• Title/Summary/Keyword: BMN

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Cation Ordering and Microwave Dielectric Properties of $Ba(Mg_{1/3}Nb_{2/3})O_3$ Ceramics: II. Local Order-Disorder Phase Transition and Second Phase formation ($Ba(Mg_{1/3}Nb_{2/3})O_3$세라믹스의 양이온 규칙구조와 유전특성: II. 국부적 규칙-불규칙 상전이와 이차상 생성 거동)

  • 김영웅;박재환;김긍호;김윤호;박재관
    • Korean Journal of Crystallography
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    • v.12 no.2
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    • pp.81-87
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    • 2001
  • We have studied the effect of sintering temperature and time on the cation ordering and second phase formation in Ba(Mg/sub 1/3/Nb/sub 2/3/)O₃(BMN) microwave ceramics by using transmission electron microscopy. The relationship between the structural-chemical behavior arid microwave dielectric properties has also been investigated. It is revealed that according to the sintering conditions the BMN ceramics show very diverse local ordering behavior, such as the development of domain twinning and "core-shell"-structured grains and the formation of local disordered domains, though having 1 : 2 cation ordering structure basically. The disordered structure is found in Mg-excess region. Such local chemical variation seems to be caused by the formation of BaNb₂O/sub 6/-like second phase in its neigh-boring grain boundary. The microwave dielectric quality factor of the ceramics decreases greatly with the increase of the structural-chemical inhomogeneity and diversity.

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Physical Properties of $Ba_{1-x}Sr_x(Mg{1/3}Nb_{2/3})O_3$Ceramics ($Ba_{1-x}Sr_x(Mg{1/3}Nb_{2/3})O_3$ 세라믹스의 물리적 특성)

  • 김부근;김재윤;김강언;정수태;조상희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.325-328
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    • 1999
  • The physical and electrical properties of $\textrm{Ba}_1$ $_{x}\textrm{Sr}_{x}$($\textrm{Mg_{1/3}Nb_{2/3}}$)$\textrm{O}_3$ (x =0, 0.2, 0.4, 0.6, 0.8, 1.0) ceramics were investigated. The Bal $_{x}\textrm{Sr}_{x}$($\textrm{Mg_{1/3}Nb_{2/3}}$)$\textrm{O}_3$ systems were shown that the hexagonally ordered superlattices were increased with increasing x values. The relative densities of all samples were over 97% theoretical densities. The dc resistivities of samples were $10^{13}$ - $10^{14}$$\Omega\textrm{cm}$at room temperature, these values were nearly constant at 130(x=0)-$230^{\circ}C$ (x=l). However, the resistivities of samples decreased rapidly above those temperature and their activation energies were from 1.0 to 1.52 eV. The relative dielectric constant was 33(BMN) and 30.6(SMN) respectively. And the highest value was shown at x=0.4 and the value was 34.3. The temperature coefficient of dielectric constant was -61 ppm/$^{\circ}C$(BMN) and 79 ppm/$^{\circ}C$ (SMN) respectively.

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Transparent Nano-floating Gate Memory Using Self-Assembled Bismuth Nanocrystals in $Bi_2Mg_{2/3}Nb_{4/3}O_7$ (BMN) Pyrochlore Thin Films

  • Jeong, Hyeon-Jun;Song, Hyeon-A;Yang, Seung-Dong;Lee, Ga-Won;Yun, Sun-Gil
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.20.1-20.1
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    • 2011
  • The nano-sized quantum structure has been an attractive candidate for investigations of the fundamental physical properties and potential applications of next-generation electronic devices. Metal nano-particles form deep quantum wells between control and tunnel oxides due to a difference in work functions. The charge storage capacity of nanoparticles has led to their use in the development of nano-floating gate memory (NFGM) devices. When compared with conventional floating gate memory devices, NFGM devices offer a number of advantages that have attracted a great deal of attention: a greater inherent scalability, better endurance, a faster write/erase speed, and more processes that are compatible with conventional silicon processes. To improve the performance of NFGM, metal nanocrystals such as Au, Ag, Ni Pt, and W have been proposed due to superior density, a strong coupling with the conduction channel, a wide range of work function selectivity, and a small energy perturbation. In the present study, bismuth metal nanocrystals were self-assembled within high-k $Bi_2Mg_{2/3}Nb_{4/3}O_7$ (BMN) films grown at room temperature in Ar ambient via radio-frequency magnetron sputtering. The work function of the bismuth metal nanocrystals (4.34 eV) was important for nanocrystal-based nonvolatile memory (NVM) applications. If transparent NFGM devices can be integrated with transparent solar cells, non-volatile memory fields will open a new platform for flexible electron devices.

