tweets into training and testing sets. Naïve Bayes and Random Forest classifiers are then analyzed and evaluated from their performances. Our experiment results show that Random Forest is a better classifier compared to Naïve Bayes.

Features of the Impact of Social and Digital Changes on the System of Government Regulation of Banking Activity

  • Zalutska, Khrystyna;Pasichnyk, Vаsyl;Smolinska, Natalia;Grybyk, Igor;Antonova, Liudmyla
    • International Journal of Computer Science & Network Security
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    • v.22 no.4
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    • pp.217-222
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    • 2022
  • The main purpose of the article is to study the features of the impact of social and digital changes on the system of government regulation of banking acitivity. The digital economy sets the vector along which socio-economic systems of micro-, meso-, macro-levels will develop in the long term, which necessitates research and a comprehensive analysis of digital transformation processes. Once a priority for individual innovative companies, today digital transformation has become a mass phenomenon, and the corresponding projects are vital for the success of not only individual companies, but also regions and countries. At the same time, this transformation itself is closely connected with the trend of servicing socio-economic systems and is largely implemented on its basis. Moreover, this relationship and the mechanism for its implementation remain insufficiently studied, which necessitates the development of tools for its identification, assessment and management. As a result of the analysis, the key aspects of the impact of social and digital changes on the system of state regulation of banking activities were identified.

Comprehensive Transcriptomic Analysis of Cordyceps militaris Cultivated on Germinated Soybeans

  • Yoo, Chang-Hyuk;Sadat, Md. Abu;Kim, Wonjae;Park, Tae-Sik;Park, Dong Ki;Choi, Jaehyuk
    • Mycobiology
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    • v.50 no.1
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    • pp.1-11
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    • 2022
  • The ascomycete fungus Cordyceps militaris infects lepidopteran larvae and pupae and forms characteristic fruiting bodies. Owing to its immune-enhancing effects, the fungus has been used as a medicine. For industrial application, this fungus can be grown on geminated soybeans as an alternative protein source. In our study, we performed a comprehensive transcriptomic analysis to identify core gene sets during C. militaris cultivation on germinated soybeans. RNA-Seq technology was applied to the fungal cultures at seven-time points (2, 4, and 7-day and 2, 3, 5, 7-week old cultures) to investigate the global transcriptomic change. We conducted a time-series analysis using a two-step regression strategy and chose 1460 significant genes and assigned them into five clusters. Characterization of each cluster based on Gene Ontology and Kyoto Encyclopedia of Genes and Genomes databases revealed that transcription profiles changed after two weeks of incubation. Gene mapping of cordycepin biosynthesis and isoflavone modification pathways also confirmed that gene expression in the early stage of GSC cultivation is important for these metabolic pathways. Our transcriptomic analysis and selected genes provided a comprehensive molecular basis for the cultivation of C. militaris on germinated soybeans.