• Title/Summary/Keyword: Barium

Search Result 816, Processing Time 0.032 seconds

Crystal Structures of Ba-ferrites Synthesize by Coprecipitation-Oxidation Method (공침-산화법으로 합성된 바륨페라이트의 결정구조)

  • 신형섭
    • Journal of the Korean Ceramic Society
    • /
    • v.34 no.10
    • /
    • pp.1045-1052
    • /
    • 1997
  • Barium ferrites (BaFe12O19) were synthesized at the various temperature by the coprecipitation-oxidation method. X-ray diffraction Rietveld analysis for barium ferrites were performed, their microstructures were observed and their magnetic properties were measured, in order to analyze the crystal structures and determine the optimal temperature of heat-treatment. The barium ferrite, its average particle size 80 nm, was formed at 600℃ through the hematite (α-Fe2O3), but the site occupations of the Fe's in tetrahedral and bipyramidal sites and of the Ba relatively low. Increasing the heating temperature, these occupations and the magnetization increased, and the crystal c-axis decreased. These changes were very small at the heat treatment of above 800℃, but the particles were rapidly grown. It is suggested that the optimal temperature of heat-treatment is 800℃, at which temperature crystal structure is relatively stable and the particles hardly ever grow.

  • PDF

Gamma Ray Shielding Study of Barium-Bismuth-Borosilicate Glasses as Transparent Shielding Materials using MCNP-4C Code, XCOM Program, and Available Experimental Data

  • Bagheri, Reza;Moghaddam, Alireza Khorrami;Yousefnia, Hassan
    • Nuclear Engineering and Technology
    • /
    • v.49 no.1
    • /
    • pp.216-223
    • /
    • 2017
  • In this work, linear and mass attenuation coefficients, effective atomic number and electron density, mean free paths, and half value layer and $10^{th}$ value layer values of barium-bismuth-borosilicate glasses were obtained for 662 keV, 1,173 keV, and 1,332 keV gamma ray energies using MCNP-4C code and XCOM program. Then obtained data were compared with available experimental data. The MCNP-4C code and XCOM program results were in good agreement with the experimental data. Barium-bismuth-borosilicate glasses have good gamma ray shielding properties from the shielding point of view.

Oral contrast media for computed tomography of canine pancreas

  • Choi, Jihye;Chang, Jinhwa;Oh, Sunkyoung;Yoon, Junghee
    • Korean Journal of Veterinary Research
    • /
    • v.51 no.2
    • /
    • pp.165-169
    • /
    • 2011
  • Barium suspension, oral iodine contrast medium and water were applied in eight dogs to evaluate (1) distension of gastrointestinal tract, (2) the effect of the oral contrast media on the identification of the pancreas from surrounding organs, and (3) image quality and the presence of artifacts in canine pancreas computed tomography (CT) images. Oral iodine contrast medium, gastrografin, produced significant artifacts that deteriorated the CT images of the pancreas. The use of water did not provide the fullness of the gastrointestinal lumens. Barium suspension was effective for the identification of the pancreas from the surrounding gastrointestinal tract, without significantly increasing image noise. Barium suspension can be used as an optimal contrast medium that will not cause an adverse effect on the pancreatic density and image quality.

A new low dielectric constant barium titanate - poly (methyl methacrylate) nanocomposite films

  • Upadhyay, Ravindra H.;Deshmukh, Rajendra R.
    • Advances in materials Research
    • /
    • v.2 no.2
    • /
    • pp.99-109
    • /
    • 2013
  • In the present investigation, nanocomposite films with poly(methyl methacrylate) (PMMA) as a polymer matrix and barium titanate as a filler were prepared by solution casting method. Barium titanate nano particles were prepared using Ti(IV) triethanolaminato isopropoxide and hydrated barium hydroxide as precursors and tetra methyl ammonium hydroxide (TMAH) as a base. The nanocomposite films were characterized using XRD, FTIR, SEM and dielectric spectroscopy techniques. Dielectric measurements were performed in the frequency range 100 Hz-10 MHz. Dielectric constant of nanocomposites were found to depend on the frequency, the temperature and the filler fraction. Dissipation factors were also influenced by the frequency and the temperature but not much influenced by the filler fractions. The 10 wt% of BT-PMMA nanocomposite had the lowest dielectric constant of 3.58 and dielectric loss tangent of 0.024 at 1MHz and $25^{\circ}C$. The dielectric mixing model of Modified Lichtenecker showed the close fit to the experimental data.

