• The Journal of Engineering Geology
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• v.16 no.4 s.50
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• pp.393-402
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• 2006

The contamination characteristics of BTEX and TPH components in silty soils with the oil leakage event from point source were studied. The over ratios of three soil pollution standard for TPH component were $1.5{\sim}1.7$ times higher than that of BTEX component. The mean and maximum values of BTEX and TPH components with sample points were B-zone > A-zone > C-zone, and the highest concentrations were measured at $1{\sim}2m$ depth below surface. BTEX and TPH components were increased with linear distance in zone within 120 m and 80 m from point source. For the zone more than 120 m, BTEX and TPH concentrations were under soil pollution standard. The cutoff values of indicator kriging using BTEX and TPH components were defined as confirmative limit, warn- ing limit and counterplan limit. The variograms of indicator-transformed data were selected linear model. The contamination ranges of BTEX and TPH components using confirmative limit and warning limit were estimated similar, but the contamination range of those using counterplan limit was much reduced. The maximum contamination probabilities were estimated by probability maps usinB confirmative limit, warning limit and counterplan limit. The maximum contamination probabilities with three soil pollution standard were estimated 26%, 26% and 13% for BTEX component, and 44%, 38% and 26% for TPH component.

• Journal of Korean Society on Water Environment
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• v.21 no.4
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• pp.403-409
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• 2005

Methyl tert-butyl ether (MTBE) contamination in groundwater often coexists with benzene, toluene, ethylbenzene, and xylene (BTEX) near the source of the plume. Then, groundwater contamination problems have been developed in areas where the chemical is used. Common sources of water contamination by BTEX and MTBE include leaking underground gasoline storage tanks and leaks and spills from above ground fuel storage tanks, etc. In oil-contaminated environments, anaerobic biodegradation of BTEX and MTBE depended on the concentration and distribution of terminal electron acceptor. In this study, effect of electron acceptor on the anaerobic biodegradation for BTEX and MTBE-contaminated soil was investigated. This study showed the anaerobic biodegradation of BTEX and MTBE in two different soils by using nitrate reduction, ferric iron reduction and sulfate reduction. The soil samples from the two fields were enriched for 65 days by providing BTEX and MTBE as a sole carbon source and nitrate, sulfate or iron as a terminal electron acceptor. This study clearly shows that degradation rate of BTEX and MTBE with electron acceptors is higher than that without electron acceptors. Degradation rate of Ethylbenzene and Xylene is higher than that of Benxene, Toluene, and MTBE. In case of Benzene, Ethylbenzene, and MTBE, nitrate has more activation. In case of Toluene and Xylene, sulfate has more activation.

• Tribology and Lubricants
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• v.33 no.6
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• pp.263-268
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• 2017

The significance of maintaining the soil environment is gradually increasing owing to soil and underground water contamination by petroleum leak accidents. However, the purification of soil is an expensive and more time-consuming process than the purification of contaminated water and air. Moreover, determining the source and people responsible for soil pollution gets often embroiled in legal conflicts, further delaying the cleanup process of the contaminate site. Generally, TPH (total petroleum hydrocarbon) pattern analysis is used to determine the petroleum species and polluter responsible for soil contamination. However, this process has limited application for petroleum products with a similar TPH pattern. In this study, we analyze the TPH pattern and specific sectional ratio (${\sim}C_{10}$, $C_{10}-C_{12}$, $C_{12}-C_{36}$, and $C_{36}{\sim}$) of various domestic petroleum products to identify the petroleum product responsible for soil contamination. Also, we perform BTEX (benzene, toluene, ethyl benzene, xylene) quantitative analysis and determine B:T:E:X ratio using GC-MS. The results show that gasoline grade 1 and 2 have a similar TPH pattern but different BTEX values and ratios. This means that BTEX analysis can be used as a new method to purify soil pollution. This complementary TPH and BTEX method proposed in this study can be used to identify the petroleum species and polluters present in the contaminated soil.

• Journal of Environmental Impact Assessment
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• v.22 no.5
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• pp.481-489
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• 2013

There are U.S. troops with a force about 290,000 strong stationed all around the world, approximately 150 countries. Among the troops, USFK has performed principal part with its stationing for 50 years against the military threat of North Korea. However, as a result of an investigation made into environmental contamination of several bases which were restituted from US to ROK by the Land Partnership Plan in the process of relocation of USFK, it was found that the area was contaminated by not only TPH and BTEX caused by diesel fuel and JP-8 but also various heavy metal over the standard level according to the operations of corps. Among these bases, 4 corps, each of which has different duties and function, were chosen to be analyzed for the characteristics and degrees of soil contamination. Fisrt of all, in armored camp the soil was contaminated by TPH and heavy metal (Zn, Ni, Pb) due to the repairing activities of tracked vehicles and shooting exercises. In army aviation camp, the soil was contaminated by TPH, BTEX and heavy metal (Zn, Cd) due to repairing activities of aircrafts. Also, in engineer camp there was contaminated area polluted by TPH and heavy metal (Zn, Pb) caused by open-air storage of various construction materials and TPH, BTEX and heavy metal (Zn, Pb, Cu) contamination of aircraft shooting area in shooting range camp were detected. Managing environment will be more effective when we identify the contaminative characteristics and take necessary measures in advance.

