• Title/Summary/Keyword: Attached material

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Reduction of Nitrate using Nanoscale Zero-Valent Iron Supported on the Ion-Exchange Resin (이온교환 능력을 가진 지지체에 부착된 나노 영가철을 이용한 질산성 질소의 환원과 부산물 제거)

  • Park, Heesu;Park, Yong-Min;Jo, Yun-Seong;Oh, Soo-Kyeong;Kang, Sang-Yoon;Yoo, Kyoung-Min;Lee, Seong-Jae;Choi, Yong-Su;Lee, Sang-Hyup
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.6
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    • pp.679-687
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    • 2007
  • Nanoscale zero valent ion (nZVI) technology is emerging as an innovative method to treat contaminated groundwater. The activity of nZVI is very high due to their high specific surface area, and supporting this material can help to preserve its chemical nature by inhibiting oxidation. In this study, nZVI particles were attached to granular ion-exchange resin through borohydride reduction of ferrous ions, and chemical reduction of nitrate by this material was investigated as a potential technology to remove nitrate from groundwater. The pore structure and physical characteristics were measured and the change by the adsorption of nZVI was discussed. Batch tests were conducted to characterize the activity of the supported nZVI and the results indicated that the degradation of nitrate appeared to be a pseudo first-order reaction with the observed reaction rate constant of $0.425h^{-1}$ without pH control. The reduction process continued but at a much lower rate with a rate constant of $0.044h^{-1}$, which is likely limited by mass transfer. To assess the effects of other ions commonly found in groundwater, the same experiments were conducted in simulated groundwater with the same level of nitrate. In simulated groundwater, the rate constant was $0.078h^{-1}$ and it also reduced to $0.0021h^{-1}$ in later phase. The major limitation in application of ZVI for nitrate reduction is ammonium production. By using a support material with ion exchange capacity, the problem of ammonium release can be solved. The ammonium was not detected in the batch test, even when other competitive ions such as calcium and potassium existed.

A study on characteristics of magneto-dielectrics as the antenna substrate (안테나 기판으로 자성유전체 특성에 관한 연구)

  • Lee, Young-Soon;Yoo, Jin-Ha;Lee, Ga-Young;Cho, Yun-Ki;Kim, Ui-Jung;Oh, Byoung-Hee
    • Journal of Advanced Navigation Technology
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    • v.13 no.6
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    • pp.838-845
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    • 2009
  • In order to obtain magneto-dielectrics with various permmittivity and permeability which could be used as the antenna substrate, various magneto-dielectrics compounded of dielectric materials(such as silicon and epoxy resin) and magnetic materials(such as carbonyl iron, barium and strontium powder) were fabricated. The relative permittivity and permeability of those were measured by use of HP 4291B impedance analyzer. Based upon the measured results, inverted-F meander monopole antennas(IFA) which were printed on the magneto-dielectric substrates fabricated as film type were designed and fabricated to investigate into variations of antenna characteristics such as the resonant frequency and impedance bandwidth in comparison with use of dielectric substrate. Some simulated and measured results for the designed IFA were presented. Characteristics of magneto-dielectrics which are different according as the choice of magnetic material or the composition ratio between magnetic material and dielectric material is different have been discussed.

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Analysis on Thermal Performance of BIPV in Spandrel (스펜드럴부 적용 BIPV 모듈의 열 특성 분석)

  • Kim, Ha-Ryeon;Kim, Jin-Hee;Kang, Gi-Hwan;Yu, Gwon-Jong;Kim, Jun-Tae
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.364-369
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    • 2011
  • Recently, the cases of BIPV(Building-integrated Photovoltaic) have been increased with interest in renewable energy application for buildings. PV System in building can perform a variety of roles as an energy supplier, exterior materials, aesthetic element and etc. To apply PV modules in buildings, various factors should be considered, such as the installation angle and orientation of PV module, shading, and temperature. The temperature of PV modules that are attached to building surfaces especially is one of the most important factors, as it affects both the electrical efficiency of a PV module and the energy load in a building. BIPV modules designed as finished material for spandrels are presented in this paper. The purpose of this study is to analysis on the thermal performance characteristics of BIPV modules. This study dealt with different types of BIPV modules depending on the backside material, such as clear glass and backsheet. The analysis of monitoring data shows that the PV module temperature was closely related to the solar radiation on the BIPV module surface, and the BIPV used at the backside also had an effect on the PV module temperature that in turn determines its thermal performance.

