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Fabrication and characterization of the nano- and micro-particles applied dry adhesives (나노 또는 마이크로 입자의 전사를 이용한 건식 접착제의 제조 및 특성 분석)

  • Yu, Min Ji;Vu, Minh Canh;Han, Sukjin;Park, Jae Hong;Kim, Sung-Ryong
    • Journal of Adhesion and Interface
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    • v.20 no.1
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    • pp.23-28
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    • 2019
  • In this study, the micro- and nano-particles were used and their shapes were transferred into the polydimethylsiloxane (PDMS) film to fabricate the dry adhesives and their properties were investigated. The Cu nanoparticles of the sizes of 20 nm, 40 nm and 70 nm and the polymethylmethacrylate (PMMA) beads of the size of $5{\mu}m$ were used to transfer their images and the resultant properties of the dry adhesives were compared. The effects of particle size and materials on the mechanical property, tensile adhesion strength, light transmittance, surface morphology, water contact angle were studied. The dry adhesives obtained from the transfer process of Cu nanoparticles with the size of 20 nm resulted in the enhancement of tensile adhesion strength more than 300% compared to that of the bare PDMS. The formation of nanostructure of large surface area on the surface of the PDMS film by the Cu nanoparticles may responsible for the improvement. This study suggests that the use of nanoparticles during the fabrication of PDMS dry adhesives is easy and effective and could be applied to the fabrication of the medical patch.

Risk factors for hospital admission in revisiting patients to the emergency department with abdominal pain

  • Bae, Jung Kwang;Kim, Hye Jin;Ryu, Seokyong;Choi, Seung Woon;Kang, Tae Kyung;Oh, Sung Chan;Cho, Suk Jin;Lee, Sun Hwa
    • Journal of The Korean Society of Emergency Medicine
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    • v.29 no.6
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    • pp.679-686
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    • 2018
  • Objective: The aim of this study was to identify the clinical characteristics and risk factors associated with the admission of patients in the emergency department (ED) within 30 days after discharge. Methods: A retrospective, observational study was conducted on adult patients presenting with abdominal pain to the ED of a single, urban, university hospital, between January 2014 and December 2015, who revisited the ED within 30 days after discharge. Data was collected on the emergency severity index level, time to contact doctors, physical examination, laboratory tests, use of computed tomography (CT), and patient disposition on revisitation. The primary outcome was hospital admission following an ED revisit in the 30-day period after the first visit. Results: During the study period, 19,480 patients visited the ED with the chief complaint of abdominal pain, and 13,577 were discharged. A total of 251 patients (1.29%) revisited the ED within 30 days, of which 89 were eligible for the study. The primary outcome was associated with not performing a CT scan on the initial visit and an increased C-reactive protein (CRP) value. Receiver operating characteristic curve analysis showed that a cut-off baseline CRP value of >0.35 mg/dL can predict the primary outcome with a sensitivity and specificity of 75% and 62.1%, respectively (area under the curve, 0.701; 95% confidence interval, 0.569-0.833; P=0.007). Conclusion: An increased CRP value and not performing abdominal CT were associated with a higher rate of admission following ED revisits of patients with abdominal pain. Future prospective studies on the role of abdominal CT imaging in patients presenting to the ED with abdominal pain will be needed.

An approach for moment-rotation relationship and bearing strength of segment lining's joint (세그먼트 라이닝 이음부의 모멘트-회전 관계와 지압강도 계산)

  • Lee, Young Joon;Chung, Jee Seung
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.23 no.2
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    • pp.93-106
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    • 2021
  • In general, segment lining tunnel refers to a tunnel formed by connecting precast concrete segments as a ring and connecting such rings to each other in the longitudinal direction of the tunnel. As the structural properties of the segment lining is highly dependent on the behavior of the segment joints, thus correct modelling of joint behavior is crucial to understand and design the segment tunnel lining. When the tunnel is subjected to ground loads, the segment joint behaves like a hinge that resists rotation, and when the induced moment exceeds a certain limit of the rotation then it may enter into non-linear field. In understanding the effect of the segment joint on the lining behavior, a moment-rotation relationship of the segment joint was explored based on the Japanese practice and Janssen's approach commonly used in the actual design. This study also presents a method to determine the rotational stiffness of joint refer to the bearing strength. The rotation of the segment joint was estimated in virtual design conditions based on the existing models and the proposed method. And the sectional force of the segment lining and joint were calculated along with the estimated rotation. As the rotation at the segment joint increases, the joint contact area decreases, so the designer have to verify the segment joint for bearing strength as well. This paper suggests a consistent method to determine the rotational stiffness and bearing strength of joints.

