• Title/Summary/Keyword: Alpha phase

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The Effect of Ginseng Extracts on the Photooxidation of Liposome I. The protective effect of the formation of hydroperoxides (Liposome의 광산화반응에 미치는 인삼추출물의 영향 제1보. Hydroperoxide 생성 억제 효과)

  • Baek, Tae-Hong;Kim, Yeong-Ho;Lee, Jun-Hong
    • Journal of Ginseng Research
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    • v.14 no.3
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    • pp.379-384
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    • 1990
  • In order to study the lipid peroxidation caused by light and the protective action it in biological memberane, reverse-phase evaporation liposome (REV) was employed as a model memberance and the effect of several antioxidants and ginseng water extracts were tested. In the presence of photosensitizer, liposome was oxidized easily and the oxidation index dut to the peroxidation was increased. The oxidation index of liposome was increased according to the increase in temperature. When dl-${\alpha}$-tocopherol, ${\beta}$-carotene or L-ascorbic acid was added into the reaction mixture, the photooxidation of liposome was inhibited. Ginseng water extract and crude saponin inhibited the rate of oxidation index of liposome in low concentration but increase in high concentration. On the other hand, when lipid hydroperoxide of liposome was tested by ferrothiocyanate method, ginseng water extract and crude saponin acted as antioxidants.

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Hydrogen Absorption Kinetics on Al/Pd Film in the $\alpha$ Phase (Al/Pd 박막의 수소 흡수 동역학[$\alpha$상])

  • Cho, Young-Sin
    • Journal of Hydrogen and New Energy
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    • v.18 no.3
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    • pp.334-341
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    • 2007
  • Al film(135.5 nm thick) with Pd film(39.6 nm thick) was made by thermal evaporation method. Electrical resistance change by hydrogen absorption and desorption was measured with four point measurement method. Even though Al film(135.5 nm thick) did not absorb any hydrogen at room temperature, Al/Pd film absorbed hydrogen at upto 640 torr pressure. Hydrogen absorption kinetics was monitored by measuring resistance change of the sample in the temperature range from $25^{\circ}C$ to $40^{\circ}C$. Absorption activation energy of Al/Pd film was about 10.7 and 17.7 kcal/mol H for 1st stage and last stage respectively at 1 torr hydrogen pressure. This activation values are bigger than that of Pd film, but are much less than that of Al film. This result indicates there is possibility that Al can be storage material for hydrogen by using Pd film evaporation on it.

Properties of $Sr_{0.8}Bi_{2.3}{(Ta_{1-x}Nb_{x})}_{2}O_{9+{\alpha}}$ Thin Films

  • Park, Sang-Jun;Jang, Gun-Eik
    • Transactions on Electrical and Electronic Materials
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    • v.1 no.1
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    • pp.22-25
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    • 2000
  • Polycrystalline SBTN layered ferroelectric thin film with various Nb mole ratios were prepared by sol-gel method Pt/ $SiO_2$/Si (100) substrates. The films were annealed at different temperature and characterized in terms of phase and microstructure. The films were crystallized with a high (105) diffraction intensity and had rodike structure, SBTN films fired at 800$^{circ}C$ revealed standard hysteresis loops with no fatigue for up to 10$^{10}$ cycles. At an applied voltage of 5V the dielectric constant($varepsilon$) , dissipation factor (tan $delta$), remanent polarization(ZPr) and coercive field(Ec) of typical S $r_{0.8}$B $i_{2.3}$(T $a_{1-x}$ N $b_{x}$) $O_{9+}$$alpha$/ thin film(x=0.1) prepared on Pt/ $SiO_2$/Si (100) were about 277.7, 0.042, 3.74$mu$C/$textrm{cm}^2$, and 24.8kv/cm respectively.ly.y. respectively.ly.y.y..

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Environmental Toxic Agents on Genetic Material and Cellular Ativity V. The Roles of DNA Polymerases on Mutagen-Induced DNA Repair Synthesis in Relation to Cell Cycle in Chinese Hamster Ovary Cells (환경성 유해요인이 유전물질과 세포활성에 미치는 영향 V. CHO세포에서 세포주기에 따라 돌연변이원에 의해 유발된 DNA회복합성에 미치는 DNA중합효소의 역할)

