• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.355-362
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• 2009

The chemical modification of multi-wall carbon nanotubes (MWNTs) is an emerging area in material science. In the present study, hydroxyl functionalized oxovanadium(IV) Schiff-base; N,N'-bis(4-hydroxysalicylidene)-ethylene-1, 2-diamineoxovanadium(IV), [VO($(OH)_2$-salen)]; has been covalently anchored on modified MWNTs. The new modified MWNTs ([VO($(OH)_2$-salen)]-MWNTs]) have been characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron (XPS), UV-Vis, Diffuse reflectance (DRS), FT-IR spectroscopy and elemental analysis. The analytical data indicated a composition corresponding to the mononuclear complex of tetradentate Schiff-base ligand. The characterization of the data showed the absence of extraneous complex, retention of MWNTs and covalently anchored on modified MWNTs. Liquid-phase oxidation of cyclohexane with $H_2O_2$ to a mixture of cyclohexanone, cyclohexanol and cyclohexane-1,2-diol in $CH_3$CN have been reported using oxovanadium(IV) Schiff-base complex covalently anchored on modified MWNTs as catalysts. This catalyst is more selective toward cyclohexanol formation.

• Geotechnical Engineering
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• v.10 no.2
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• pp.69-84
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• 1994

In the present study, the application of a method of anchored or waste tyre wall in reinforcing the unstable slope is investigated. For design purposes a method of external stability analysis of the reinforced slope, together with a method of internal stability analysis of a wall itself, is presented. In order to predict the passive resistance expected in the anchor or waste tyre Meyerhof's bearing capacity theory is moapaed and experimental results of stress distribution of a pile section under lateral loading is used. Hurray's pull-out teat results are compared with the passive resistances of anchors predicted by the proposed method, and alto the advantages in design are compared with a method of reinforced earth wall with steel strips. Finally a design example of reinforced slope using anchored or caste tyre wall is presented and the overall stability is analyzed in detail by the proposed method of analysis. The efficiency of a method of anchored or waste tyre wall is further analyzed, comparing with a method of changing geometry of the origin리 unstable slope.

• Proceedings of the Korean Geotechical Society Conference
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• 1998.03a
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• pp.221-230
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• 1998

• Proceedings of the Korean Geotechical Society Conference
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• 2002.03a
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• pp.271-278
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• 2002

Recently, deep excavation for high-rise buildings occurs frequently to accommodate the rapidly increasing population in urban area. The stability of the earth retaining structures for deep excavation becomes more critical. The behavior of the earth retaining structures should be accurately predicted in a design stage, but the predicted behavior is different from the measured data due to uncertain soil properties and problems in construction. In this study the back-analysis using Powell's optimization theory was performed to match the measured deflection and results obtained from back-analysis were presented.

• Journal of the Korean Geotechnical Society
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• v.15 no.3
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• pp.113-129
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• 1999

In this study, a total of 12 types of sequential model tests were conducted at the laboratory for small scale anchored walls. The sequential behavior for flexible wall embedded in sand was investigated by varying degrees of relative density of Joomoonjin sand and flexibility number of model wall. The model tests were carried out in a 1000mm width, 1500mm length, and 1000mm high steel box. Load cells, pressure cells, displacement transducer and dial gauges were used to measure the anchor forces, lateral wall deflections, lateral earth pressures and vertical displacements of ground surface, respectively. Limited model tests were performed to examine the parameters for soil-wall interaction model and the formulation of analytical method was revised in order to predict the behavior of anchored wall in sand. Based on the model tests and proposed analytical method, model simulations were performed and the predictions by the present approach were compared with measurements by the model tests and predictions by other commercial programs. It is shown that the prediction by the present approach simulates qualitatively well the general trend observed for model test.

