• 한국대기환경학회지
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• 제13권6호
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• pp.475-486
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• 1997

The characteristics of atmospheric aerosols were investigated as a function of particle size and water solubility. The atmospheric aerosols were sampled with classifying into 12 size ranges by the use of Andersen low-pressure impactor. Collected aerosol particles were extracted by ultrapure water and filtered to be separated into water-soluble and insoluble components. The concentrations 12 elements in both components were determined by PIXE analysis. And the concentrations of 8 ions in the soluble component were analyzed by ion chromatography. In general, the mass size distribution of particulate matter was represented as a bimodal distribution. The mass size distributions of S$(SO_4^{2-}), K(K^+), Zn and NH_4^+$ skewed to the smaller size range and those of Si, Ca$(Ca^{2+}), Fe, Na^+ and Mg^{2+}$ skewed to the larger size range. They had roughly one peak in the fine and coarse particle region,respectively. On the other hand, the mass size distribution of Ti, Mn, Ni, Cu, $Cl^- and NO_3^-$ were represented as the bimodal distribution. Fe and Si in the aerosol particles extracted into pure water are existing in high insoluble state. Conversely, almost the whole of S is dissolved in water.

• Asian Journal of Atmospheric Environment
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• 제10권2호
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• pp.90-98
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• 2016

Total suspended particulates (TSP) in the atmosphere were collected for 2 weeks during winter in Muroran, Hokkaido, Japan, a typical iron-manufacturing city. The concentrations of polycyclic aromatic hydrocarbons (PAHs) and nitropolycyclic aromatic hydrocarbons (NPAHs) in TSP were determined by high-performance liquid chromatography (HPLC) using fluorescence and chemiluminescence detectors, respectively. No relationship was observed between the atmospheric PAH and NPAH concentration, or the atmospheric PAH and TSP concentration. However, there was a tendency that the atmospheric PAH concentration was higher when the wind blew from the coke-oven plant. Furthermore, the concentration ratios of 1-nitropyrene to pyrene, which is a suitable indicator of the contribution made by automobiles and coal combustion systems to urban air particulates, were smaller in Muroran and the values were close to those observed in particulates from coal combustion systems. Therefore, these results show that the PAH and NPAH compositions for Muroran are characteristic of an iron-manufacturing city.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2002년도 Proceedings of International Symposium on Remote Sensing
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• pp.3-6
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• 2002

In this study, we investigate the atmospheric environment changes in the aspect of optical remote sensing using surface observation data from 1971 to 2000 of Korea Meteorological Administration. Visibility, spatially averaged over Korean peninsula, is systematically reduced from about 28km to 18km during the last 30 years. It means that atmospheric conditions for the optical remote sensing over Korean peninsula are growing worse and worse due to the degradation of air quality. The 30-year average of cloud amount shows a strong seasonal variation, maximum(75%) in summer and minimum (35%) in autumn. Precipitation also shows a very similar variation pattern with cloud. The temperature and sea level pressure show a opposite seasonal change pattern, maximum(minimum in SLP) in summer and minimum(maximum in SLP) in winter, respectively. Relative humidiy(RH) is one of the variables mostly affected by urbanization or urban heat island. As a results, annual mean RH is decreased from 73% to 68% during last 30 years. When we take into account the favorable and unfavorable factors all together, summer and autumn are the worst and the best season for optical remote sensing in Korea.

• 한국대기환경학회지
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• 제18권3호
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• pp.193-204
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• 2002

To investigate the relationships between the atmospheric concentrations of PCBs and temperature, quantity of both parameters was performed at an urban site in Korea from July 1999 to January 2000. The strength of correlations between total PCB and temperature was found to be significant (r = 0.752, p < 0.001). It hence indicates that total PCB contents were affected sensitively by temperature change during the sampling period. The ratio of PCB homologs and Deca-CB(PCB 209) also behaved quite similarly to the change of temperature (r>0.60, p<0.05). This may be inferable with the progress of the gas/particle partitioning to the gas phase, especially for fri-and tetra-CBs. Because they have high vapor pressure, they generally exist in the gas phase. The Clausius-Clapeyron equation was applied to the atmospheric PCB data, relating PCB partial vapor pressure to inverse temperature. This may essentially represent the temperature-controlled transition between condensed phase and atmospheric gas phase. The slopes of the resulting plot with International Council for the Explanation of the Seas (ICES) congener ranged from -2810 to -5887, with significantly steep slope and $R^2$(p< 0.005) It was inferred that the PCB atmospheric concentration was also affected by change in the surrounding conditions such as soil, lakes and trees.

• 한국대기환경학회지
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• 제12권2호
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• pp.141-149
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• 1996

Lateral dispersion parameter(.sigma.$_{y}$) which is an important factor in atmospheric dispersion can be estimated byusing wind direction fluctuation(.sigma.$_{\theta}$). In this paper, we studied the characteristics of the .sigma.$_{\theta}$ in the Chunchon basin and calculated the .sig- ma.$_{y}$ by using the .sigma.$_{\theta}$. We could find some characteristics of the .sigma.$_{\theta}$ which showed small value, when the atmospheric condition was in weak unstable (C class) and neutral (D class). Moreover, when the atmospheric stability was neutral, there was no difference of .sigma.$_{\theta}$ with wind speed. On the other hand, .sigma.$_{\theta}$ showed large values at the strong unstable (A class) and strong stable (F class) condition with low wind speed. In this case, the .sigma.$_{\theta}$ increased as long as averaging time due to the long-period wind direction fluctuation by the terrain effect. In the result of calculation of .sigma.$_{y}$, it was smaller than that of pasquill-Gifford curve. Especially, when the atmospheric condition was in a neutral and stable, .sigma.$_{y}$ showed small increment as the downwind distance increased.creased.

