• Title/Summary/Keyword: Barium oxide

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고출력 ICP (RF) 열플라즈마 시스템을 이용한 다성분계 나노 복합체 합성

  • Lee, Mi-Yeon;Kim, Jeong-Su;Choe, Chae-Hong;Kim, Min-Ho;Seo, Jun-Ho;Hong, Bong-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.415-415
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    • 2012
  • ICP (RF) 열 플라즈마 분말 합성법은 초고온 열플라즈마(~10,000 K) 속으로 원료물질을 투입한 뒤, 용융, 기화 및 재합성의 과정을 거쳐 초미분(<1 ${\mu}s$)을 합성하는 방법으로 고출력 시스템의 경우 고온/고 엔탈피 열 유동을 통한 고융점 및 저융점 복합물질의 동시 기화에 의한 물질 조성이 제어된 나노 복합체의 대량 합성이 가능할 것으로 기대되고 있다. 본 연구에서는 전북대학교 고온플라즈마 응용연구센터의 60&200 kW의 고출력 ICP (RF) 열 플라즈마 시스템을 이용하여 LTO (Lithium Titanium Oxide)와 IZTO (Indium Zinc Tin Oxide), Barium Borosilicate Glass (K2O-BaO-B2O3-SiO2)의 다성분계 나노 복합체를 합성하였으며, FE-SEM, TEM, XRD, ICP-OES를 이용하여 그 특성을 분석하였다.

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A novel barium oxide-based Iraqi sand glass to attenuate the low gamma-ray energies: Fabrication, mechanical, and radiation protection capacity evaluation

  • Al-Saeedi, F.H.F.;Sayyed, M.I.;Kapustin, F.L.;Al-Ghamdi, Hanan;Kolobkova, E.V.;Tashlykov, O.L.;Almuqrin, Aljawhara H.;Mahmoud, K.A.
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.3051-3058
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    • 2022
  • In the present work, untreated Iraqi sand with grain sizes varied between 100 and 200 ㎛ was used to produce a colored glass sample that has shielding features against the low gamma-ray energy. Therefore, a weight of 70-60 wt % sand was mixed with 9-14 wt% B2O3, 8-10 wt% Na2O, 4-6 wt% of CaO, 3-6 wt% Al2O3, in addition to 0.3% of Co2O3. After melting and annealing the glass sample, the X-ray diffraction spectrometry was applied to affirm the amorphous phase of the fabricated glass samples. Moreover, the X-ray dispersive energy spectrometry was used to measure the chemical composition, and the MH-300A densimeter was applied to measure the fabricated sample's density. The Makishima-Makinzie model was applied to predict the mechanical properties of the fabricated glass. Besides, the Monte Carlo simulation was used to estimate the fabricated glass sample's radiation shielding capacity in the low-energy region between 22.1 and 160.6 keV. Therefore, the simulated linear attenuation coefficient changed between 10.725 and 0.484 cm-1, raising the gamma-ray energy between 22.1 and 160.6 keV. Also, other shielding parameters such as a half-value layer, pure lead equivalent thickness, and buildup factors were calculated.

Effects of Seed Layers on Formation of Barium Ferrite Thin Films and Their Magnetic Properties (씨앗층이 바륨훼라이트 박막의 형성과 자기적 성질에 미치는 영향)

  • 나종갑;이택동;박순자
    • Journal of the Korean Magnetics Society
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    • v.2 no.1
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    • pp.22-28
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    • 1992
  • Barium ferrite thin films were reactively deposited with Fe and BaO composite targets by a facing tergects sputtering unit. When thermally oxidized silicon wafers were used as substrates, minimum substrate heating of $750^{\circ}C$ was necessary for the perfect c-axis alignment in barium ferrite films. To lower the critical substrate temperature for the good c-axis alignment, such seed layers as ZnO, ${\alpha}-Fe_{2}O_{3}$ and ${\gamma}-Fe_{2}O_{3}$ were tested. The excellent c-axis algnment of BaM was obtained at a substrate temperature of $600^{\circ}C$ on ZnO seed layer whose (002) plane was parallel to the substrate surface. The magnetic properties of the BaM film showed saturation magnetization of 295 emu/cc, perpendicular coercivity of 1.7 kOe and squareness of 0.75. Optimum deposition rate of $230\;{\AA}/min$ was obtained with the composite target and this was 5 to 20 times higher than those of other investigators with oxide targets.

