• Title/Summary/Keyword: Alumina addition

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Mechanical Properties of $Al_2O_3-AlN$ Particulate Composite ($Al_2O_3-AlN$계 입자복합체의 기계적 성질)

  • 김영우;박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.33 no.1
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    • pp.101-109
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    • 1996
  • The mechanical propertieso f sintered AlN with the addition of alumina were investigated The flexural strength of the AlN dispersed ALON specimens was higher than that of ALON and fracture toughness showed similar tendency. The high-temperature flexural strength of specimens which 50 and 64.3 mol% alumina was added to AlN was constant up to 100$0^{\circ}C$ with about 290 and 420 MPa respectively but abruptly decreased at 120$0^{\circ}C$ In the specimens which contained 5 and 30mol% alumina the flexural strength increased to about 14% at 100$0^{\circ}C$ and did not decrease at 120$0^{\circ}C$ compared to at room temperature.

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The effect of stable oxide dispersoid on the high temperature oxidation behavior of Ni-Cr alloys (Ni-Cr 합금의 고온산화특성에 미치는 안정한 산화물 분산체 효과)

  • 유재민;박상환;강성군
    • Journal of the Korean institute of surface engineering
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    • v.24 no.4
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    • pp.222-229
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    • 1991
  • The oxidation behavior of Ni-6wt.% Cr alloys with various concentration of alumina dispersions(5vol.% 10vol.%) was determined at 1000 and 110$0^{\circ}C$ in oxygen of 1 atm. pressure. Some general observations were ascertained. These include: (a) the addition of alumina dispersoids significantly increased the oxidation resistance of Ni-6wt.% Cr alloy; (b) the rate of oxidation was distinctly decreased as a function of the volume percent of oxide dispersion; and (c) the presence of alumina dispersions promoted the formation of continous, protective Cr2O3 layer at 6 wt.% Cr.

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The Effects of Stabilizers on Adhesion of Electroless Copper Deposits on Alumina (Alumina 소지상의 무전해 동도금층의 밀착력에 미치는 안정제의 영향)

  • 최순돈;이희록
    • Journal of the Korean institute of surface engineering
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    • v.29 no.2
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    • pp.109-119
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    • 1996
  • In order to improve adhesion of electroless copper deposits on alumina substrates, some stabilizers such as 2-Mercapto Benzothiazole, thiourea and NaCN were added over a wide range of concentrations. The adhesion tests of the deposits were performed by using the cellophane tape and the push-pull scale. With the minor addition of the stabilizers, 2-MBT having a large molecular size gives poor adhesion, together with a finer grain structure, whereas Thiourea and NaCN show a high mechanical strength of the deposits. The high mechanical strength is supposed to be due to the easy desorption of hydrogen gas generated from the electroless reactions. A large amount of the three stabilizers decreases the adhesion for all the cases, resulting from strong adsorption of the stabilizers to the substrates.

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Influence of Zeta Potential on Fractional Precipitation of (+)-Dihydromyricetin ((+)-Dihydromyricetin 분별침전에 미치는 제타전위의 영향)

  • Ha, Geon-Soo;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.831-835
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    • 2015
  • This study evaluated the influence of the zeta potential of silica-alumina on the behavior in terms of purity, yield, and precipitate shape and size of fractional precipitation in the fractional precipitation process for the purification of (+)-dihydromyricetin. The optimal silica-alumina amount (surface area per working volume of reacting solution) for zeta potential control was $100mm^{-1}$. As the zeta potential value of silica-alumina increased, (+)-dihydromyricetin yield and precipitate size were increased. The use of silica with the highest value of the zeta potential (+4.99 mV) as a zeta potential-controlling material increased the (+)-dihydromyricetin yield by 2-fold compared with that of the use of alumina with the lowest value of the zeta potential (-19.00 mV). In addition, the (+)-dihydromyricetin yield and precipitate size was inversely correlated with the absolute value of the zeta potential. On the other hand, the purity of (+)-dihydromyricetin had almost no effect on changes in the zeta potential of silica-alumina.

Mechanical Properties of (Y, Nb)-TZP/Alumina Composites for Dental Implant Abutments (치과 임플란트 상부구조물용 (Y, Nb)-TZP/알루미나 복합체의 기계적 물성)

  • 정형호;김대준;한중석;이득용
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.508-512
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    • 2004
  • For abutment of dental implants, (Y, Nb)-TZP/Alumina composites were prepared by addition of 10-90 vol% alumina at an interval of 10 vol% into tetragonal zirconia solid solution which consists of 90.24 mol% Zr $O_2$, 5.31 mol% Y$_2$ $O_3$, and 4.45 mol% Nb$_2$O$\_$5/. Biaxial flexure strength and fracture toughness of composite were optimized by adding 10 vol% alumina, which resulted in 900 MPa and 8.9 MPam$\^$1/2/, respectively. The composite did not undergo low temperature degradation even after autoclave treatment at 200$^{\circ}C$ for 10 h. 65 of (Y, Nb)-TZP/Alumina composite abutments were employed into 40 patients and any adverse reaction, screw loosing, or fracture of abutments was not observed for the span of 2 years, indicating that the ceramic abutments can be safely used for restorations.

