• 한국주조공학회지
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• 제11권6호
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• pp.455-462
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• 1991

The formation of brittle intermetallic compound such as $VAl_3$ tends tp lower the toughness of V-Al alloys. Also, due to the high melting point of vanadium, it is difficult to make that alloy by previous ingot metallurgy method. To depress the technique has been adopted. The effect of particle size and milling time on the phase has been thoroughly studied. For mechanical alloying, SPEX mixed/mill has been used. The milling time and the composition of V and Al are varied to find the optimum condition of forming amorphous phase. The X-Ray Diffrection pattern, microstructure detection, microhandess test, experiments are carried out to analyze MA product. When the final step is reached, no lamellar-structure is detected. The steady state condition is observed after 8 hours and 10 hours milling for 15wt.%Al and 30wt.%Al alloy, respectively. The microhardness continuously increases up to 10 hours after then it remains constant.

• 한국세라믹학회지
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• 제46권5호
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• pp.467-471
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• 2009

Effects of boron and carbon on the densification and thermal decomposition of an AlN-SiC-$TiB_2$ system were investigated. $SiO_2$ was mostly removed by the addition of carbon, while $Al_2O_3$ formed $Al_4O_4C$ and promoted the densification of the systems above $1850^{\circ}C$. Rather porous specimens were obtained without the additives after hot pressing at $2100^{\circ}C$, while densification was mostly completed at $2000^{\circ}C$ by using the additives. The sintering temperature decreased further to $1950^{\circ}C$ by applying spark plasma sintering. The additives promoted the shrinkage of AlN by forming a liquid phase which was originated from the carbo- and boro-thermal reduction of $Al_2O_3$ and AlN.

• 대한기계학회논문집
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• 제11권3호
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• pp.509-518
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• 1987

본 연구에서는 냉간 축대칭 전방 압출에 가중잔류항법을 적용하여 재료의 가 공 경화 및 강소성 경계를 고려하는 프로그램을 개발하여 변형도, 응력, 변형력, 강소 성 경계등을 FEM과 동일한 조건에서 비교 해석하고 다른 공정에 적용할 수 있게 하고 또한 곡면다이와 원추형다이를 설계 제작하여 다이의 형상과 단면 감소율이 변형도와 응력 분포에 미치는 영향을 검토하고 압출된 제품의 성질을 분석하여 실제 공정에 이 바지하며 이론 계산과 실험을 비교함이 목적이다.

• 한국표면공학회지
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• 제53권5호
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• pp.201-206
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• 2020

A SiOxCy(-H) thin film was synthesized by atmospheric pressure dielectric barrier discharge(APDBD), and a SiO₂-like layer was formed on the surface of the film by oxidation treatment using oxygen plasma. Hexamethylcyclotrisiloxane was used as a precursor for the SiOxCy(-H) synthesis, and He gas was used for stabilizing APDBD. Oxygen permeability was evaluated by forming an oxidized SiOxCy(-H) thin film on a PET film. When the single-layer oxidized SiOxCy(-H) film was coated on the PET, the oxygen gas permeability decreased by 46% compared with bare PET. In case of three-layer oxidized SiOxCy(-H) film, the oxygen gas permeability decreased by 73%. The oxygen permeability was affected by the thickness of the SiO₂-like layer formed by oxidation treatment rather than the thickness of the SiOxCy(-H) film. The excellent corrosion resistance was demonstrated by coating an oxidized SiOxCy(-H) thin film on the silver-coated aluminum PCB for light emitting diode (LED).

• 한국재료학회지
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• 제12권7호
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• pp.533-539
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• 2002

Porous anodic aluminum oxide layer for nano templates was prepared in acidic solutions. In order to investigate effects of 2nd anodization on ordered formation behaviors of the porous oxide layers, electrochemical and microstructural studies were performed, primarily using TEM, FE- SEM, AFM, and Ultramicrotomy. The pore diameter of the anodic oxide layer increased approximately linearly with increasing voltages, and to the contrary, the pore density decreased. It was shown that 2nd anodizing on the cell base after dissolving 1st anodic oxide layer was remarkably effective for forming ordered array of the pores, comparing with the case for 1st anodization only. And for controlling the diameter of pores, widening method by chemical dissolution seemed more practical than by electrochemical methods.

• 한국정밀공학회지
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• 제16권9호
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• pp.123-134
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• 1999

A new forming technology has been developed to fabricate near-net shape components by using aluminum alloys with globular microstructure. The estimations of filling characteristic in the forging simulation with arbitrarily shaped dies of SSM are calculated by finite element method with proposed algorithm. The proposed model and various boundary conditions for arbitrarily shaped die are investigated with the coupling calculation between the liquid phase flow and the solid phase deformation. The simulation processes with arbitrarily shaped dies are performed on the isothermal conditions and axisymmetric problems. To analyze the forging process simulation with SSM, new stress-strain relationship for semi-solid behaviour is described, and forging the liquid flow. Furthermore, For the purpose of getting net shape of SSM, it is important to be obtain a solid fraction in forging process with arbitrarily shaped dies. To produce a automotive part which have good mechanical properties, the filling pattern in accordance with die velocity and solid fraction distribution has to be estimated for arbitrarily shaped die.