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Study on Sludge Thickening with Mesh is Used as Filtration Msdia (여과분리재를 이용한 슬러지 농축에 관한 연구)

  • Kim, Boo-Gil;Park, Min-Soo
    • Journal of Environmental Science International
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    • v.15 no.10
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    • pp.945-949
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    • 2006
  • For a membrane bio-reactor, it is possible to fillet and separate activated sludge and effluent by head loss of centimeters, if non-woven fabric material is used as titration media. However, if non-woven fabric material is used to thicken high-concentration sludge, excessive sludge attachment causes the rapid decrease of flux. Mesh with fore sizes of $100{\mu}m,\;150{\mu}m,\;and\;200{\mu}m$ allows for easy separation of attached sludge. This study examined the possibility of mesh as filtration media. Existing close-flow filtration process, which requires maintaining sludge movement, makes It difficult to obtain high thickening rate. With a view of complementing this weakness, this study has made an experimental examination on how high-concentration sludge (about 3,000mg/L to 10,000mg/L) will be filtered and thickened when mesh module is submersed in the bio-reactor. Effluent flowed from the bottom of the bio-reactor by head loss of 65cm. In case of pore size of $100{\mu}m$, SS showed high recovery of 80% to 96%; therefore, it has been decided that mesh can be used as filtration media. Filtration lasted for more than 9 hours, until sludge with 9,000mg/L in MLSS concentration was thickened 9 times as dense. In the range from 3,610mg/L to 9,060mg/L in MLSS concentration, it was possible to obtain effluent with less than 2mg/L in MLSS concentration within 10 minutes.

Synthesis of Si-CNT-C Composites and Their Application to Lithium Ion Battery (실리콘-탄소나노튜브-탄소 복합체 제조 및 리튬이온전지 응용)

  • Kim, Chan Mi;Kim, Sun Kyung;Chang, Hankwon;Kil, Dae sup;Jang, Hee Dong
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.42-48
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    • 2018
  • Silicon has attracted extensive attention due to its high theoretical capacity, low discharge potential and non-toxicity as anode material for lithium ion batteries. In this study, Si-CNT-C composites were fabricated for use as a high-efficiency anode material in a lithium ion battery. Aerosol self-assembly and post-heat treatment processes were employed to fabricate the composites. The morphology of the Si-CNT-C composites was spherical and an average particle size was $2.72{\mu}m$. The size of the composite increased as concentration of Si and CNT increased in the precursor solution. In the Si-CNT-C composites, CNT and C carbonized from glucose were attached to the surface of Si particles. Electrochemical measurement showed that the cycle performance of Si-CNT-C composites was better than that of silicon particles.

Porosity Control in LSM Electrode Formation in Layered Plannar SOFC Module (적층 평판형 SOFC에서 LSM 전극의 기공 제어)

  • Lee, Won-Jun;Yeo, Dong-Hun;Shin, Hyo-Soon;Jeong, Dea-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.866-870
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    • 2014
  • In solid oxide fuel cell system, yttria-stabilized zirconia is generally adopted as the electrolyte, which has high strength and superior oxygen ion conductivity, and the air electrode and the fuel electrode are attached to this. Recently, new structure of 'layered planar SOFC module' was suggested to solve the reliability problem due to the high temperature stability of a sealing agent and a binding material. In this study to materialize the air electrode in a layered planar SOFC module, the LSM ink was coated to form homogeneous electrode in the channel after the ink preparation. As the porosity control agent, PMMA or active carbon powder was adopted with use of a commercial dispersant in ethanol. The optimal amounts of both the porosity control agents and the dispersant were determined. Four (4) vol% of the dispersant for the LSM-PMMA case and 15 vol% for LSM-carbon powder showed the lowest viscosities respectively to indicate the best dispersed states of the slurries. With PMMA and carbon powder, sintered LSM ink shows the relatively homogeneous distributions of pores and with increases of the agents, the porosities increased in both cases. From this, it can be thought that the amount of the PMMA or carbon powder could be used to control the porosity of the LSM ink.