• Computers and Concrete
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• v.22 no.4
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• pp.383-393
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• 2018

Infill wall strengthening method has been widely used for seismic strengthening of deteriorated reinforced concrete (RC) frame structures with non-seismic details. Although such infill wall method can ensure sufficient lateral strengths of RC frame structures deteriorated in seismic performances with a low constructional cost, it generally requires quite cumbersome construction works due to its complex connection details between an infill wall and existing RC frame. In this study, an advanced seismic strengthening method using externally-anchored precast wall panels (EPCW) was developed to overcome the disadvantage inherent in the existing infill wall strengthening method. A total of four RC frame specimens were carefully designed and fabricated. Cyclic loading tests were then conducted to examine seismic performances of RC frame specimens strengthened using the EPCW method. Two specimens were fully strengthened using stocky precast wall panels with different connection details while one specimen was strengthened only in column perimeter with slender precast wall panels. Test results showed that the strength, stiffness, and energy dissipation capacity of RC frame specimens strengthened by EPCWs were improved compared to control frame specimens without strengthening.

• Journal of the Korean Geotechnical Society
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• v.15 no.6
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• pp.187-200
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• 1999

An extensive investigation is performed to analyze the behavior of tieback anchored wall. Finite element method is used and several case histories are collected to investigate the relationship of wall deflection, anchor unbonded length, and anchor load. The finite element method can calculate wall deflection with changing the anchor unbonded length and the anchor load. Wall deflection normalized by excavation height can be related to anchor location so that it may produce a zone chart. It is found that a different chart showing the relation of the wall deflection, the anchor load, and anchor unbonded length can be constructed. It is necessary to collect more case histories considering soil conditions and to perform FE analysis extensively with changing bonded length to extend the capability of this relation chart into practice.

• Journal of the Korean Geotechnical Society
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• v.23 no.5
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• pp.77-88
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• 2007

Lateral earth pressure and horizontal displacement of the diaphragm walls constructed in multi-soil layers were analyzed by the field instrumentation from six building construction sites in urban area. The distribution of the developed earth pressure of the anchored diaphragm walls during excavation shows approximately a trapezoid diagram. The maximum earth pressure of anchored diaphragm walls corresponds to $0.45{\gamma}H$ and the earth pressure acts at the upper part of the walls. The maximum earth pressure is two times larger than the empirical earth pressure of flexible walls in sands suggested by Terzaghi and Peck(1967), Tschebotarioff(1973), and Hong and Yun(1995a). The horizontal displacement of diaphragm walls is closely related with supporting systems such as struts, anchors, and so on. The horizontal displacement of anchored walls shows less than 0.1 percent of the excavated depth, and the horizontal displacement of strutted walls shows less than 0.25 percent of the excavated depth. Therefore, the restraining effect of horizontal displacement to the anchored diaphragm walls is larger than the strutted diaphragm walls. In addition, since the horizontal displacement of the diaphragm walls is lower than the criterion, $\delta=0.25%H$, used for control the anchored retention wall using soilder piles, the safety of excavation sites applied with the diaphragm walls is pretty excellent.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.03a
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• pp.14-25
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• 2010

The Yi Sun-Sin grand bridge is the suspension bridge which connects Myodo and Gwangyang. It is over the main navigation channel of Gwangyang Harbor. South anchorage(AN1, Myodo side) of the bridge is designed as rock anchored type. It sustains using the resistance of the underground rock's mass in Myodo. As this type of anchorage can minimize the exposure of the structure, It is economically efficient and environmentally friendly. North anchorage (AN2, Gwangyang side) is designed as the gravity type. This anchorage is 68 meters in diameter and use its own weight to support. Instead of normal rectangular diaphragm wall, the circular shape diaphragm wall is adopted to the north anchorage. It doesn't need to use internal temporary facilities, so it can significantly improve the constructability of the structure.

• Geotechnical Engineering
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• v.14 no.6
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• pp.81-92
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• 1998

A beam on elasto-plastic foundation modeling of soldier pile and woodlagging tieback walls or anchored walls was developed and tested. An instrumented full scale tieback wall in sand was constructed at the National Geotechnical Experimentation Bite located on Texas A&M University. The experimental earth pressure deflection relationship (p-y curves) was developed from the measurements. The construction sequence was simulated in the proposed method. The conceptual methodology of an anchored wall design was introduced by using the proposed method. The proposed method was evaluated with the measurements of case histories in sand and clay. A parametric research was performed to study the most influencing factors for the proposed method. It is concluded that the proposed method represents a significant improvement on the prediction of bending moments and deflections of the properly designed walls.