Characteristics by Surfactant Condition at Copper CMP (구리 CMP시 비이온 계면활성제의 알루리마 슬러리 안정성에 대한 효과)

  • Lee, Do-Won;Kim, Nam-Hoon;Kim, Sang-Yong;Seo, Yong-Jin;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1288-1291
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    • 2004
  • In this study, physical characteristics of alumina slurry on variation of pH value and the effect of non-ionic surfactants on alumina slurry for copper chemical mechanical planarization (CMP) slurry have been investigated. After pH value of the slurry with alumina abrasive was changed by adding various amount of $HNO^3$ or KOH, the differences of settling rate, particle size, and zeta-potential were estimated. Better settling rates were shown in slurries with alumina abrasive at near pH 1. Higher zeta-potential was shown at around pH 2 in alumina slurry and the point of zero charge (PZC) was measured at about pH $9\sim10$. Non-ionic surfactant was added in the slurry with 5wt% alumina abrasive to get its effect on slurry practically. Abrasive size was smaller increased when amount of surfactant increased in slurry with P-4 as abrasive; on the other side, it was smaller when amount of surfactant decreased with AES-12. Variation of zeta-potential has no tendency with adding surfactant; however, values of zeta-potential were between $35\sim50mV$. The proper amount of surfactant was $0.1\sim1.0wt%$ in slurry with P-4 and $0.5\sim1.0wt%$ in slurry with AES-12 respectively. Excellent dispersion stabilization was obtained by addition of non-ionic surfactant

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A study on properties of 400kN porcelain suspension insulator for transmission line by analyzing of raw materials (400kN 송전용 자기애자의 재질에 따른 특성 연구)

  • Choi, In-Hyuk;Choi, Jang-Hyun;Jung, Yoon-Hwan;Lee, Dong-Il;Jung, Gil-Jo;Min, Byeong-Wook
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1637-1639
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    • 2004
  • In order to analyze the physical and chemical characteristics of the home production porcelain insulators by change of the alumina addition amount, 36000lbs ball socket type suspension insulators which were manufactured in 1989, 1995 and 2001 removed in transmission line and an experiment was performed. By the result, 8 [wt.%] alumina that influences the mechanical properties and arc resistance properties in case of insulators that were manufactured in 1989 was contained, and the relative density and the fracture toughness of insulators appeared by 94.2% and 1.4 [MPa $M^{1/2}$], respectively. However, 12 [wt.%] alumina was contained in case of insulators that were manufactured in 1995, and the relative density and the fracture toughness of insulators appeared preferably lower by 92% and 1.3 [MPa $M^{1/2}$], respectively. Amount of alumina was contained most by 17 [wt.%] in case of insulators that were manufactured in 2001. It was confirmed that the electrical and mechanical characteristics such as the relative density and the fracture toughness appeared excellently by 96% and 1.7 [MPa $m^{1/2}$], respectively.

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Wetting Behavior of Dolomite Substrate by Liquid Fe-19%Cr-10%Ni Alloy at 1753K

  • Shin, Min-Soo;Lee, Joon-Ho;Park, Joo-Hyun
    • Korean Journal of Materials Research
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    • v.19 no.2
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    • pp.115-118
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    • 2009
  • The use of dolomite refractories has increased during the past several years in the manufacturing of clean steel during the stainless steelmaking process. However, at the same time, the use of dolomite refractories has led to what is known as the skull formation. In the present work, to understand the skull formation, the wetting characteristics of dolomite substrates by liquid Fe-19wt%Cr-10wt%Ni alloys in various oxygen partial pressures were initially investigated at 1753K using the sessile drop technique. For comparison, the wetting characteristics of alumina substrates were investigated with the same technique. It was found that the wetting index, (1+$cos{\theta}$), of dolomite is approximately 40% higher compared to those of alumina. In addition, the oxygen partial pressure to generate the surface oxide, which may capture the liquid metal on the refractory surface, for dolomite is much lower than that for alumina. From this study, it was concluded that the use of dolomite is much more closely associated with the skull formation compared to the use of alumina due to the stronger wettability and the surface oxide formation at a lower oxygen partial pressure of dolomite.

Effect of Alumina Coating on Mechanical Properties of SiC Whisker Reinforced Silicon Nitrate Ceramic Composite

  • Lee, Ki-Ju;Xu, Jing-Wen;Hwang, Woon-Suk;Cho, Won-Seung
    • Corrosion Science and Technology
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    • v.6 no.1
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    • pp.24-28
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    • 2007
  • Alumina coated SiC whiskers were prepared by homogeneous precipitation of aluminum sulfate. The Si3N4 composites reinforced with coated SiC whiskers were fabricated by hot-pressing at $1800^{\circ}C$ for 2 h under an $N_{2}$ atmosphere of 0.1 MPa to examine the effects of coated whiskers on the mechanical properties of SiC whisker reinforced $Si_{3}N_{4}$ composite. By the addition of alumina coated SiC whiskers instead of as received ones, the fracture toughness of composite was about 6.7 $MPam^{1/2}$ which was slightly lower than as received SiC whisker reinforced composite. This result seems to be caused by the fact that the crack deflection and whisker pull-out were decreased. Thus, alumina coated SiC whiskers were considered to form relatively strong interface bond with $Si_{3}N_{4}$ matrix.

The Effect of Paste Composition and Particle Size on the Alumina Ceramics Metallizing (Paste의 조성과 입도 변화가 알루미나 세라믹스의 Metallizing에 미치는 영향에 관한 연구)

  • 김태송;김성태;김종희
    • Journal of the Korean Ceramic Society
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    • v.30 no.5
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    • pp.347-356
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    • 1993
  • In joining alumina ceramics to metal by using Mo-Mn metallizing process the effects of metallizing thickness, temperature, and the composition of paste on the bond strength and the microstructure of joining interface were investigated. The bond strength variation in the range of metallizing temperature, 1350~155$0^{\circ}C$ was more than 150MPa above 145$0^{\circ}C$ and the optimum metallizing thickness was 30${\mu}{\textrm}{m}$. The optimum contents of Mn in Mo-Mn paste was 5% due to the bond strength decrease with the increase of addition. The effect of SiO2 addition in paste on bond strength was saturated around 200MPa. It was also observed that as the particle size of Mo decreased, the joinning with higher bond strength was shown in spite of low metallizing temperature.

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