Effect of La3+ and Ti4+ Ions on the Magnetic Properties of Barium Hexaferrite Powders Synthesized Using Sol-Gel Method

  • Ertus, Emre Burak;Yildirim, Serdar;Celik, Erdal
    • Journal of Magnetics
    • /
    • v.21 no.4
    • /
    • pp.496-502
    • /
    • 2016
  • Doped and undoped barium hexaferrite powders ($BaFe_{12}O_{19}$, $Ba_{0.7}Ti_{0.3}Fe_{12}O_{19}$ and $Ba_{0.7}La_{0.3}Fe_{12}O_{19}$) were produced by the sol-gel method. The effects of substituting elements were studied in terms of the magnetic properties of barium hexaferrite powders. The magnetic properties were remarkably changed by the substitution of $La^{3+}$ and $Ti^{4+}$ ions for the $Ba^{2+}$ ion and were accompanied by oxygen deficiency in the $BaFe_{12}O_{19}$. Coercivities ($H_C$) from 4200 to 5100 Oe, remanences ($M_R$) from 22 to 49 emu/g and saturation magnetizations ($M_S$) from 41 to 73 emu/g were obtained for different samples. The obtained results were discussed in detail.

Removal of heavy metal by coprecipitation with barium sulfate (황산바륨의 공침현상을 이용한 중금속 이온의 제거)

  • Lim, Heon-Sung;Lee, Sueg-Geun
    • Analytical Science and Technology
    • /
    • v.19 no.4
    • /
    • pp.280-284
    • /
    • 2006
  • The objective of this study is to investigate the removal of heavy metal by using the coprecipitation of barium sulfate. Several parameters governing the efficiency of the coprecipitation method were evaluated by the pH of sample solution, amount of coprecipitant, and addition of sulfide for the removal of As(V), Cd(II), Cr(III), Cr(VI), Cu(II), Hg(II) and Pb(II) metal ions ($10{\mu}g/ml$ each). The coprecipitation was about 80% - 95% only for lead at low pH but under 10% for other ions. The amount of removal was about 95% - 100% for Cd, Hg, Pb, Cu in the all pH range by the addition of sulfide with barium sulfate but As(V) and Cr(III, VI) ions were not affected by the same conditions.

Morphology of Barium Titanyl Oxalate Produced by Homogeneous Precipitation from Acidic Solution of Dimethyl Oxalate (Dimethyl Oxalate에 의한 균일 침전법으로 생성된 Barium Titanyl Oxalate의 형태학적 연구)

  • Min, Chonkyu;Lee, Chul
    • Analytical Science and Technology
    • /
    • v.10 no.3
    • /
    • pp.203-208
    • /
    • 1997
  • Barium titanyl oxalate(BTO) was precipatated by utilizing the thermal decomposition of dimethyl oxalate in acidic aqueous solution having $BaCl_2$ and $TiCl_4$. Particle morphology of BTO was influeneced by the various experimental factors. i.e.. the faster rate to nucleation with higher temperature and the higher ratio of [DMO]/[$Ba^{2+}+Ti^{4+}$] was found to correspond to the faster rate of transformation of particle size distribution from unimodal to broad unimodal through bimodal. The BT powder obtained by calcination at $900^{\circ}C$ in air consists of larger particles than BT generated by general coprecipitation method and shows tetragonal symmetry. The stirring during reaction was also found to have much effect upon characteristics of BTO and BT.

  • PDF