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Cation Ordering and Microwave Dielectric Properties of $Ba(Mg_{1/3}Nb_{2/3})O_3$Ceramics: I. Long-Range Order Parameter ($Ba(Mg_{1/3}Nb_{2/3})O_3$ 세라믹스의 양이온 규칙구조와 유전특성: I. 장거리 규칙도)

  • 김영웅;박재환;김윤호;박재관
    • Korean Journal of Crystallography
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    • v.12 no.2
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    • pp.76-80
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    • 2001
  • We have studied the effect of sintering conditions on the long-range order parameter of the 1 : 2 cation ordering in Ba(Mg/sub 1/3/Nb/sub 2/3/)O₃microwave dielectrics prepared through a columbite precursor method. It is found that the order parameter depends strongly on the sintering conditions. As the heat-treatment time increases at 1350℃, the long-range order parameter decreases. When sintered at 1500℃ for 4 hours, BMN shows a high long-range order parameter of 0.94.

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The Effect of Mg Deficiency on the Microwave Dielectric Characteristics of (Mg1/2Nb2/3)O3 Ceramics (Mg 결핍에 따른 Ba(Mg1/2Nb2/3)O3 세라믹스의 마이크로파 유전특성)

  • Paik, Jong-Hoo;Lee, Mi-Jae;Choi, Byung-Hyun;Kim, Hyo-Tae;Jee, Mi-Jung;Lim, Eun-Kyeong;Nahm, Sahn;Lee, Hwack-Joo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.384-389
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    • 2004
  • Crystal structure and microwave dielectric properties of Ba(Mg1/3Nb2/3) $O_3$ (BMN) ceramics were investigated. Ba(Mg1/3Nb2/3) $O_3$ has the 1:2 ordered hexagonal structure. The 1:2 ordering and relative density of specimens increased with small Mg deficiency(x). The variation of Q${\times}$ $f_{0}$ with Mg deficiency is very similar to that of 1:2 ordering and relative density. The highest Q${\times}$ $f_{0}$ achieved in this investigation is about 96,000 for Ba(Mg1/3Nb2/3) $O_3$. The improvement of Q${\times}$ $f_{0}$ with Mg-deficiency is related to the increase of degree of ordering and relative density of the specimen.

Crystal structure of $Ba(Mg_{1/3}Nb_{2/3})O_3$ - $La(Mg_{2/3}Nb_{1/3})O_3$ Complex perovskite compound ($Ba(Mg_{1/3}Nb_{2/3})O_3$ - $La(Mg_{2/3}Nb_{1/3})O_3$ 복합 페로브스카이트 화합물의 결정구조)

  • Paik, Jong-Hoo;Lee, Mi-Jae;Choi, Byung-Hyun;Lee, Jong-Won;Jee, Mi-Jung;Lim, Eun-Kyeong;Nahm, Sahn;Lee, Hwack-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.283-287
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    • 2003
  • Crystal structure of $(Ba_{1-x}La_x)[Mg_{(1+x)/3}Nb_{(2-x)/3}]O_3$ (BLMN) ceramics with $0{\leq}x{\leq}1$ was investigated using synchrotron X-ray powder diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). When La content, x, is above 0.1, the 1:2 ordered hexagonal structure found in $Ba(Mg_{1/3}Nb_{2/3})O_3$ (BMN) was transformed into 1:1 ordered cubic structure. The 1:1 ordered cubic structure was maintained up to x=0.7. However, when x exceeded 0.7, BLMN was transformed 1:1 ordered structure which has cation displacement and in-phase and anti-phase tilt of octahedra.

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Crystal Structure of Ba(Mg1/3Nb2/3)O3 - La(Mg2/3Nb1/3)O3Complex Perovskite Compound (Ba(Mg1/3Nb2/3)O3 - La(Mg2/3Nb1/3)O3복합 페로브스카이트 화합물의 결정구조)

  • Paik, Jong-Hoo;Lee, Mi-Jae;Choi, Byung-Hyun;Jee, Mi-Jung;Lim, Eun-Kyeong;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.7
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    • pp.718-723
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    • 2004
  • Crystal structure of $(Ba-{1-x}La_x)[Mg_\frac{1+x}{3}}Nb_\frac{{2-x}{3}}]O_3$ (BLMN) ceramics with 0\leq1x \geq was investigated using synchrotron X-ray powder diffraction (XRD) and high reso(B $a_{l-x}$L $a_{x}$)[M $g_{(1+x)}$3/N $b_{(2-x)/3}$$O_3$lution transmission electron microscopy (HRTEM). When the La content, x, is above 0.1, the 1:2 ordered hexagonal structure found in Ba($Mg_\frac{1}{3}Nb_\frac{2}{3}})O_3$(BMN) was transformed into 1:1 ordered cubic structure. The 1:1 ordered cubic structure was maintained up to x=0.7. When x exceeded 0.7, however, BLMN was transformed into 1:1 ordered structure which has cation displacement and in-phase and anti-phase tilt of octahedra.

