• Journal of Hydrogen and New Energy
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• v.9 no.4
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• pp.161-167
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• 1998

It has been investigated the effects of alloying elements and binders on the corrosion behavior of metal hydride electrodes for anode of Ni/MH secondary battery. The $AB_5$-type alloys, $(LM)Ni_{4.49}Co_{0.1}Mn_{0.205}Al_{0.205}$ and $(LM)Ni_{3.6}Co_{0.7}Mn_{0.3}Al_{0.4}$, were used for the experiments. The electrodes were prepared by mixing and cold-pressing of alloy powders with Si sealent or PTFE powders, or cold-pressing the electroless copper coated alloy powders. The amount of copper coating was 20wt%. In order to examine corrosion behavior of the electrodes, the corrosion current and the current density, in 6M KOH aqueous solution after removal of oxygen in the solution, were measured by potentiodynamic and cyclic voltamo methods. The results showed that Co in the alloy increased corrosion resistance of the electrode whereas Ni decreased the stability of the electrode during the charge-discharge cycles. The electrode used Si sealant as a binder showed a lower corrosion current density than the electrode used PTFE and the electrode used Cu-coated alloy powders showed the best corrosion resistance.

• Journal of the Korean Electrochemical Society
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• v.10 no.1
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• pp.7-13
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• 2007

We synthesized and investigated $La_{0.75}Sr_{0.25}FeO_3$ by Glycine Nitrate Process(GNP) method used as cathode materials for SOFC(solid oxide fuel cell). Optimized amount of glycine is 3.17 mol. ICP elemental composition analysis indicated that the stoichiometry of the synthesized powders have nearly nominal values. SEM images and XRD patterns reveal that the synthesized powder has uniform size distribution and high degree of crystallinity. The sample powders were isostatically pressed to form a pellet. The green body was sintered at $1200^{\circ}C$ and the relative density of the sintered specimens were measured by Archimedes mettled. We measured electrochemical performance of LSF by AC impedance spectroscopy. Resistance of LSF shows lower value than that of LSM throughout all temperature region. The anode-supported solid oxide fuel cell showed a performance of $342mW/cm^2(0.7V,\;488mA/cm^2)$ at $750^{\circ}C$. The electrochemical characteristics of the single cell were examined by at impedance method.

• Journal of the Korean Electrochemical Society
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• v.7 no.4
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• pp.173-178
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• 2004

Silicon thin film were synthesized from silane and argon gas mixture directly on copper foil by rf PECVD and then lithium ion batteries were prepared from them employed as the negative electrodes without any further treatment. In the present study, two different kinds of silicon thin films, amorphous silicon and copper silicide were prepared by changing deposition temperature. Amorphous silicon film was prepared below $200^{\circ}C$, but copper silicide film with granular shape was formed by the reaction between silicon radical and diffused copper ions under elevating temperature above $400^{\circ}C$. The amorphous silicon film gives higher capacity than copper silicide, but the capacity decreases sharply with charge-discharge cycling. This is possibly due to severe volume changes. The cyclability is improved, however, by employing the copper silicide as a negative electrode. The copper silicide plays an important role as an active material of the electrode, which mitigates volume change cause by the existence of silicon and copper chemical bonding and provides low electrical resistance as well.

• Journal of the Korean Electrochemical Society
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• v.18 no.4
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• pp.161-171
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• 2015

High-yield zinc germanium oxide ($Zn_2GeO_4$) and zinc tin oxide ($Zn_2SnO_4$) nanowires were synthesized using a hydrothermal method. We investigated the electrochemical properties of these $Zn_2GeO_4$ and $Zn_2SnO_4$ nanowires as anode materials of lithium ion battery and sodium ion battery. The $Zn_2GeO_4$ and $Zn_2SnO_4$ nanowires showed excellent cycling performance of the lithium ion battery, with a maximum capacity of 1021 mAh/g and 692 mAh/g after 50 cycles, respectively, with a high Coulomb efficiency of 98 %. For the first time, we examined the cycling performance of $Zn_2GeO_4$ and $Zn_2SnO_4$ nanowires for sodium ion batteries. The maximum capacity is 168 mAh/g and 200 mAh/g after 50 cycles, respectively, with a high Coulomb efficiency of 97%. These nanowires are expected as promising electrode materials for the development of high-performance lithium ion batteries as well as sodium ion batteries.

• Resources Recycling
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• v.25 no.1
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• pp.24-30
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• 2016

The study to obtain tantalum concentration from electronic components (ECs) on Printed circuit board assembly (PCBA) of laptop was conducted. Electronic components on laptop PCBA were detached from boards by using self-developed experimental apparatus. The detached electronic components were sieved and 93.2 wt.% of tantalum capacitors were concentrated from the size interval from 2.80 mm to 6.35 mm. The tantalum capacitors were pulverized by hammer mill and electrodes (anode and cathode) were removed from the grinding products by using magnetic separators under the magnetic force of 300 Gauss. Finally, tantalum concentrate was concentrated from the magnetic separator products by using Knelson concentrator, and the maximum efficiency of 76.9% was achieved under the operating condition of bowl rotating speed of 200 rpm, and fluidizing water flowrate of 7 L/min. The grade and recovery of Ta concentrate under the condition were 81.1% and 78.8%, respectively.