The Structural Relationships between Job-Engagement, Self-Esteem, Positive Thinking on Image-Making Efficacy of Beauty Professionals (뷰티 종사자의 이미지메이킹 효능감에 의한 긍정적 사고, 자아존중감 및 직무몰입의 구조적 관계)

  • Lee, Yu-Rim;Yu, Jin-Woo;Kim, Jang-Hyeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.377-386
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    • 2020
  • The image of beauty professionals who have wide contact with consumers is an important factor that can increase satisfaction and loyalty in consumers by exerting a positive influence on them. The purpose of this study is to investigate the influence of, and relationships among, self-esteem, positive thinking, and job commitment on image-making efficacy in beauty professionals. The method and scope of this study were carried out by theoretical research related to image-making efficacy, positive thinking, self-esteem, job engagement, and survey research with beauty professionals located in Seoul and the Gyeonggi-do area. We used SPSS v. 23.0 and Amos v. 23.0 to analyze demographic characteristics, the coefficient of internal consistency of the survey items, descriptive statistics, Pearson's correlation, and the Sobel Test. The results of the study show that the image-making efficacy of beauty professionals had a positive (+) effect on self-esteem, positive thinking, and job commitment. Second, self-esteem in beauty professionals was found to exert a positive effect (+) on their positive thinking and job commitment. Third, positive thinking by beauty professionals contributed to a positive effect (+) on job commitment. Fourth, the study found that self-esteem and positive thinking mediated the relationship between beauty professionals' image-making efficacy and job commitment.

Vibration and Impact Transmission for each Variable of Woodpile Metamaterial (우드파일 메타물질의 변수 별 진동 및 충격에 끼치는 영향)

  • Ha, Young sun;Hwang, Hui Y.;Cheon, Seong S.
    • Composites Research
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    • v.34 no.3
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    • pp.155-160
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    • 2021
  • Metamaterials are complexes of elements that can create properties not found in naturally occurring materials, such as changing the direction of forces, creating negative stiffness, or altering vibration and impact properties. In the case of wood pile metamaterials that are easy to manufacture and have excellent performance in reducing vibration and shock in the vertical direction, basic research on variables affecting shock transmission is needed to reduce shock. Although research on impact reduction according to geometrical factors is being conducted recently, studies on the effect of material variables on impact reduction are insufficient. In this paper, finite element analysis was carried out by variablizing the geometrical properties (lamination angle, diameter, length) and material properties (modulus of elasticity, specific gravity, Poisson's ratio) of wood pile cylinders. Through finite element analysis, the shape of the wooden pile cylinder delivering impact was confirmed, and the effect of each variable on the reduction of impact force and energy was considered through main effect diagram analysis, and frequency band analysis was performed through fast Fourier transform. proceeded In order to reduce the impact force and vibration, it was found that the variables affecting the contact area of t he cylinder have a significant effect.

The Effects of Street Tree's Vertical Structures on Thermal Comfort (열쾌적성에 대한 가로수 수직적 구조의 영향 분석)