• 한국대기환경학회지
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• 제2권2호
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• pp.60-65
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• 1986

Atmospheric particulates were collected at a site near the front gate of the Yonsei University using nine stages Andersen air sampler and the distribution of seasonal particle size was investigated. Rubber, Pb and Zn contents of the collected particulates in each stage were determined. Particle size distribution of atmospheric particulate, which was made by concentration distribution curve method, was usually divided into two groups, course (particles larger than 1 - 2 $\mu m in diameter$) and fine (particles smaller than 1 - 2 \mu m in diameter$) groups, regardless of sampling period. More than 80 percent of the total rubber contents in atmospheric particulates were larger than $5 \mu m$ in diameter, meaning that most of rubber particles were originated from tire tread. After benzene extraction for 4 hrs, the extracts were analyzed by Curie-point pyrolysis gas chromatography for rubber content. Pb and Zn contents were determined by atomic absorption spectroscopy. The annual average concentration of rubber particles was $4.2 \mu g/m^3$, which corresponded to 2.2% of the annual average total suspended particulates. Average concentration of styrene brtadiene rubber was about five times that of natural rubber. Annual average concentrations of Pb and Zn were $1.2 \mu g/m^3 and 0.4 \mu g/m^3$ respectively, which corresponded to about 0.7% and 0.2% of the annual average total suspended particulates.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제10권S_1호
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• pp.23-28
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• 2001

A new numerical weather prediction and dispersion model, the Operational Multi-scale Environment model with Grid Adaptivity(OMEGA) including an embedded Atmospheric Dispersion Model(ADM), is introduced as a next generation atmospheric simulation system for real-time hazard predictions, such as severe weather or the transport of hazardous release. OMEGA is based on an unstructured grid that can facilitate a continuously varying horizontal grid resolution ranging from 100 km down to 1 km and a vertical resolution from 20 -30 meters in the boundary layer to 1 km in the free atmosphere. OMEGA is also naturally scale spanning and time. In particular, the unstructured grid cells in the horizontal dimension can increase the local resolution to better capture the topography or important physical features of the atmospheric circulation and cloud dynamics. This means the OMEGA can readily adapt its grid to a stationary surface, terrain features, or dynamic features in an evolving weather pattern. While adaptive numerical techniques have yet to be extensively applied in atmospheric models, the OMEGA model is the first to exploit the adaptive nature of an unstructured gridding technique for atmospheric simulation and real-time hazard prediction. The purpose of this paper is to provide a detailed description of the OMEGA model, the OMEGA system, and a detailed comparison of OMEGA forecast results with observed data.

• 한국환경과학회지
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• 제18권4호
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• pp.375-388
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• 2009

Numerical simulation is essential to indicate the flow of the atmosphere in the region with a complicated topography which consists of many mountains in the inland while it is neighboring the seashore. Such complicated topography produces land and sea breeze as the mesoscale phenomenon of meteorology which results from the effect of the sea and inland. In the mesoscale simulation examines, the change of the temperature in relation to the one of the sea surface for the boundary condition and, in the inland, the interaction between the atmosphere and land surface reflecting the characteristic of the land surface. This research developed and simulated PNULSM to reflect both the SST and vegetation effect as a bottom boundary for detailed meteorological numerical simulation in coastal urban area. The result from four experiments performed according to this protocol revealed the change of temperature field and wind field depending on each effect. Therefore, the lower level of establishment of bottom boundary suitable for the characteristic of the region is necessary to figure out the atmospheric flow more precisely, and if the characteristic of the surface is improved to more realistic conditions, it will facilitate the simulation of regional environment.

• 한국대기환경학회지
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• 제8권2호
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• pp.121-127
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• 1992

This study was carried out to investigate the features of air pollutants in rainwater and trace their transported trajectories from other countries. Chemical analysis data of rainwater and suspended particulates collected at Seoul, Kanghwa, and Taean for three years were used to evaluate the effects of long-range transport of air pollutants. Scavenging theory on washout and rainout effect during a rainy period was applied to estimate whether pollutants in the precipitation were long-range transported or not. On the other hand, precipitation weighted surface wind were evaluated to analyze the effect from local sources on atmospheric concentrations. As a result, contribution of air pollutants caused by anthropogenic sources in the precipitation which was identified to be long range transported was confirmed significantly high and trajectory of these pollutants was to be equivalent to 850mb isobar. Although concentration of acidifying components increased in the precipitation, neutralization by alkaline soil components such as $Ca^{2+}$ and $Mg^{2+}$ was conspicuous especially during Yellow-sand period.

• 한국대기환경학회지
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• 제12권4호
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• pp.369-376
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• 1996

Major atmospheric stability classification methods were evaluated with meteorological data obtained by scoustic sounding profiler (SODAR/RASS) in Seoul. The Psequill classificatio method, the method most widely used because of its good agreement in respect of synoptic scope under the steady state, fails to describe the time lag, the response time on stability by heating or cooling caused by daily insolation or noctrunal surface radiation. Horizontal and vertical standard deviation of wind fluctuation $(\sigma_A and \sigma_E)$ method tend to classify night-time stable condition (E, F class) into unstable condition (A, B class). The classification matrix tables for Vogt's vertical temperature difference and wind speed using method ($\Delta$T $\cdot$ U) and bulk Richardson number (Rb) were amended for practical use over Seoul. The modified tables for $\Delta$T $\cdot$ U and Rb method were made by using comprehensive frequency distribution from Pasquill's method and other existing results, and the correlation coefficient(r) was equal to 0.829. It was confirmed that atmospheric stability could be changed with monitoring site characteristics, height and vertical difference between sensors of monitoring station, and classification method itself.