• Title/Summary/Keyword: B.t. H-14

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High Coercive Nd-Fe-B Sintered Magnets for High Temperature Application

  • Kim, D.H.;Kim, A.S.;Lim, T.H.;Jang, T.S.
    • Journal of Magnetics
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    • v.14 no.1
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    • pp.27-30
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    • 2009
  • Various sintered magnets containing $28{\sim}31\;wt%$ Nd and $0{\sim}7\;wt%$ Dy were evaluated for coercivity and irreversible flux loss as a preliminary study to develop highly-coercive, high-temperature magnets that can be applied for driving motors in a hybrid vehicle. The sintered magnets were prepared in sequence of strip casting, HD treatment, jet milling, magnetic field pressing, sintering and post-annealing. Increasing Dy content and adjusting post-annealing temperature monotonically increased coercivity of magnets from about 14 kOe to 30 kOe. A magnet containing 28 wt% Nd and 7 wt% Dy exhibits a $(BH)_{max}$+$_i{H_c}$ value of almost 64. This is very close to what the automobile industry considers as the minimum value (65) for a hybrid vehicle system. Moreover, irreversible flux loss of the magnet was about 3% at $200^{\circ}C$, which is well less than the allowable limit (5%) to a driving motor in hybrid vehicles.

The Effects of Feeding Feed Additives Containing Microorganisms on Characteristics of Excreta in Finishing Pigs (비육돈에 미생물제제 급여시 분뇨 특성에 미치는 효과)

  • Kwag, J.H.;Choi, D.Y.;Park, Ch.H.;Kim, J.H.;Jeong, K.H.;Yang, Ch.B.;Yoo, Y.H.;Chen, H.S.;La, C.S.
    • Journal of Animal Environmental Science
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    • v.13 no.3
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    • pp.153-160
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    • 2007
  • Study for the effect of three different microbial feed additives(henceforth MA-A, MA-B, and MA-C) on feed coversion rate, and physical and chemical characteristics of swine finisher was conducted. MA-B had higher number of Lactobacillus spp. and yeast, compared to any other. The amylase activity of MA-B was also higher than any other. The daily feed intake rates of pigs fed control, MA-A, MA-B and MA-C were 3.15, 3.14, 3.31 and 3.42 kg, respectively. MA-C had the highest weight gain. However, there was no significant difference between treatments. The weights of feces daily excreted by pigs fed control, MA-A, MA-B, and MA-C were 2.14, 2.02, 2.18, and 2.23 kg/day, respectively. The volume of urine daily excreted by pigs fed control, MA-A, MA-B, and MA-C were 3.14, 3.26, 3.27, and $3.41\;{\ell}/day$, respectively. Water content, T-N, $P_{2}O_{5}$, and $K_{2}O$ in swine manure were not significantly different between treatments. The BOD were between 42,576 and $67,450\;mg/{\ell}$ for feces and were between 5,882.5 and $8,657.5\;mg/{\ell}$ for urine, respectively. The SS were between 138,000 and $180,000\;mg/{\ell}$ for feces and were between 875.0 and $1450.0mg/{\ell}$ for urine, respectively.

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Increased Stability of Bacillus polyfermenticus SCD in Low pH, High Temperature and High Glucose Concentration via Three Layer Coating (Bacillus polyfermenticus SCD의 Three Layer Coating에 의한 pH, 열, 높은 glucose 농도에 대한 안정성효과)

  • 이진옥;전경동;강재선;이재화
    • KSBB Journal
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    • v.19 no.3
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    • pp.221-225
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    • 2004
  • Bacillus polyfermenticus SCD derived from Bacillus sp., which is commonly called as Bisroot$^{ⓡ}$. The goal of this study, is to Increase stability of Bacillus polyfermenticus SCD in low pH, high temperature and high glucose concentration via three layer coating. The viability of coated Bacillus polyfermenticus SCD increased to 30%, 20%, 14% in the condition of pH 2 4 6 than that of uncoated Bacillus polyfermenticus SCD at 37$^{\circ}C$ for 4 h. Final viability of the coated Bacillus polyfermenticus SCD in 80$^{\circ}C$ increased to 40% than that of uncoated Bacillus polyfermenticus SCD. In high glucose concentration coated Bacillus polyfermenticus SCD is more stable than uncoated about 50%. In conclusion, the three layer coated Bacillus polyfermenticus SCD is very stable for low pH, high temperature and high glucose concentration.

