• Title/Summary/Keyword: All-solution-process

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Simultaneous degradation of nitrogenous heterocyclic compounds by catalytic wet-peroxidation process using box-behnken design

  • Gosu, Vijayalakshmi;Arora, Shivali;Subbaramaiah, Verraboina
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.488-497
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    • 2020
  • The present study investigates the feasibility of nitrogenous heterocyclic compounds (NHCs) (Pyridine-Quinoline) degradation by catalytic wet peroxidation (CWPO) in the presence of nanoscale zerovalent iron supported on granular activated carbon (nFe0/GAC) using statistical optimization technique. Response surface methodology (RSM) in combination with Box-Behnken design (BBD) was used to optimize the process parameters of CWPO process such as initial pH, catalyst dose, hydrogen peroxide dose, initial concentration of pyridine (Py) and quinolone (Qn) were chosen as the main variables, and total organic carbon (TOC) removal and total Fe leaching were selected as the investigated response. The optimization of process parameters by desirability function showed the ~85% of TOC removal with process condition of initial solution pH 3.5, catalyst dose of 0.55 g/L, hydrogen peroxide concentration of 0.34 mmol, initial concentration of Py 200 mg/L and initial concentration of Qn 200 mg/L. Further, for TOC removal the analysis of variance results of the RSM revealed that all parameter i.e. initial pH, catalyst dose, hydrogen peroxide dose, initial concentration of Py and initial concentration of Qn were highly significant according to the p values (p < 0.05). The quadratic model was found to be the best fit for experimental data. The present study revealed that BBD was reliable and effective for the determination of the optimum conditions for CWPO of NHCs (Py-Qn).

A Study on 4PL Development to Improve Air Cargo Process (항공물류 프로세스 개선을 위한 4PL 도입 연구)

  • Na, Hyeong-Seok;Jho, Yong-Chul;Lee, Chang-Ho
    • Proceedings of the Safety Management and Science Conference
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    • 2008.04a
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    • pp.383-387
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    • 2008
  • Nowadays, the tendency of world air cargo is noteworthy and air traffic in terms of cargo throughput will no doubt grow significantly in the new Region, with India and China's booming economy and the upcoming Olympics 2008. For example, in the first 11 months of 2006 cargo traffic was increased by 6.3%. First of all, the market of air cargo in Korea grows very quickly and diversifies. It is an essential factor in the process of development of Northeast-Asia as a hub for Air Cargo logistics. However the process of air cargo in Korea is complex as compared with other north-east asia nations. At the same time, it has many problems and causes inconvenience to owners of freight. This paper investigated the process of air cargo in Korea now and analyzed problems of the process. We emphasize that 4PL is the excellent solution from among many alternatives. It is also worthy of notice that EPCglobal network strengthen the role of 4PL. In conclusion, the 4PL system based on EPCglobal network will result in a good success, so it will raise a prestige of air cargo in Korea to a higher position.

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Institutional Solution to Complex Conflicts in the Site Selection Process of Offshore Wind Power - from a Multi-level Governance Perspective (해상풍력 입지 선정 과정에서 복합적 갈등의 제도적 해결방안 - 다층적 거버넌스 관점에서)

  • Seunghyeok Ahn;Yoonmie Soh;Hojae Ryu;Minho Han;Sun-Jin Yun
    • New & Renewable Energy
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    • v.19 no.2
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    • pp.40-58
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    • 2023
  • Several offshore wind power conflicts occur due to the problems in which the site selection process led by private operators is improperly managed. To review the institutional improvement measures that solve this problem, domestic and foreign institutions and operational cases were comparatively analyzed, focusing on key actors from the multi-level governance perspective. First, the status of the site selection process in the Republic of Korea, major issues in stakeholder conflicts, and discussions on the planned site system-related laws (draft) were reviewed. Next, the site selection process and relevant cases in Germany, the Netherlands, and Japan were analyzed. In all these countries, site selection is done by the central government. In Germany and the Netherlands, maritime-related ministries establish overall offshore wind power site plans and conduct strategic environmental assessments for these plans. Futhermore, in the process of determining each individual site, extensive site investigation including environmental assessments are conducted. This aspect needs to be supplemented in the discussion on the direction of institutional improvement in the Republic of Korea.