  • 엄경일;김춘광;신은주;문용석;이천복
    • Environmental Mutagens and Carcinogens
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    • v.9 no.1
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    • pp.23-32
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    • 1989
  • Chinese hamster ovary (CHO)-K1 cells echibited a differential sensitivity in the process of DNA repair synthesis induced by ethyl methanesulfonate (EMS) or bleomycin (BLM) in relation to cell cycle. Two assays were employed in this study: alkaline elution and unscheduled DNA synthesis. The post-treat-ment with aphidicolin (APC), an inhibitor of DNA polymerase alpha, inhibited DNA repair synthesis induced by EMS in G2 phase, while APC did not show any effect on BLM-induced DNA repair synthesis in all phases. On the other hands, the 2', 3'-dideoxythymidine (ddTTP), an inhibitor of DNA polymerase beta, inhibited DNA repair synthesis induced by EMS or BLM in both of G1 and G2 phases. These results suggested that the involvement of DNA polymerase alpha and beta in DNA repair was dependent on cell stage or used chemical agent.

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Volumetric Thermal Analysis of Hydrogen Desorption from Mg-13.5wt%Ni Hydride (Mg-13.5wt%Ni 합금 수소화합물의 수소방출에 대한 부피법에 의한 열분석)

  • HAN, JEONG SEB;PARK, KYUNG DUCK
    • Journal of Hydrogen and New Energy
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    • v.26 no.4
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    • pp.308-317
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    • 2015
  • To investigate the effect of microstructure on the formation of the desorption peak, the volumetric thermal analysis technique (VTA) was applied to the Mg-13.5 wt% Ni hydride system. The sample made by the HCS (hydriding combustion synthesis) process had two kinds of Mg microstructures. Linear heating was started with various constant heating rates. Only one peak was appeared in the case of the small initial hydrogen wt% (0.83 wt%). Yet, two peaks were appeared with increasing initial hydrogen wt% (1.85 and 3.73 wt%) when only Mg was hydrogenated. The first peak was formed through the evolution of hydrogen from $MgH_2$, made by eutectic Mg. The second peak was formed through the evolution of hydrogen from $MgH_2$, made by primary Mg. Therefore, this result shows that the microstructure also has a considerable effect on forming the desorption peak. We have also derived the hydrogen desorption equations by VTA to get apparent activation energy when the rate-controlling step for the desorption of the hydrided system is the diffusion of hydrogen through the ${\alpha}$ phase and the chemical reaction ${\beta}{\rightarrow}{\alpha}$.

Performance Analysis of a Geothermal Heat Pump System Operated by a Diesel Engine (I) - Soil temperature prediction in Pusan and Chinju - (엔진구동 지열 열펌프의 성능 분석 (I) - 부산.진주지방 지중온도 예측 -)

  • 김영복
    • Journal of Biosystems Engineering
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    • v.23 no.2
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    • pp.135-146
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    • 1998
  • The equation to predict the soil temprature of Pusan and Chinju city as a function of time and soil depth for the geothermal energy utilization system and agriculture was devised. The equation was $T(x,t)\;=\;Tm\;-\;To{\cdot}ExP(-{\xi}){\cdot}cos{{\omega}{\cdot}[t-to-x/(2{\cdot}{\alpha}{\cdot}{\omega})^{0.5}]}$ with the soil thermal diffusivity, ${\alpha},\;of\;0.4\;\textrm{m}^2/day,\;0.0375\;\textrm{m}^2/day$ and phase zero point, to, of 24 days, 22.4 days in Pusan and Chinju city, respectively, during ten years from 1987 to 1996. The predicted and measured soil temperatures agreed well with the coefficient of determination of 0.95 at the soil depth of 0.0, 0.5, 1.0, 3.0, 5.0 m. The maximum and minimum temperature in Pusan 3.7, $30.1^{\circ}C$ at soil surface and 14.3, $18.0^{\circ}C$ at the depth of 5.0 m. The total mean temperature of soil in Pusan and Chinju city was about 16.3, $16.0^{\circ}C$, respectively.