Crystal Structure of Nalidixic Acid (Nalidixic Acid의 결정구조)

  • 김문집;신준철
    • Korean Journal of Crystallography
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    • v.6 no.2
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    • pp.98-102
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    • 1995
  • The crystal structure of -Ethyl-1,4-dihydro-7-methyl-1,8-naphthyridin-4-one-3-carboxylic acid [Nalicixic Acid] has been determined from single crystal X-ray diffraction study; C12H12N2O3, monoclinic, P21/c, a=8.910(2)Å, b=13.145(3)Å, c=9.370(3)Å, β =100.06(2)°, V=1080.6Å, T=293K, Z=4, CuKα(λ=1.5418Å). The molecular structure was solved by direct method and refined by full-matrix least squares to a final R=0.055 for 1555 unique observed [F0>4σ(F0)] reflections and 166 parameters. The conformation of the molecule is stabilized by an intramolecular O(17)-H(17)…O(14) hydrogen bond [2.525(2)Å, 144.3(10)°].

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Effect of Strip-cast Conditions on the Formation of Microstructures in Nd-Fe-B alloys (Strip-cast 조건이 Nd-Fe-B 합금의 미세조직 형성에 미치는 영향)

  • Lee, D.H.;Jang, T.S.;Kim, D.H.;Kim, Andrew S.
    • Journal of the Korean Magnetics Society
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    • v.12 no.1
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    • pp.34-40
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    • 2002
  • In order to improve the microstructure of the strip cast Nd-Fe-B alloys that are frequently used for production of high energy sintered magnets, influence of various strip casting conditions on the microstructure and phase formation and distribution were investigated. Nd-Fe-B strips consisting of microstructures suitable for preparation of high energy sintered magnets could be obtained when the wheel speed was below 5 m/s. The compositional limit that can avoid the crystallization of free iron in the as-cast state was estimated to be Nd$\_$14/Fe$\_$79/B$\_$7/. Regardless of the compositional variation, <001> preferred orientation of Nd$_2$Fe$\_$14/B normal to the strip surface was always occurred below 5 m/s, which would eventually enhance the grain alignment during pressing the powder under a magnetic field. While the coercivity of the strip cast alloys increased with the increase of the wheel speed, mainly due to the refinement of Nd$_2$Fe$\_$14/B grains, it decreased with the reduction of Nd content in the alloy composition as the formation of free iron increased.

Polarographic Studies on the Kinetics of Cu(II)-thiocyanate and the Adsorption Wave of Cu(I)-thiocyanate (Polarography에 依한 Cupric-thiocyanate의 Kinetics와 Cuprous-thiocyanate의 Adsorption Wave에 關한 硏究)

  • Hwang, Jung-Euy;Chung, Chong-Jae;Son, Moo-Young;Park, Yu-Chul
    • Journal of the Korean Chemical Society
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    • v.14 no.3
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    • pp.213-219
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    • 1970
  • In the presence of hydrogen peroxide, the effects of temperature and pH to the catalytic reaction velocity of cupric -thiocyanate and the quantities of reduction products adsorbed on the D.M.E. have been studied by polarographic method. According to these experiments, the following empirical equation has been derived for the relation among temperature $T_i$, concentration of hydrogen ion $pH_i$ and adsorbed cuprous-thiocyanate in moles/$cm^2Z_{ij}$, and rate constant log$K_{ij}$ $$log\;K_{ij}=\frac{1}{T_i}\{A(pH_j)+B\}+C(pH_j)+D$$ $$Z_{ij}=\frac{1}{T_i}\{{\alpha}(pH_j)^{\frac{1}{2}}+{\beta}\}+{\gamma}(pH_j)^{\frac{1}{2}}+{\delta}$$ where, A,B,C,D and {$\alpha},{\beta},{\gamma},{\delta}$ are constants. The Calculated values by both equations are well agreed with empirical values within 8% in the error.

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Investigation on the phonon behavior of MgB2 films via polarized Raman spectra

  • R. P. Putra;J. Y. Oh;G. H. An;H. S. Lee;B. Kang
    • Progress in Superconductivity and Cryogenics
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    • v.26 no.1
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    • pp.14-19
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    • 2024
  • In this study, we explore the anisotropy of electron-phonon coupling (EPC) constant in epitaxially grown MgB2 films on c-axis oriented Al2O3, examining its correlation with the critical temperature (Tc) and local structural disorder assessed through polarized Raman scattering. Analysis of the polarized Raman spectra reveals angle-dependent variations in the intensity of the phonon spectra. The Raman active mode originating from the boron plane, along with two additional phonon modes from the phonon density of states (PDOS) induced by lattice distortion, was distinctly observed. Persistent impurity scattering, likely attributed to oxygen diffusion, was noted at consistent frequencies across all measurement angles. The EPC values derived from the primary Raman active phonon do not significantly vary with changing observation angles, followed by that the Tc values calculated using the Allen and Dynes formula remain relatively constant across all polarization angles. Although the E2g phonon mode plays a crucial role in the EPC mechanism, the determination of Tc values in MgB2 involves not only electron-E2g coupling but also contributions from other phonon modes.