Development of Stochastic Decision Model for Estimation of Optimal In-depth Inspection Period of Harbor Structures (항만 구조물의 최적 정밀점검 시기 추정을 위한 추계학적 결정모형의 개발)

  • Lee, Cheol-Eung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.28 no.2
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    • pp.63-72
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    • 2016
  • An expected-discounted cost model based on RRP(Renewal Reward Process), referred to as a stochastic decision model, has been developed to estimate the optimal period of in-depth inspection which is one of critical issues in the life-cycle maintenance management of harbor structures such as rubble-mound breakwaters. A mathematical model, which is a function of the probability distribution of the service-life, has been formulated by simultaneously adopting PIM(Periodic Inspection and Maintenance) and CBIM(Condition-Based Inspection and Maintenance) policies so as to resolve limitations of other models, also all the costs in the model associated with monitoring and repair have been discounted with time. From both an analytical solution derived in this paper under the condition in which a failure rate function is a constant and the sensitivity analyses for the variety of different distribution functions and conditions, it has been confirmed that the present solution is more versatile than the existing solution suggested in a very simplified setting. Additionally, even in that case which the probability distribution of the service-life is estimated through the stochastic process, the present model is of course also well suited to interpret the nonlinearity of deterioration process. In particular, a MCS(Monte-Carlo Simulation)-based sample path method has been used to evaluate the parameters of a damage intensity function in stochastic process. Finally, the present stochastic decision model can satisfactorily be applied to armor units of rubble mound breakwaters. The optimal periods of in-depth inspection of rubble-mound breakwaters can be determined by minimizing the expected total cost rate with respect to the behavioral feature of damage process, the level of serviceability limit, and the consequence of that structure.

Use of a Solution-Adaptive Grid (SAG) Method for the Solution of the Unsaturated Flow Equation (불포화 유동 방정식의 해를 위한 해적응격자법의 이용 연구)

  • Koo, Min-Ho
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.1
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    • pp.23-32
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    • 1999
  • A new numerical method using solution-adaptive grids (SAG) is developed to solve the Richards' equation (RE) for unsaturated flow in porous media. Using a grid generation technique, the SAG method automatically redistributes a fixed number of grid points during the flow process, so that more grid points are clustered in regions of large solution gradients. The method uses the coordinate transformation technique to employ a new transformed RE, which is solved with the standard finite difference method. The movement of grid points is incorporated into the transformed RE, and therefore all computation is performed on fixed grid points of the transformed domain without using any interpolation techniques. Thus, numerical difficulties arising from the movement of the wetting front during the infiltration process have been substantially overcome by the new method. Numerical experiments for an one-dimensional infiltration problem are presented to compare the SAG method to the modified Picard method using a fixed grid. Results show that accuracy of a SAG solution using 41 nodes is comparable with the solution of the fixed grid method using 201 nodes, while it requires only 50% of the CPU time. The global mass balance and the convergence of SAG solutions are strongly affected by the time step size (Δt) and the weighting parameter (${\gamma}$) used for generating solution-adaptive grids. Thus, the method requires automated readjustment of Δt and ${\gamma}$ to yield mass-conservative and convergent solutions, although it may increase computational costs. The method can be effective especially for simulating unsaturated flow and other transport problems involving the propagation of a sharp-front.

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A Optimizing Study on maximizing the earning power of casting industry production through TPI (주물 산업의 수익력 극대화를 위한 생산부문의 TPI 최적화 연구)

  • Kang, Byong-Rho;Lee, Chang-Ho
    • Journal of the Korea Safety Management & Science
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    • v.16 no.2
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    • pp.185-192
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    • 2014
  • The production type of foundry industry is a small quantity batch production methods that require the highly skilled technology in the global competition in the variety of customer needs and directly under the influence of fluctuations characteristic. Therefore suitability for small quantity batch production and flexible production capacity and price competitiveness is needed more than anything. To do this, we need transcription and comprehensive innovation activities to maximize the revenue structure of the organization and field survival foundation should be developed the TPI(Total Profit Innovation) process in all aspects of the organization and all employees are involved in order to create a cost, quality, time, and service part of the overall aim how to achieve those effects within a short period of time. We applied the TPI process for S company in the foundry business innovation and productivity through cost reduction. We will expect the productivity improvement and financial performance improvement and then continually accumulate and review the results.

Improving Construction Site Supervision with Vision Processing AI Technology (비전 프로세싱 인공지능 기술을 활용한 건설현장 감리)

  • Lee, Seung-Been;Park, Kyung Kyu;Seo, Min Jo;Choi, Won Jun;Kim, Si Uk;Kim, Chee Kyung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.235-236
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    • 2023
  • The process of construction site supervision plays a crucial role in ensuring safety and quality assurance in construction projects. However, traditional methods of supervision largely depend on human vision and individual experience, posing limitations in quickly detecting and preventing all defects. In particular, the thorough supervision of expansive sites is time-consuming and makes it challenging to identify all defects. This study proposes a new construction supervision system that utilizes vision processing technology and Artificial Intelligence(AI) to automatically detect and analyze defects as a solution to these issues. The system we developed is provided in the form of an application that operates on portable devices, designed to a lower technical barrier so that even non-experts can easily aid construction site supervision. The developed system swiftly and accurately identifies various potential defects at the construction site. As such, the introduction of this system is expected to significantly enhance the speed and accuracy of the construction supervision process.

