• Advances in materials Research
• /
• v.1 no.2
• /
• pp.115-128
• /
• 2012

The structural and electrical properties of $(1-x)Ba(Sm_{1/2}Nb_{1/2})O_3-xBaTiO_3$; ($0{\leq}x{\leq}1$) ceramics were prepared by conventional ceramic technique at $1375^{\circ}C$/7 h in air atmosphere. The crystal symmetry, space group and unit cell dimensions were derived from the X-ray diffraction (XRD) data using FullProf software whereas crystallite size and lattice strain were estimated from Williamson-Hall approach. XRD analysis of the compound indicated the formation of a single-phase cubic structure with the space group Pm m. Dielectric study revealed that the compound $0.75Ba(Sm_{1/2}Nb_{1/2})O_3-0.25BaTiO_3$ is having low and ${\varepsilon}^{\prime}$ and ${\varepsilon}^{{\prime}{\prime}}$ a low $T_{CC}$ (< 5%) in the working temperature range (up to+$100^{\circ}C$) which makes this composition suitable for capacitor application and may be designated as 'Stable Low-K' Class I material as per the specifications of the Electronic Industries Association. The correlated barrier hopping model was employed to successfully explain the mechanism of charge transport in the system. The ac conductivity data were used to evaluate the density of states at Fermi level, minimum hopping length and apparent activation energy of the compounds.

• Journal of the Korea Institute of Building Construction
• /
• v.12 no.1
• /
• pp.87-97
• /
• 2012

This paper presents a method of estimating the setting time of cement mortar incorporating recycled aggregate powder (RP) and cement kiln dust (CKD) at various curing temperatures by applying an equivalent age method. To estimate setting time, the equivalent age using apparent activation energy (Ea) was applied. Increasing RP and CKD leads to a shortened initial and final set. Ea at the initial set and final set obtained by Arrhenius function showed differences in response to mixture type. These were estimated to be from 10~19 KJ/mol in all mixtures, which is smaller than those of conventional mixture ranging from 30~50 KJ/mol. Based on the application of Ea to Freisleben Hansen and Pederson's equivalent age function, equivalent age is nearly constant, regardless of curing temperature and RP contents. This implies that the concept of maturity is applicable in estimating the setting time of concrete containing RP and CKD. A high correlation was observed between estimated setting time and measured setting time. A multiregression model was provided to determine setting time reflecting RP and CKD. Thus, the setting time estimation method studied herein can be applicable to concrete incorporating RP and CKD in the construction field.

• Proceedings of the International Microelectronics And Packaging Society Conference
• /
• 2001.11a
• /
• pp.75-87
• /
• 2001

Three different kinds of substrate used in this study : bare Cu substrate, Ni-P/Cu substrate with a Ni-P layer thickness of $5\mu\textrm{m},$ and Au/Ni-P/Cu substrate with the Ni-P and Au layers of $0.15\mu\textrm{m}$ and $5\mu\textrm{m}$ thickness respectively. The wettability of various Sn-base solders was affected by the substrate metal finish used, i.e., nickel, gold and copper. On the Au/Ni-F/Cu substrate, Sn-base solders wet better than any of the other substrate metal finishes tested. The interfacial reaction between various substrate and Sn-base solder was investigated at $70^{\circ}C,$ $100^{\circ}C,$ $120^{\circ}C,$ $150^{\circ}C,$ $170^{\circ}C$ and $200^{\circ}C$ for reaction times ranging from 0 day to 60 day. Intermetallic phases was formed along a Sn-base solder/ various substrate interface during solid-state aging. The apparent activation energy for growth of Sn-Ag/Cu, Sn-Ag-Bi/Cu, and Sn-Bi/Cu couples were 65.4, 88.6, and 127.9 Kj/mol, respectively. After isothermal aging, the fracture surface shoved various characteristics depending on aging temperature and time, and the types of BGA pad.