• Journal of Korea Soil Environment Society
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• v.4 no.2
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• pp.45-53
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• 1999

The soil samples were measured at 90 sites of Soil's Network In 1997~1998 which was established for the investigation of soil contamination in Seoul. This study was more focused to measure and analyze for BTEX(Benzene, Toluene, Ethylbenzene and Xylene) concentration in the Soil Network. Also, the samples were analyzed by Purge & Trap method. As a result, the BTEX were detected at all sampling sites in Seoul. The Min. Max and Mean BTEX concentration were respectively 0.047mg/kg, 2.618mg/kg and 0.437mg/kg in 1998. The concentration of the BTEX detected at all sampling sites was lower than that of the intervention standards(at industrial areas) of Soil Preservation Act.

• Journal of Soil and Groundwater Environment
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• v.7 no.2
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• pp.3-11
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• 2002

The objective of this study was to survey the oil contamination around the Mountain Baegun at Uiwang city to obtain the preliminary data for bioremediation. For measuring the oil concentrations and physical properties from soil, we analyzed BTEX. TPH and pH, organic content, water content, pormeability coefficient, gravity, porosity and used the purge & trap method for analyzing BTEX. Using the Accelerated Solvent Extractor, we pretreated the samples and then analyzed TPH using GC-FID as soon as possible. From the analysis results, maximum concentration of TPH was 24.773mg/kg and BTEX was 101.7mg/kg. The results of TPH at the Mountain Baegun were higher than the enforcement standard of soil contamination(Korea) and the BTEX concentrations were also higher than the advisory standard of soil contamination(Korea). From these results, the Mountain Baegun may requires to remedy the oil-contaminated soil. In addition, we performed the field bioremediation test for five weeks at the Mountain Baegun using the microbial additives that were developed by our laboratory. From the results of the field test, we could find the about 95% of the oil was removed from the contaminated soil in five weeks. So we consider that it is the one of the useful solutions to remedy the oil-polluted site.

• Korean Journal of Environmental Agriculture
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• v.33 no.4
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• pp.414-418
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• 2014

BACKGROUND: Benzene, toluene, ethylbenzene and xylene (BTEX), which are volatile aromatic hydrocarbons and main constituents of gasoline, are neuro-carcinogenic organic pollutants in soil and groundwater. Korea Ministry of Environment has established the maximum permissible level of BTEX in arable soil to 1, 20, 50 and 15 mg/kg, respectively. METHODS AND RESULTS: To understand an arable soil contamination by BTEX, we collected 92 samples from the arable lands around oil reservoir, and analyzed the BTEX residue using a GC-MS with head-space sampler. A linear correlation between BTEX concentration and peak areas was detected with coefficient correlations in the range of 0.9807-0.9995. The method LOQ of BTEX was 0.002, 0.014, 0.084, and 0.038 mg/kg, respectively. Recoveries of 0.5 mg/kg BTEX were found to be 73.7-96.9%. The precision was reliable since RSD percentage (0.7-7.5%) was below 30, which was the normal percent value. Also, BTEX in all samples were detected under the LOQ. CONCLUSION: These results showed that the investigated arable soils around airport and oil reservoir in Korea were not contaminated by oils.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.368-371
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• 2003

Accidental release of petroleum products from underground storage tank(USTs) is one of the most common causes of groundwater contamination. BTEX is the major components of fuel oils, which are hazardous substances regulated by many nations. In addition to BTEX, other gasoline consituents such as MTBE(methyl-t-buthyl ether), anphthalene are also toxic to humans. Natual attenuation processes include physic, chemical, and biological trasformation. Aerobic and anaerobic biodegradation are believed to be the major processes that account for both containment of the petroleum-hydrocarbon plum and reduction of the contaminant concentrations. Aerobic bioremediation has been highly effective in the remediation of many fuel releases. However, Bioremediation of aromatic hydrocarbons in groundwater and sediments is ofen limited by the inability to provide sufficient oxygen to the contaminated zones due to the low water solubility of oxygen. Anaerobic processes refer to a variety of biodegradation mechanisms that use nitrate, ferric iron, sulfate, and carbon dioxide as terminal electron accepters. The objectives of this study was to conduct laboratory-scale microcosm studies in assessing enhanced bioremediation potential of BTEX and MTBE under various electron accepters(aerobic, nitrate, ferric iron, sulfate) in contaminated Soil. these results suggest that, presents evidence and a variety pattern of the biological removal of aromatic compounds under enhanced nitrate-, Fe(III)-, sulfate-reducing conditions.

• Journal of Soil and Groundwater Environment
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• v.19 no.6
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• pp.18-23
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• 2014

The BTEX contamination of soil around gas station in Korea was investigated in 53 gas stations in 2013 by official test method on soil pollution. Each gas station was divided into oil tank area, line area, and surrounding area. The concentration of BTEX in 1066 sites of 53 gas stations was N.D.~ 3437.36 mg/kg. The order of average concentration for area was as follows: line area ($20.91{\pm}144.79mg/kg$) > tank area ($15.11{\pm}110.08mg/kg$) > surrounding area ($10.79{\pm}111.40mg/kg$). It was the number of sampling site exceeding regulatory levels at surrounding area the most at all. The average concentration of xylene was the highest, while that of ethylbenzene was the lowest.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.536-539
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• 2003

This study area has been contaminated by oils. To identify contaminated ranges and to assess the possibility of contamination dispersion, monitoring wells were installed and slug test, field soil permeability test, automatic or manual measurement of groundwater table, and groundwater quality analyses in field and laboratory were performed. In addition, a groundwater modeling program was used to assess the possibility of oil contamination dispersion, based on field data and groundwater quality data. The results showed that concentration of oil contaminants in groundwater have been decreased by dispersion and adsorption.