  • Lee, Su-Been;Choe, Hye-Yeong;Jo, Hyun-Kil;Yun, Young-Jo;Kil, Sung-Ho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.24 no.4
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    • pp.15-29
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    • 2021
  • Urban green spaces offer a variety of benefits to living things and humans. However, existing green spaces have been reduced and fragmented due to urbanization, and there is a limit to creating new large green spaces in densely developed cities. Street trees have fewer restrictions on land use, which can be a measure to secure green areas in cities. In Korea, excessive pruning is being done on some street trees for reasons such as blocking of building signboards, contact with electric wires, and restrictions on sidewalk widths. Therefore, it is necessary to quantitatively understand the relationship between the benefits provided by street trees and their structures to come up with an efficient and systematic planning and management plan for urban street trees. In this study, we quantitatively analyzed the relationship between the thermal comfort improvement by the shades of street trees and the vertical structure, planting environment, and types of street trees. To calculate the thermal comfort felt by human body, we calculated UTCI (Universal Thermal Climate Index) of each street tree. For the vertical structure of street trees, we used Terrestrial LiDAR and the point clouds of street tree's crown was sliced vertically at 1m intervals. We conducted a multiple regression analysis on the thermal comfort improvement using the variables we obtained from fields. As a result, in the case of a street tree's vertical structure, the lager the volume of tree's crown located 3-4m (β=0.298, p<.05) and 6-7m (β=0.568, p<.001) above clear length, the better the cooling effect. In addition, the thermal comfort improvement was assessed to decrease as the DBH increased (β=-0.435, p<.001). In general, the crown diameter and DBH are positively correlated, with a cooling effect occurring as crown diameter increases. In this study, the opposite result was obtained due to the small number of trees measured, so additional research is needed by increasing the number of tree samples. In the case of the planting environment, the effect of improving thermal comfort was higher in the shaded area of trees planted to the south (β=-0.541, p<.001). Since unsystematic management of street trees can deteriorate the function of them, quantitative evaluations of the vertical structure of street trees are required, which can provide specific measures for planning and management of urban street trees with thermal comfort effect.

Study on the Platinum Deposition in Membrane of Polymer Electrolyte Membrane Fuel Cell during Electrode Degradation Process (고분자전해질 연료전지의 전극 열화 과정에서 고분자막에 석출된 백금에 관한 연구)

  • Oh, Sohyeong;Gwon, Hyejin;Yoo, Donggeun;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.202-207
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    • 2022
  • The study on electrode degradation of Proton Exchange Membrane Fuel Cell (PEMFC) was mainly studied on the particle growth and active area reduction of Pt on the electrode. The degradation of the electrode catalyst Pt in contact with the membrane affects the deterioration of the polymer membrane, but there are not many studies related to this. In this study, the phenomenon of the deposition of deteriorated Pt inside the polymer membrane during the accelerated electrode catalyst degradation test and its effects were studied. The voltage change (0.6 V ↔ 0.9 V) was repeated up to 30,000 cycles to accelerate the platinum degradation rate. When the voltage change cycle was repeated while oxygen was introduced into the cathode, the amount of Pt deposited inside the film was larger than when nitrogen was introduced. As the number of voltage change cycles increased, the amount of Pt deposited inside the membrane increased, and Pt dissolved in the cathode moved toward the anode, showing a uniform distribution throughout the membrane at 20,000 cycles. In the process of the accelerated electrode catalyst degradation test, the hydrogen crossover current density of the membrane did not change, and it was confirmed that the deposited Pt did not affect the durability of the membrane.

Improving the DIMP Sorption Capacity Durability of Zirconium Based Metal-Organic Frameworks Coated with Polydimethylsiloxane at High Humidity (PDMS 코팅을 통한 지르코늄 기반 금속유기골격체의 고습 환경에서 DIMP 흡착 성능 지속성 개선)

  • Jang, Wonhyeong;Jeong, Sangjo
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.296-301
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    • 2022
  • Due to the fact that zirconium based metal-organic frameworks (Zr-MOFs), such as UiO-66, have a large specific surface area and excellent selective adsorption capacity, Zr-MOFs are gaining attention as materials that can provide protection from the attack of chemical warfare agents in battleground. However, most of the metal-organic frameworks have an issue of selective adsorption capacity degraded by water molecules when exposed to the atmosphere, because of the weak metal-organic ligand bonds and the presence of voids. Therefore, polydimethylsiloxane (PDMS), a representative hydrophobic polymer material, was coated on the surface of UiO-66 to enhance the sustainability of the diisopropyl methylphosphonate (DIMP) sorption capacity in the battleground condition. Through the analysis of surface structure and organic functional group distribution of PDMS coated UiO-66, silicon was confirmed to be evenly coated. The contact angle increased by over 30° for the PDMS coated UiO-66, indicating that the hydrophobicity was improved. In addition, both the UiO-66 and PDMS coated UiO-66 were used as adsorbents for DIMP, a similar chemical warfare agent, to investigate the durability of adsorption capacity in a high humidity environment. The PDMS coated UiO-66 showed higher durability of adsorption capacity for 20 days than that of pristine UiO-66.