• Journal of the Korean Ceramic Society
• /
• v.32 no.4
• /
• pp.419-428
• /
• 1995

Polycrystalline silicon carbide (SiC) thick films were depostied by low pressure chemical vapor deposition (LPCVD) using CH3SiCl3 (MTS) and H2 gaseous mixture onto isotropic graphite substrate. Effects of deposition variables on the SiC film were investigated. Deposition rate had been found to be surface-reaction controlled below reactor temperature of 120$0^{\circ}C$ and mass-transport controlled over 125$0^{\circ}C$. Apparent activation energy value decreased below 120$0^{\circ}C$ and deposition rate decreased above 125$0^{\circ}C$ by depletion effect of the reactant gas in the direction of flow in a horizontal hot wall reactor. Microstructure of the as-deposited SiC films was strongly influenced by deposition temperature and position. Microstructural change occurred greater in the mass transport controlled region than surface reaction controlled region. The as-deposited SiC layers in this experiment showed stoichiometric composition and there were no polytype except for $\beta$-SiC. The preferred orientation plane of the polycrystalline SiC layers was (220) plane at a high reactant gas concentration in the mass transfer controlled region. As depletion effect of reactant concentration was increased, SiC films preferentially grow as (111) plane.

• Journal of the Korean Ceramic Society
• /
• v.24 no.5
• /
• pp.453-460
• /
• 1987

β'-sialon(Z=2.7) specimens with <30%wt. graphite as a reducing agent were decomposed at 1350°up to 1,450℃ under the atmosphere of 90% N2-10%H2. The decomposition of β'-sialon was calculated from the change in Z-value, and the formation of new minerals was identified from X-ray diffraction patterns. The decomposition reactions of sialon were considered to yield a stable sialon close to β-silicon nitride and some aluminum compounds according to the following equations; β'-sialon(s)＋C(s)＋N2(g)→β2-sialon(metastable)＋β3-sialon(stalbe phase) β2-sialon(s)＋C(s)＋N2(g)→β3-sialon(s)＋AlN(s)＋α-Al2O3(s)＋15R(s)＋SiO(g)＋Al2O(g)＋CO(g) Z-value; β2( 3.5)>β'( 2.7)>β3( 0.5) The decomposition rate of sialon was controlled by two mechanisms ; One was characterized by the interface area of contact, corresponding to an apparent activation energy of 50.5Kcal/mol in the initial stage, and the other by the diffusion, corresponding to that of 104.3Kcal/mol in the final stage of the decomposition.

• Economic and Environmental Geology
• /
• v.33 no.1
• /
• pp.61-75
• /
• 2000

Through modeling fault network using thin plate finite element technique in the San Andreas Fault system with slip rate over 1mm/year, as well as elevation, heat flow, earthquakes, geodetic data and crustal thickness, we compare the results with velocity boundary conditions of plate based on the NUVEL-1 plate model and the approximation of deformation in the Great Basin region. The frictional and dislocation creep constants of the crust are calculated to reproduce the observed variations in the maximum depth of seismicity which corresponds to the temperature ranging from $350^{\circ}C$ to $410^{\circ}C$. The rheologic constants are defined by the coefficient of friction on faults, and the apparent activation energy for creep in the lower crust. Two parameters above represent systematic variations in three experiments. The pattern of model indicates that the friction coefficient of major faults is 0.17~0.25. we test whether the weakness of faults is uniform or proportional to net slip. The geologic data show a good agreement when fault weakness is a trend of an additional 30% slip dependent weakening of the San Andreas. The results of study suggest that all weakening is slip dependent. The best models can be explained by the available data with RMS mismatch of as little as 3mm/year, so their predictions can be closely related with seismic hazard estimation, at least along faults where no data are available.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.15 no.3 s.39
• /
• pp.271-280
• /
• 1991