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Degradation and Ecotoxicity Reduction of Reactive Dye by Using Advanced Oxidation Process (고도산화공정을 이용한 반응성 염료의 제거 및 생태독성 저감)

  • Seo, Kyung Ae;Park, Jae Hong;Jung, Soo Jung;Lim, Byung Jin
    • Journal of Korean Society on Water Environment
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    • v.29 no.2
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    • pp.204-211
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    • 2013
  • In this study, the deriving optimum conditions for decolorization of Acid Orange II solution was carried using $TiO_2$ advanced oxidation process. After that, on base of the deriving results, the range of dye concentration was estimated. In addition, acute toxicity test was also carried to assess toxicity unit according to decolorization and TOC removal. In case of the blockage of light, 20 mg/L of dye solution, and 0.5 g $TiO_2$, the effect of decolorization at pH 3 was larger than at pH 6 and 10, so it was shown that decolorization is dependent on pH. The use of 5 g $TiO_2$ showed best performance of decolorization, but that of 3 g $TiO_2$ was chosen to optimum condition in considering of economical aspects. Four light sources, sun, fluorescent lamp, BLB lamp, and UV-B lamp, were used and decolorization was 99.4% and 100% at 50 mg/L, 98.6% and 99.7% at 100 mg/L for sun and UV-B lamp, respectively. In spite of the optimum condition of decolorization at pH 3, the evaluation of acute toxicity test showed highly toxic. In conclusion, although the optimum treatment of dye solution is performed, water ecology can be polluted in discharging it into water system. Therefore, it is needed to study of water ecological system with dye water treatment, and it takes all the circumstances into consideration.

A Posterior Preference Articulation Method to Dual-Response Surface Optimization: Selection of the Most Preferred Solution Using TOPSIS (쌍대반응표면최적화를 위한 사후선호도반영법: TOPSIS를 활용한 최고선호해 선택)

  • Jeong, In-Jun
    • Knowledge Management Research
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    • v.19 no.2
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    • pp.151-162
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    • 2018
  • Response surface methodology (RSM) is one of popular tools to support a systematic improvement of quality of design in the product and process development stages. It consists of statistical modeling and optimization tools. RSM can be viewed as a knowledge management tool in that it systemizes knowledge about a manufacturing process through a big data analysis on products and processes. The conventional RSM aims to optimize the mean of a response, whereas dual-response surface optimization (DRSO), a special case of RSM, considers not only the mean of a response but also its variability or standard deviation for optimization. Recently, a posterior preference articulation approach receives attention in the DRSO literature. The posterior approach first seeks all (or most) of the nondominated solutions with no articulation of a decision maker (DM)'s preference. The DM then selects the best one from the set of nondominated solutions a posteriori. This method has a strength that the DM can understand the trade-off between the mean and standard deviation well by looking around the nondominated solutions. A posterior method has been proposed for DRSO. It employs an interval selection strategy for the selection step. This strategy has a limitation increasing inefficiency and complexity due to too many iterations when handling a great number (e.g., thousands ~ tens of thousands) of nondominated solutions. In this paper, a TOPSIS-based method is proposed to support a simple and efficient selection of the most preferred solution. The proposed method is illustrated through a typical DRSO problem and compared with the existing posterior method.

Research on the Solution and Properties of Ni-P/n-$Al_2O_3$ Electroless Composite Plating

  • Huang, Yan-bin;Liu, Fei-fei;Zhang, Qi-yong;Ba, Guo-zhao;Liang, Zhi-jie
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.257-260
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    • 2007
  • In order to further improve the corrosion resistance and wear resistance of the Ni-P coatings of electroless plating, electroless Ni-P/n-$Al_2O_3$ composite deposits were prepared by adding some nano $Al_2O_3$ Particles in Ni-P plating bath. The bath composition and proproties were studied in this paper. The orthogonal test was applied in order to get the new composite solution, taking the initial stable potential as evaluation standard and considering the elements correlation at the same time. The processing parameters have been optimized by single factor experiment in which the depositing speed was chosen as the evaluation standard. The results showed that the process is stable and the composite Ni-P/n-$Al_2O_3$ deposits werebright and smooth, whose hardness and corrosion resistance are much better than simple Ni-P coatings. Furthermore the surface appearance and structure of the composite Ni-P/n-$Al_2O_3$ coating were investigated by SEM and XRD method. It was proved that the coating surface is typical cystiform cells and its structure is amorphous. All test results ofcomposite coating showed that all various physical coating properties had been improved by adding nano-particles. The hardness of optimal coating is more than 600HV and increases to 1000HV after heat-treating, and its hardness is 20~50% higher than Ni-P coating. The rust points appeared in 200 hour by immersing the coating into the 10%HCl solution and the corrosive speed is $3{\times}10^{-3}mg/(cm^2{\cdot}h)$which was obtained after 300 hour. In the same condition Ni-P coating is $5.6{\times}10^{-3}mg/(cm^2{\cdot}h)$. The salt spray resistance of the layers can exceed 600h with the thickness $20{\mu}m$.