• Title/Summary/Keyword: Anisyltitanium compounds

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Synthesis of Anisyltitanium Compounds and their Reactivity (O-Anisyltitanium 화합물의 합성 및 반응성)

  • Koo, Bon-Joon;Kyung, Suk-Hun
    • Applied Biological Chemistry
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    • v.37 no.3
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    • pp.216-220
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    • 1994
  • Organoanisyltitanium compounds which have chlorine or isopropoxy group as ligand were synthesized and purely isolated. These new compounds were proved to be stable at $0^{\circ}C$ under argon atmosphere for some weeks. They react readily at low temperature with carbonyl compound, especially aldehyde and ketone, to coresponding alcohols. In competition reaction of aldehyde/ketone pair these organotitanium species showed complete aldehyde selectivity.

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