• Journal of the Korean Institute of Gas
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• v.26 no.6
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• pp.16-23
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• 2022

In this study, characteristics of effect on hydrogen gas was investigated to hydrogen embrittlement by disk and tensile tests. The developed and commercial alloy was fabricated to a plate material made from an alloy ingot. The prepared materials were processed in the form of a disk to measure rupture pressure by hydrogen and helium gas at a rate of 0.1 to 1,000 bar/min. In the hydrogen pre-charged tensile test, a specimen was hydrogenated using an anode charging method, and the yield strength, ultimate tensile strength, elongation, and reduction in area rate were carried by a strain rate test. Also, the microstructure was observed to the fracture surface of the tensile test specimen. As a result, the developed materials satisfied endurable hydrogen embrittlement, and the fractured surface showed a brittleness fracture surface with a depth of several ㎛, but dimple due to ductile fracture could be observed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.4
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• pp.405-412
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• 2012

In the MCFC power generation system, the combustor supplies a high temperature mixture of gases to the cathode and heat to the reformer by using the off-gas from the anode; the off-gas includes high concentrations of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and avoid local heating, a catalytic combustor is usually adopted. Catalytic combustion is also generally accepted as one of the environmentally preferred alternatives for generation of heat and power from fossil fuels because of its complete combustion and low emissions of pollutants such as CO, UHC, and $NO_x$. In this study, experiments were conducted on catalytic combustion behavior in the presence of Pd-based catalysts for the BOP (Balance Of Plant) of 5 kW MCFC (Molten Carbonate Fuel Cell) power generation systems. Extensive investigations were carried out on the catalyst performance with the gaseous $CH_4$ fuel by changing such various parameters as $H_2$ addition, inlet temperature, excess air ratio, space velocity, catalyst type, and start-up schedule of the pilot system adopted in the BOP.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.251-251
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• 2016

For several decades, industrial processes consume a huge amount of raw water for various objects that consequently results in the generation of large amounts of wastewater. Wastewaters are consisting of complex mixture of different inorganic and organic compounds and some of them can be toxic, hazardous and hard to degrade. These effluents are mainly treated by conventional technologies such are aerobic and anaerobic treatment and chemical coagulation. But, these processes are not suitable for eliminating all hazardous chemical compounds form wastewater and generate a large amount of toxic sludge. Therefore, other processes have been studied and applied together with these techniques to enhance purification results. These include photocatalysis, absorption, advanced oxidation processes, and ozonation, but also have their own drawbacks. In recent years, electrochemical techniques have received attention as wastewater treatment process that could be show higher purification results. Among them, boron doped diamond (BDD) attract attention as electrochemical electrode due to good chemical and electrochemical stability, long lifetime and wide potential window that necessary properties for anode electrode. So, there are many researches about high quality BDD on Nb, Ta, W and Si substrates, but, their application in effluents treatment is not suitable due to high cost of metal and low conductivity of Si. To solve these problems, Ti has been candidate as substrate in consideration of cost and property. But there are adhesion issues that must be overcome to apply Ti as BDD substrate. Al, Cu, Ti and Nb thin films were deposited on Ti substrate to improve adhesion between substrate and BDD thin film. In this paper, BDD films were deposited by hot filament chemical vapor deposition (HF-CVD) method. Prior to deposition, cleaning processes were conducted in acetone, ethanol, and isopropyl alcohol (IPA) using sonification machine for 7 min, respectively. And metal layer with the thickness of 200 nm were deposited by DC magnetron sputtering (DCMS). To analyze microstructure X-ray diffraction (XRD, Bruker gads) and field emission scanning electron microscopy (FE-SEM, Hitachi) were used. It is confirmed that metal layer was effective to adhesion property and improved electrode property. Electrochemical measurements were carried out in a three electrode electrochemical cell containing a 0.5 % H2SO4 in deionized water. As a result, it is confirmed that metal inter layer heavily effect on BDD property by improving adhesion property due to suppressing formation of titanium carbide.

• Journal of the Korean Electrochemical Society
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• v.18 no.1
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• pp.17-23
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• 2015

$Li_4Ti_5O_{12}$ (LTO) have attracted much attention of researchers in the field of energy storage, because of their excellent stability for electric vehicle application. A main drawback of LTO is however their insulating nature due to the wide bandgap, which should be addressed to enhance the battery performance. In this study, we investigated the effect of water solubility of dopant precursor on the electrochemical characteristics of conducting LTO prepared by doping with $Cr^{3+}$ ions with the well-known wet-mixing method. The solubility of dopant precursor directly affected the morphology and the phase of doped LTO, and therefore their battery performance. In the case of employing the most soluble dopant precursor, $Cr(NO_3)_2$, the doped LTO demonstrated a markedly enhanced discharge capacity at high C-rate (130mAh/g @ 10C), which is about 2 times higher value than that of bare LTO.

• Journal of the Korean Electrochemical Society
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• v.3 no.2
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• pp.100-103
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• 2000

Polymeric gel electrolytes based on polyacrylronitile blended with poly(vinylidene fluoride-co-hexafluoro-propylene)(P(VdF-co-HFP), which were reinforced with glass fiber cloth(GFC) to increase the mechanical strength, were prepared for the practical use in secondary battery. Test cell consisting of $LiCoO_2$ as a cathode and mesophase pich-based ca.bon fiber (MCF) as an anode material showed a capacity of 110 mAh/g based on the cathode weight at 0.2C rate at room temperature. Over $80\%$ of initial capacity was retained after 400cycles, indicating that GFC is suitable for a reinforcing material to increase the mechanical strength of gel based electrolytes.