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Design of Double Layer Shielding Structure using Eco-friendly Shielding Materials (친환경 차폐물질을 이용한 이중구조 차폐체의 설계)

  • Park, Ji Koon;Choi, Il Hong;Park, Hyung Hoo;Yang, Sung Woo;Kim, Kyo Tae;Kang, Sang Sik
    • Journal of the Korean Society of Radiology
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    • v.10 no.8
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    • pp.559-563
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    • 2016
  • Recently, a barium(Ba) and an iodine(I) being studied as a conventional lead(Pb) alternatives of shielding material has excellent shieding rate, but the characteristic x-ray photons in the energy range near 30 keV line is released. In this study, with bismuth oxide(BiO) coupled barium sulfate($BaSO_4$) double layer, transmitted spectra, shieding rates and relative weighting rates were evaluated to validate the applicability of eco-friendly double layer shieding structure using monte carlo simulations as a prior study. From the evaluation results, in 0.4mm and 0.5mm thickness of BiO layers coupled with top 0.1mm-$BaSO_4$ layer, the shieding rate showed 1.9% and 3.9% higher than 0.6mm thickness of Pb single layer, respectively. In addition, the relative weight also 28% and 34.5% lower than 0.6mm-Pb in 0.4mm and 0.5mm thickness of BiO layers coupled with top 0.1mm-$BaSO_4$ layer.

Study on Low-Temperature Solid Oxide Fuel Cells Using Y-Doped BaZrO3 (Y-doped BaZrO3을 이용한 저온형 박막 연료전지 연구)

  • Chang, Ik-Whang;Ji, Sang-Hoon;Paek, Jun-Yeol;Lee, Yoon-Ho;Park, Tae-Hyun;Cha, Suk-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.9
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    • pp.931-935
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    • 2012
  • In this study, we fabricate and investigate low-temperature solid oxide fuel cells with a ceramic substrate/porous metal/ceramic/porous metal structure. To realize low-temperature operation in solid oxide fuel cells, the membrane should be fabricated to have a thickness of the order of a few hundreds nanometers to minimize IR loss. Yttrium-doped barium zirconate (BYZ), a proton conductor, was used as the electrolyte. We deposited a 350-nm-thick Pt (anode) layer on a porous substrate by sputter deposition. We also deposited a 1-${\mu}m$-thick BYZ layer on the Pt anode using pulsed laser deposition (PLD). Finally, we deposited a 200-nm-thick Pt (cathode) layer on the BYZ electrolyte by sputter deposition. The open circuit voltage (OCV) is 0.806 V, and the maximum power density is 11.9 mW/$cm^2$ at $350^{\circ}C$. Even though a fully dense electrolyte is deposited via PLD, a cross-sectional transmission electron microscopy (TEM) image reveals many voids and defects.

Preparation of Core-Shell Structured BaTiO3 Powder Via Coating of Cr2O3 and Mn2O3 (Cr2O3 및 Mn2O3의 코팅에 의한 Core-Shell 구조의 BaTiO3 분말 제조)

  • Kwon, Byung-Soo;Lee, Hye-Un;Jang, Jung-Yoon;Lee, Sang-Kil;Chung, In Jae;Cho, Young-Sang;Park, Tae-Jin;Choi, Guang-Jin
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.99-105
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    • 2008
  • Core-shell structured $BaTiO_3$ powders were produced via nano-coating of $Cr_2O_3$ and $Mn_2O_3$ to barium titanate powder system for MLCCs. From preliminary experiments, the optimal solution reaction condition employing using $KMnO_4$, $K_2Cr_2O_4$ and sulfur was established. Not only powders of $Cr_2O_3$ and $Mn_2O_3$ were synthesized but also their coating on $BaTiO_3$ powders were peformed under the same reaction condition. The coating was carried out in two ways, one-step and two-step, and its results were characterized for comparison. Conclusively speaking, two oxide additives were coated onto the $BaTiO_3$ powder surface with high quality and excellent reaction yield even under mild condition, which indicates that the contents as well as the properties of additive shell layer can be precisely controlled with rather ease.

Nitric Oxide Synthase Mediates Carbon Monoxide-Induced Stimulation of L-type Calcium Currents in Human Jejunal Smooth Muscle Cells