Fabrication of 3D Paper-based Analytical Device Using Double-Sided Imprinting Method for Metal Ion Detection (양면 인쇄법을 이용한 중금속 검출용 3D 종이 기반 분석장치 제작)

  • Jinsol, Choi;Heon-Ho, Jeong
    • Clean Technology
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    • v.28 no.4
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    • pp.323-330
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    • 2022
  • Microfluidic paper-based analytical devices (μPADs) have recently been in the spotlight for their applicability in point-of-care diagnostics and environmental material detection. This study presents a double-sided printing method for fabricating 3D-μPADs, providing simple and cost effective metal ion detection. The design of the 3D-μPAD was made into an acryl stamp by laser cutting and then coating it with a thin layer of PDMS using the spin-coating method. This fabricated stamp was used to form the 3D structure of the hydrophobic barrier through a double-sided contact printing method. The fabrication of the 3D hydrophobic barrier within a single sheet was optimized by controlling the spin-coating rate, reagent ratio and contacting time. The optimal conditions were found by analyzing the area change of the PDMS hydrophobic barrier and hydrophilic channel using ink with chromatography paper. Using the fabricated 3D-μPAD under optimized conditions, Ni2+, Cu2+, Hg2+, and pH were detected at different concentrations and displayed with color intensity in grayscale for quantitative analysis using ImageJ. This study demonstrated that a 3D-μPAD biosensor can be applied to detect metal ions without special analysis equipment. This 3D-μPAD provides a highly portable and rapid on-site monitoring platform for detecting multiple heavy metal ions with extremely high repeatability, which is useful for resource-limited areas and developing countries.

The healing pattern of a 4 mm proximal infrabony defect was not significantly different from a 2 mm defect adjacent to dental implant in a canine mandible

  • An, Min Kuk;Kim, Hyun Ju;Choi, Jin Uk;Kim, Kyoung-Hwa;Lee, Yong-Moo;Rhyu, In-Chul;Seol, Yang-Jo
    • Journal of Periodontal and Implant Science
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    • v.52 no.5
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    • pp.422-434
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    • 2022
  • Purpose: The purpose of this study was to evaluate and compare the healing patterns of 2-mm and 4-mm proximal infrabony defects adjacent to dental implants in canine mandibles. Methods: Four male beagles were used. Two groups were created: a 2-mm group (n=4) and a 4-mm group (n=4) depending on the horizontal dimension of proximal infrabony defects adjacent to implants. Bone healing patterns between the 2 groups were evaluated and compared at 8 and 16 weeks using radiographic, histological, histomorphometric, and fluorescent labelling analyses. Results: According to microcomputed tomography, the median bone volume fraction, bone mineral density, and the percentage of radiographic distance from the defect bottom to the most coronal bone-to-implant contact (radio-mcBIC) were 32.9%, 0.6 g/cm3, and 73.7% (8 weeks) and 45.7%, 0.7 g/cm3, and 76.0% (16 weeks) in the 2-mm group and 57.7%, 0.8 g/cm3, and 75.7% (8 weeks) and 50.9%, 0.8 g/cm3, and 74.7% (16 weeks) in the 4-mm group, respectively. According to histomorphometry, the median bone area fraction, mcBIC and the percentage of BIC amounted to 36.7%, 3.4 mm, and 58.4% (8 weeks) and 49.2%, 3.4 mm, and 70.2% (16 weeks) in the 2-mm group and 50.0%, 3.0 mm, and 64.8% (8 weeks) and 55.7%, 3.0 mm, and 69.6% (16 weeks) in the 4-mm group, respectively. No statistically significant differences were found between the groups for any variables (P>0.05). Conclusions: The proximal defects that measured 2 mm and 4 mm showed similar healing patterns at 8 and 16 weeks, and the top of bone formation in the defects was substantially limited to a maximum of 1.6 mm below the implant shoulder in both groups.