Emulsion graft copolymerization of MMA onto cotton fiber using Ce(IV) salt as an initiator was carried out. Graft yield and graft efficiency were observed according to the kinds and concentrations of emulsifier and polymerization conditions. The physical properties of MMA grafted cotton fabric were investigated. The results of this study were as follows: 1. The heighest graft yield of emulsion graft polymerization occurred at the concentration below cmc of emulsifier, which was different from emulsion polymerization. Nonionic sur- factant as an emulsifier was more effective than anionic one. 2. The highest graft yield was obtained at the initiator concentration $1{\times}10^{-2}mol/l$. The viscometric molecular weight of PMMA was in the order of 106. 3. As reaction time increased, the graft yield increased but the graft efficiency decreased. 4. Elevation of reaction temperature resulted in increase of graft yield. The apparent activation energy of MMA graft polymerization was 4.72 Kcal/mol. 5. Physical properties of MMA grafted cotton fabric varied with increase of grafting. Thickness and stiffness showed a noticeable increase, whereas tensile strength and elongation was slightly increased. Crease recovery increased as the graft yield increase up to $50\%$ and decreased thereafter.

• Transactions of Materials Processing
• /
• v.18 no.7
• /
• pp.544-549
• /
• 2009

This study aimed to elucidate the deformation mechanism during low-temperature superplasticity of fine-grained Ti-6Al-2Sn-4Zr-2Mo-0.1Si alloy in the context of constitutive equation. For this purpose, initial coarse equiaxed microstructure was refined to $2.2{\mu}m$ via dynamic globularization. Globularized microstructure exhibited large superplastic elongations(434-826%) at temperatures of $650-750^{\circ}C$ and strain rate of $10^{-4}s^{-1}$. It was found that the main deformation mechanism of fine-grained material was grain boundary sliding accommodated by dislocation motion with both stress exponent (n) and grain size exponent (p) values of 2. When the alpha grain size, not sub-grain size, was considered to be an effective grain size, the apparent activation energy for low-temperature superplasticity of the present alloy(169kJ/mol) was closed to that of Ti-6Al-4V alloy(160kJ/mol).

• BMB Reports
• /
• v.39 no.4
• /
• pp.394-399
• /
• 2006

The transport of putrescine into a moderately salt tolerant cyanobacterium Synechocystis sp. PCC 6803 was characterized by measuring the uptake of radioactively-labeled putrescine. Putrescine transport showed saturation kinetics with an apparent $K_m$ of $92{\pm}10\;{\mu}M$ and $V_{max}$ of $0.33{\pm}0.05\;nmol/min/mg$ protein. The transport of putrescine was pH-dependent with highest activity at pH 7.0. Strong inhibition of putrescine transport was caused by spermine and spermidine whereas only slight inhibition was observed by the addition of various amino acids. These results suggest that the transport system in Synechocystis sp. PCC 6803 is highly specific for polyamines. Putrescine transport is energy-dependent as evidenced by the inhibition by various metabolic inhibitors and ionophores. Slow growth was observed in cells grown under salt stress. Addition of low concentration of putrescine could restore growth almost to the level observed in the absence of salt stress. Upshift of the external osmolality generated by either NaCl or sorbitol caused an increased putrescine transport with an optimum 2-fold increase at 20 mosmol/kg. The stimulation of putrescine transport mediated by osmotic upshift was abolished in chloramphenicol-treated cells, suggesting possible involvement of an inducible transport system.

• Journal of Powder Materials
• /
• v.19 no.2
• /
• pp.134-139
• /
• 2012

P/M coppers are subjected to the isothermal compression tests at the strain rate ranging from 0.01 to 10.0 $s^{-1}$ and the temperature from 200 to $800^{\circ}C$. The processing map reveals the dynamic recrystallization (DRX) domain in the following temperature and strain rate ranges: $600-800^{\circ}C$ and 0.01-10.0 $s^{-1}$, respectively. In the domain, the region at temperature of $600^{\circ}C$ and strain rate of $10^{-2}s^{-1}$ shows peak efficiency. From the kinetic analysis, the apparent activation energy in the DRX domain is 190.67 kJ/mol and it suggests that lattice self-diffusion is the rate controlling mechanism.