• Title/Summary/Keyword: Barbier

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Zinc Mediated Barbier Type Allylation of Cyclic Imides and Subsequent Coupling Reactions with Carbon Nucleophiles

  • Kang, Seok-Won;Heo, Eun-Young;Jun, Jong-Gab;Kim, Sung-Hoon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.12
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    • pp.1924-1928
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    • 2004
  • Allylations of N-benzyl and N-methyl cyclic imides were accomplished successfully under mild Barbier type conditions using zinc metal, allyl bromide and catalytic amount of $PbBr_2$. Subsequent coupling reactions with some carbon nucleophiles afforded 1,2- and 1,4-addition products in moderate to high yields.

CERTIFICATION OF N. D. T. OPERATORS

  • Barbier, R.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.2 no.1
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    • pp.31-49
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    • 1982
  • Description of the French certification system; comparison between useful certification systems of other countries, look to the future.

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Synthesis of Dienamides via the Reaction of Nitrile with Allylindium Reagents and Intramolecular Acyl Group Quenching Cascade

  • Kim, Sung-Hwan;Kim, Yu-Mi;Kim, Jae-Nyoung
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2351-2356
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    • 2010
  • Various dienamide derivatives were synthesized in reasonable yields from benzonitriles having an amide moiety at the ortho-position, via the sequential (i) In-mediated allylation of nitrile moiety to form an imine intermediate, (ii) intramolecular quenching of an acyl group by the imine intermediate, and (iii) a proton transfer to dienamide.

LIQUID PENETRANT TESTING AT LOW TEMPERATURE (저온에서 행하는 액체침투 탐상방법)

  • Barbier, R.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.3 no.1
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    • pp.26-30
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    • 1983
  • Tests on Liquid Penetrant products normally utilized in the temperature range $10^{\circ}C\;to\;40^{\circ}C$ have shown that the required sensibility can not be obtained at temperatures lower than $10^{\circ}C$ with the penetration and development time usually specified in the operating procedures. It is thus confirmed that $10^{\circ}C$ is the lowest allowable temperature for use of these products. The results obtained with a penetrant and develope. specially formulated for low temperatures (SHERWIN B 305+D100) are satisfactory between $0^{\circ}C\;and\;15^{\circ}C$.

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