Small-Scale Wind Energy Harvester Using PZT Based Piezoelectric Ceramic Fiber Composite Array (PZT계 압전 세라믹 파이버 어레이 복합체를 이용한 미소 풍력 에너지 하베스터)

  • Lee, Min-Seon;Na, Yong-Hyeon;Park, Jin-Woo;Jeong, Young-Hun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.5
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    • pp.418-425
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    • 2019
  • A piezoelectric ceramic fiber composite (PCFC) was successfully fabricated using $0.69Pb(Zr_{0.47}Ti_{0.53})O_3-0.31[Pb(Zn_{0.4}Ni_{0.6})_{1/3}Nb_{2/3}]O_3$ (PZT-PZNN) for use in small-scale wind energy harvesters. The PCFC was formed using an epoxy matrix material and an array of Ag/Pd-coated PZT-PZNN piezo-ceramic fibers sandwiched by Cu interdigitated electrode patterned polyethylene terephthalate film. The energy harvesting performance was evaluated in a custom-made wind tunnel while varying the wind speed and resistive load with two types of flutter wind energy harvesters. One had a five-PCFC array vertically clamped with a supporting acrylic rod while the other used the same structure but with a five-PCFC cantilever array. Stainless steel (thickness: $50{\mu}m$) was attached onto one side of the PCFC to form the PZT-PZNN cantilever. The output power, in general, increased with an increase in the wind speed from 2 m/s to 10 m/s for both energy harvesters. The highest output power of $15.1{\mu}W$ at $14k{\Omega}$ was obtained at a wind speed of 10 m/s for the flutter wind energy harvester with the PZT-PZNN cantilever array. The results presented here reveal the strong potential for wind energy harvester applications to supply sustainable power to various IoT micro-devices.

Design of a 10× Zoom Lens with an Expander for an MWIR Camera Using Athermal Material Composition Method (비열화 소재 구성 방법을 이용한 중적외선 카메라용 확장형 10배 줌 렌즈 설계)

  • Ryu, Tae-Sik;Park, Sung-Chan
    • Korean Journal of Optics and Photonics
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    • v.33 no.6
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    • pp.287-294
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    • 2022
  • This study presents a method for designing an athermal middle wavelength infrared (MWIR) zoom lens with the iterative selection of material compositions on an athermal glass map. The optical properties of glass for MWIR are generally very sensitive to temperature, compared with visible glass. To compensate for focus error due to temperature change, the non-athermalized zoom system requires a large amount of movement of a compensator, which results in an unstable zoom system. To solve this problem, the material compositions for an athermal zoom lens have effectively been obtained using the thermal aberration correction process analytically on an athermal glass map. An expander lens is used to enlarge the focal lengths of an original main zoom lens two times. Finally, while this expander is attached to an original athermal zoom system, the final zoom system equipped with this expander doubles the focal length ranges and has stable performance over a specified temperature range.

Application of Nano-TDR Health Monitoring System in Civil Engineering (나노-TDR센서를 이용한 토목구조물 모니터링 시스템)

  • Han, Heui-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.5 s.57
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    • pp.93-100
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    • 2009
  • This study presents reasonable relationships to estimate the deformation based on beam mechanism analysis and TDR(Time Domain Reflectometry) data. To declar the length points of co-axial cable installed in civil structure, Nano material ($BaTiO_3$ powders and silver mixture) is used on co-axial cables. From the laboratory test, nano material could make the correct information about attached cable points on beam, and TDR sensor system and Fourier series (data filter) found out the deformation of beam. Therefore it is concluded that the correct deformed information of beam were acquired by Nano-TDR and Fourier filter, they are much more effective to apply at health monitoring system in civil structure compared to conventional TDR or Fiber Optic Sensor (FOS) systems.

Flexibility Study of Silicon Thin Film Transferred on Flexible Substrate (폴리머 기판 위에 전사된 실리콘 박막의 기계적 유연성 연구)

  • Lee, Mi-Kyoung;Lee, Eun-Kyung;Yang, Min;Chon, Min-Woo;Lee, Hyouk;Lim, Jae Sung;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.3
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    • pp.23-29
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    • 2013
  • Development of flexible electronic devices has primarily focused on printing technology using organic materials. However, organic-based flexible electronics have several disadvantages, including low electrical performance and long-term reliability. Therefore, we fabricated nano- and micro-thick silicon film attached to the polymer substrate using transfer printing technology to investigate the feasibility of silicon-based flexible electronic devices with high performance and high flexibility. Flexibility of the fabricated samples was investigated using bending and stretching tests. The failure bending radius of the 200 nm-thick silicon film attached on a PI substrate was 4.5 mm, and the failure stretching strain was 1.8%. The failure bending radius of the micro-thick silicon film attached on a FPCB was 2 mm, and the failure strain was 3.5%, which showed superior flexibility compared with conventional silicon material. Improved flexibility was attributed to a buffering effect of the adhesive between the silicon film and the substrate. The superior flexibility of the thin silicon film demonstrates the possibility for flexible electronic devices with high performance.