The Effect of Mg Deficiency on the Microwave Dielectric characteristics of $Ba(Mg_{1/3}Nb_{2/3})O_3$ Ceramics (Mg 결핍에 따른 $Ba(Mg_{1/3}Nb_{2/3})O_3$ 세라믹스의 마이크로파 유전특성)

  • Paik, Jong-Hoo;Lee, Mi-Jae;Choi, Byung-Hyun;Lee, Jong-Won;Jee, Mi-Jung;Lim, Eun-Kyeong;Nahm, Sahn;Lee, Hwack-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.46-50
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    • 2003
  • Crystal structure and microwave dielectric properties of $Ba(Mg_{1/3-x}Nb_{2/3})O_3$ (BMN) ceramics were investigated. $Ba(Mg_{1/3}Nb_{2/3})O_3$ has the 1:2 ordered hexagonal structure. The 1:2 ordering and relative density of specimens increased with small Mg deficiency(x). The variation of Q-value with Mg deficiency is very similar to that of 1:2 ordering and relative density. The highest $Q{\times}f_0$ achieved in this investigation is about 96,000 for $Ba(Mg_{1/3-0.02}Nb_{2/3})O_3$. The improvement of Q-value with Mg-deficiency is related to the increase of degree of ordering and relative density of the specimen.

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CYP1A1 Gene Polymorphisms: Modulator of Genetic Damage in Coal-Tar Workers

  • Giri, Shiv Kumar;Yadav, Anita;Kumar, Anil;Dev, Kapil;Gulati, Sachin;Gupta, Ranjan;Aggarwal, Neeraj;Gautam, Sanjeev Kumar
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.7
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    • pp.3409-3416
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    • 2012
  • Aim: It is well known that polycyclic aromatic hydrocarbons (PAHs) such as benzo (a) pyrene have carcinogenic properties and may cause many types of cancers in human populations. Genetic susceptibility might be due to variation in genes encoding for carcinogen metabolizing enzymes, such as cytochrome P-450 (CYP450). Our study aimed to investigate the effect of genetic polymorphisms of CYP1A1 (m1 and m2) on genetic damage in 115 coal-tar workers exposed to PAHs at their work place. Methods: Genetic polymorphisms of CYP1A1 were determined by the PCR-RFLP method. Comet and buccal micronucleus assays were used to evaluate genetic damage among 115 coal tar workers and 105 control subjects. Results: Both CYP1A1 m1 and CYP1A1 m2 heterozygous and homozygous (wt/mt+mt/mt) variants individually as well as synergistically showed significant association (P<0.05) with genetic damage as measured by tail moment (TM) and buccal micronuclei (BMN) frequencies in control and exposed subjects. Conclusion: In our study we found significant association of CYP1A1 m1 and m2 heterozygous (wt/mt)+homozygous (mt/mt) variants with genetic damage suggesting that these polymorphisms may modulate the effects of PAH exposure in occupational settings.

SOM-Based $R^{*}-Tree$ for Similarity Retrieval (자기 조직화 맵 기반 유사 검색 시스템)

  • O, Chang-Yun;Im, Dong-Ju;O, Gun-Seok;Bae, Sang-Hyeon
    • The KIPS Transactions:PartD
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    • v.8D no.5
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    • pp.507-512
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    • 2001
  • Feature-based similarity has become an important research issue in multimedia database systems. The features of multimedia data are useful for discriminating between multimedia objects. the performance of conventional multidimensional data structures tends to deteriorate as the number of dimensions of feature vectors increase. The $R^{*}-Tree$ is the most successful variant of the R-Tree. In this paper, we propose a SOM-based $R^{*}-Tree$ as a new indexing method for high-dimensional feature vectors. The SOM-based $R^{*}-Tree$ combines SOM and $R^{*}-Tree$ to achieve search performance more scalable to high-dimensionalties. Self-Organizingf Maps (SOMs) provide mapping from high-dimensional feature vectors onto a two-dimensional space. The map is called a topological feature map, and preserves the mutual relationships (similarity) in the feature spaces of input data, clustering mutually similar feature vectors in neighboring nodes. Each node of the topological feature map holds a codebook vector. We experimentally compare the retrieval time cost of a SOM-based $R^{*}-Tree$ with of an SOM and $R^{*}-Tree$ using color feature vectors extracted from 40,000 images. The results show that the SOM-based $R^{*}-Tree$ outperform both the SOM and $R^{*}-Tree$ due to reduction of the number of nodes to build $R^{*}-Tree$ and retrieval time cost.

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