• 한국표면공학회지
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• 제32권1호
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• pp.49-60
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• 1999

The protective oxide scales and coatings formed on high temperature materials must be preserved in high temperature atmosphere. And the thermal stresses induced by thermal cycling and the growth stresses by the formation of oxide scales can cause the loss of adherence and spalling of the oxide scales and coated layers. Among the coating processes Al diffusion coating is favored due to thermochemical stability and superior adherence in an hostile atmosphere. In this study, protective oxide forming element, Al was coated on Ni, Inconel 600 and 690 by diffusion coating process varying coating temperature and time. And the surface stability and adherence of oxide scales formed on those Al diffusion coated materials were evaluated by thermal cycling test. Al diffusion coated specimens showed superior cyclic oxidation resistance compared to bare ones and specimens coated for longer period had better cyclic oxidation resistance, due to the abundant amount of Al in the coated layer. Meanwhile Al diffusion coated Inconel 600 and 690 showed improved cyclic oxidation resistance by the effect of Al in the coated layer and Cr in the substrate. Comparing both Al diffusion coated Inconel 600 and 690, Al diffusion coated Inconel 690 maintained better adhesion between coated layer and substrate by virtue of the bridging effect resulting from the segregation of Cr in the interdiffusion zone.

• 한국전기전자재료학회논문지
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• 제34권2호
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• pp.105-109
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• 2021

CNT fiber has been in the spotlight as a conductor, but the conductivity of CNT fibers do not match that of CNT. This study reveals that the conductivity of CNT fiber can be improved by depositing Al/Cu through vacuum evaporation. Cu is commonly used for deposition on CNT fibers. But low bonding strength of the interface between CNT and Cu could be a disadvantage. To overcome this, Al was deposited on the CNT fiber for forming aluminum carbide islands to increase the interfacial bonding strength. The conductivity characteristics were improved as the deposition time increased. The resistance was measured as a function of temperature, demonstrating that the temperature coefficient of resistance (TCR) is improved to be 241 ppm/℃ in comparison with that of as-received CNT fibers at -1,251 ppm/℃, when the CNT fibers are deposited with Al and Cu, respectively, for 90s and for 540s.

• Advances in Computational Design
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• 제7권2호
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• pp.129-137
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• 2022

Compo-casting method is one of the popular technique to produce metal based matrix composites. But, one of the main challenges in this process is un-uniform spreading of reinforced subdivisions (particles) inside the metallic matrix and the lack of desirable mechanical properties of the final produced composites due to the low bonding strength among the metal matrix and reinforcement particles. To remove these difficulties and to promote the mechanical properties of these kind of composites, the WARM ARB technique was utilized as supplementary technique to heighten the mechanical and microstructural evolution of the casted Al/Al₂O₃ composite strips. The microstructure evolution and mechanical properties of these composites have been considered versus different WARM ARB cycles by tensile test, average Vickers micro hardness test, wear test and scanning electron microscopy (SEM). The SEM results revealed that during the higher warm- ARB cycles, big alumina clusters are broken and make a uniform distribution of alumina particles. It was shown that cumulating the forming cycles improved the mechanical properties of composites. In general, combined compo-casting and ARB process would consent making Al/Al₂O₃ composites with high consistency, good microstructural and mechanical properties.

• 대한방사성의약품학회지
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• 제7권1호
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• pp.22-32
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• 2021

Fluorine-18 is by far the most widely exploited radionuclide in PET (positron emission tomography) radiochemistry. The physical half-life of fluorine-18 allows for chemical manipulation within a restricted timeframe, and cyclotron-produced fluoride ion has been widely applied in aliphatic and aromatic nucleophilic radiofluorinations to produce a variety of established radiotracers. Radiotracers have become more structurally complicated to address diverse targets in physiobiological systems. There is therefore an unmet need to complement traditional C-¹⁸F bond-forming radiofluorination with new and efficient radiolabeling techniques to tackle the myriad of possible chemical environments. This review discusses recent advances in organometallic fluorine-18 bond creation in ¹⁸F-radiochemistry. Although not widely employed, new radiolabeling strategies for constructing boron-¹⁸F, silicon-¹⁸F, aluminum-¹⁸F, and other metal-¹⁸F bonds are described in view of their potential use in the development of novel radiopharmaceuticals.