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Effect of Reverse Transformation on the Damping Capacity of High Manganease Austenitic Stainless Steel (고 Mn 오스테나이트계 스테인리스강의 감쇠능에 미치는 역변태의 영향)

  • Kang, C.Y.
    • Journal of Power System Engineering
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    • v.16 no.4
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    • pp.60-65
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    • 2012
  • This study was carried out to investigate the effect of reverse transformation on the damping capacity in high manganese austenitic stainless steel. ${\alpha}^{\prime}$-martensite was formed with the specific direction and surface relief by deformation. Over 95% of the austenite phase was transformed to deformation-induced ${\alpha}^{\prime}$-martensite by 70% cold rolling. Reverse transformation became rapid above an annealing temperature of $550^{\circ}C$, but there was no significant transformation above $700^{\circ}C$. In addition, with increasing annealing time at $700^{\circ}C$, reverse transformation was induced rapidly, but the transformation was almost completed at 10 min. Damping capacity was increased up to $700^{\circ}C$, and than unchanged with the increasing annealing temperature. Damping capacity increased steeply with an increasing reverse treatment time up to 10min, whereas there were no significant change with a treatment time of more than 10 min. Damping capacity increased with an increasing the reversed austenite and was strongly affected by reversed austenite.

Fatigue Crack Propagation Characteristics of Duplex-Stainless Steel Weldments (II) -Crack Propagation on Near-Threshold Region- (2상계 스테인리스강 용접부의 피로크랙 전파특성 (II) -하한계치 근접에서의 전파특성-)

  • 권종완;김상대;이택순
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.1
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    • pp.115-124
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    • 1989
  • Near-threshold fatigue crack-growth behavior at room temperature for a duplex stainless steel weldments was investigated to evaluate the effect of load ratio, microstructural change, and residual stresses. Near-threshold fatigue crack propagation behavior is found to show a marked sensitivity to .alpha./.gamma. phase ratio, and little residual stress effects. Threshold values in the heat affected zones are higher than those of base metals and threshold values for crack growth decrease with increasing the load ratio in the base metals and weldments. The fractrographic features in base metals, weldments and heat affectred zones were discussed in terms mechanism of crack growth.

Changes in Carotenoids Contents in Pureed and Cooked Carrot and Spinach during Storage (가열처리 및 저장조건에 따른 당근과 시금치퓨레의 Carotenoids 함량변화와 이성질화 형성에 관한 연구)

  • ;;Robert M, Russell
    • Korean journal of food and cookery science
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    • v.19 no.1
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    • pp.83-95
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    • 2003
  • Investigations were conducted on the changes in carotenoids content, and quantification of cis-trans-${\beta}$-carotene Isomers in pureed and cooked carrot and spinach during storage. The isomerization and degradation of carotenoids were monitored by high-performance liquid chromatography on a C$\_$30/ reversed-phase column with diode-array detection. The results showed that lutein, ail-trans-${\beta}$-carotene, ${\alpha}$-carotene, 9-cis-${\beta}$-carotene and 13-cis-${\beta}$-carotene were present in carrot and spinach. Zeaxanthin and cryptoxanthin were present in raw spinach. The contents of lutein, zeaxanthin, cryptoxanthin, ${\alpha}$-carotene and all-trans-${\beta}$-carotene in pureed and cooked carrot and spinach decreased with increasing storage period. The 9-cis and 13-cis carotenoid isomers were the major types formed in cooked carrot during storage. Cooking was not found to alter the carotenoid profile of the sample, but increased the total amount of carotenoids compared with pured ones. This increase could be explained that cooking itself increased the extraction efficiency and inactivated the enzymes degradating carotenoids.

Fabrication of High Strength Mg-Li-Al Alloys by Squeeze Casting Process (용탕단조법에 의한 고강도 Mg-Li-Al합금 제조)

  • Han, Chang-Hwa;Hwang, Yong-Ha;Kim, Yong-Woo;Kim, Do-Hyang;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.17 no.3
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    • pp.267-275
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    • 1997
  • Fabrication of high strength Mg-Li-Al alloys by squeeze casting was established by the stabilization of melt and mold temperatures, applied pressure and the refining method. The entrapment of inclusions during pouring was prevented using 30 ppi alumina foam filter. The as-cast microstructure consists of a mixture of ${\alpha}$ and ${\beta}$ phases including AILi and $MgLi_2$, Al particles, which are distributed in the ${\beta}$ matrix. The grain sizes of gravity and squeeze casting alloys were 288 ${\mu}m$ and 207 ${\mu}m$ respectively. The addition of Al in Mg-Li alloys promoted the formation of second phase particles, which were adjusted to optimize the properties of Mg-Li-Al alloys. The Mg-10wt%Li-5wt%Al alloy after heat treatment at $350^{\circ}C$ for 1 hour showed the maximum hardness value. This is due to the facts that the amounts of ${\alpha}$ and ${\beta}$ phases and their distributions are dependent upon the solution treatment temperature, and that the amounts of AILi and $MgLi_2Al$ particles are dependent upon the Al content.

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