  • Lim, In-Ja;Yun, Ji-Hyun;Kim, Seung-Tae;Myung, Soon-Chul;Kim, Tae-Ho;Bang, Hyo-Weon
    • The Korean Journal of Physiology and Pharmacology
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    • v.8 no.3
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    • pp.161-165
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    • 2004
  • Exogenous carbon monoxide (0.2%) increases L-type calcium $(Ca^{2+})$ current in human jejunal circular smooth muscle cells. The stimulatory effect of carbon monoxide (CO) on L-type $Ca^{2+}$ current is inhibited by pre-application of L-NNA, a classical competitive inhibitor of nitric oxide synthase (NOS) with no significant isoform selectivity (Lim, 2003). In the present study, we investigated which isoform of NOS affected CO induced stimulation of L-type $Ca^{2+}$ current in human jejunal circular smooth muscle cells. Cells were voltage clamped by whole-cell mode patch clamp technique, and membrane currents were recorded with 10 mM barium as the charge carrier. Before the addition of CO, cells were pretreated with each inhibitor of three NOS isoforms for 15 minutes. CO-stimulating effect on L-type $Ca^{2+}$ current was partially blocked by N-(3-(Amino-methyl) benzyl) acetamidine 2HCl (1400W, an iNOS inhibitor). On the other hand, 3-bromo-7-nitroindazole (BNI, a nNOS inhibitor) or $N^5-(1-Iminoethyl)-L-ornithine$ dihydrochloride (L-NIO, an eNOS inhibitor) completely blocked the CO effect. These data suggest that low dose of exogenous CO may stimulate all NOS isoforms to increase L-type $Ca^{2+}$ channel through nitric oxide (NO) pathway in human jejunal circular smooth muscle cells.

Synthesis and Physical Properties of Sm Doped Pb Free 3 Phase-Glasses (Sm 농도에 따른 무연 3상 유리계의 합성과 물리적 성질)

  • Park, Jong-Ho
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.368-373
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    • 2012
  • Glasses were prepared with compositions of $(13-x)BaO-80B2_O_3-7Li_2O{\cdot}xSm_2O_3$, BBLSx(x=0.5, 0.4, 0.3) by melting the starting materials of boron oxide(99.9%), lithium oxide(99.9%), barium carbon oxide(99.9%), and samarium oxide(99.9%) and then quenching the melt at $1350^{\circ}C$. This led to good-quality BBLSx(x=0.4, 0.3) and poor-quality BBLSx(x=0.5) glasses. The physical and structural properties of the BBLSx glasses were studied by means x-ray diffraction, scanning electron microscopy(SEM), differential scanning calorimetry(DSC), and dielectric spectroscopy. From the x-ray diffraction and SEM results, the quality of the BBLSx glasses significantly depends on the $Sm_2O_3$ concentration. The x-ray diffraction pattern showed that the crystallites in the BBLSx glasses after heat treatment at $700^{\circ}C$ may be $LiBaB_9O_{15}$. From the DSC results, the glass transition temperatures($T_g$), crystallization temperatures($T_c$), and the maximum temperatures of the crystallized($T_p$) BBLSx glasses all changed with the $Sm_2O_3$ concentration. According to the dielectric spectroscopy results, the values of the real dielectric constant and Tan ${\delta}$ of the BBLSx glasses depended on the $Sm_2O_3$ concentration. The values of the real dielectric constant and Tan ${\delta}$ were also shown to depend on the measuring temperature, possibly due to the ion migration in the bulk of the BBLSx glasses.

Enhanced light-emitting performances of $Y_2O_3:Eu$ phosphor for FPD application.

  • Nazarov, Michael;Kang, Jong-Hyuk;Jeon, Duk-Young;Bukesov, Sergey;Popovici, Elisabeth-Jeanne;Muresan, Laura
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1087-1090
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    • 2004
  • Samples of yttrium oxide doped with trivalent europium have been prepared by ceramic techniques, under different synthesis conditions; barium chloride ($BaCl_2$) and sodium tetraborate ($Na_2B_4O_7$) were tested as flux. The improvement of luminescence properties in dependence on substitution of $Eu^{3+}$ for $Y^{3+}$ in the host lattice, under electron and UV excitations is demonstrated The obtained results are discussed with respect to the employed processing method.

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A Study on Fractal Analysis and 3D Images of Surface on BST Thin Films. (BST 박막 표면의 프랙탈 분석 및 3D 이미지 특성)

  • Hong, Kyung-Jin;Min, Yong-Ki;Cho, Jae-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.103-106
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    • 2002
  • The applicability of models based on fractal morphology to characterize $(Ba\;Sr)TiO_{3}$ thin film surfaces was investigated. The fractal morphology of coated barium strontium titan oxide thin film surfaces was described using fractal dimension from scanning electro microscopy image. The $(Ba\;Sr)TiO_{3}$ coating were deposited on silicon wafers using $(Ba\;Sr)TiO_{3}$ solution and spin coater. BST solution was composited by mol ratio, and then spin-coated from 3 times to 5 times coating on $Pt/SiO_{2}/Si$ substrate. Qualitative thin film analysis was performed with scanning electro microscopy (SEM), and surfaces parameters such as average grain diameter, roughness exponent and fractal dimension were determined.

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