• Applied Microscopy
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• 제49권
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• pp.1.1-1.10
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• 2019

Joints of three-dimensional (3D) rutile-type (r) tin dioxide ($SnO_2$) nanowire networks, produced by the flame transport synthesis (FTS), are formed by coherent twin boundaries at $(101)^r$ serving for the interpenetration of the nanowires. Transmission electron microscopy (TEM) methods, i.e. high resolution and (precession) electron diffraction (PED), were utilized to collect information of the atomic interface structure along the edge-on zone axes $[010]^r$, $[111]^r$ and superposition directions $[001]^r$, $[101]^r$. A model of the twin boundary is generated by a supercell approach, serving as base for simulations of all given real and reciprocal space data as for the elaboration of three-dimensional, i.e. relrod and higher order Laue zones (HOLZ), contributions to the intensity distribution of PED patterns. Confirmed by the comparison of simulated and experimental findings, details of the structural distortion at the twin boundary can be demonstrated.

• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.321-324
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• 1996

Sr1+xSm1-xFeO4-y solid solutions with a composition range 0.00 ≤x≤1.00 have been prepared at 1200 ℃ in air under normal atmospheric pressure. All the solutions exhibit the K2NiF4-type structure of tetragonal system. Mohr salt analysis shows that the mole ratio of Fe4+ ion to Fe3+ ion or the τ value increases with the x value. Nonstoichiometric chemical formulas have been formulated from the x, τ, and y values. Electrical conductivity was measured in the temperature range of 173-373 K under atmospheric air pressure. The conductivities of each sample are varied within the semiconductivity range. The conductivity at constant temperature increases steadily with x value and activation energies are varied from 0.14 to 0.32 eV. The conduction mechanism of the ferrite system may be proposed as a hopping model of conduction electrons between the mixed valence states. The Mossbauer spectrum for the composition of x=0.00 shows a six line pattern by which the existence of Fe3+(I.S.=0.32 mm/sec) can only be identified. The spectra for the compositions of x=0.50 and 1.00 presents broad single line patterns showing a mixed valence state.

• 대한화학회지
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• 제25권5호
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• pp.318-324
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• 1981

일차입자의 크기와 응집상태가 다른 두 종류의 $Fe_2O_3$를 부분침전법과 ball-mill 혼합법으로 BaCO$_3$와 혼합한 $BaCO_3-Fe_2O_3$계의 고체반응에 있어 $Fe_2O_3$분체의 영향을 조사하였다. TG, XRD, SEM 등을 측정에 사용하였으며, X-선 회절분석결과 Ba-ferrite의 생성과정은 다음과 같은 연속적인 2단계로 이루어진다는 것을 알았다. $BaCO_3 + 6Fe_2O_3\;{\longrightarrow}\;BaFe_2O_3 + 5Fe_2O_3 + CO_2{\uparrow}\;BaFe_2O_4 + 5Fe_2O_3 \;{\longrightarrow}\;BaFe_{12}O_{19}$ 또 $Fe_2O_3$원료분체의 응집상태와 혼합방법은 고체반응에 현저한 영향을 미친다는 것을 확인했다.

• 한국세라믹학회지
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• 제42권5호
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• pp.308-313
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• 2005

In this study the electrical conductivity of excess BaO in $BaTiO_3$ was measured to investigate the relationship between defects and solubility in the temperature range of $900^{\circ}C$ to $1300^{\circ}C$ under various oxygen partial pressure. First of all, quenched $BaTiO_3$ powders of various Ba/Ti ratios were analysed by X-ray diffraction to confirm whether second phase is formed or not. As the results, we observed the solubility of BaO in the temperature range of $1200^{\circ}C$ to $1400^{\circ}C$, and it was also found that the conductivity minima move to lower $PO_2$ with increasing excess BaO within solubility limit.

• 복합신소재구조학회 논문집
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• 제4권1호
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• pp.1-8
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• 2013

The finite element analysis (FEA) is a numerical technique to find solutions of field problems. A field problem is approximated by differential equations or integral expressions. In a finite element, the field quantity is allowed to have a simple spatial variation in terms of linear or polynomial functions. This paper represents a review and an accuracy-study of the finite element method comparing the FEA results with the exact solution. The exact solutions were calculated by solid mechanics and FEA using matrix stiffness method. For this study, simple bar and cantilever models were considered to evaluate four types of basic elements - constant strain triangle (CST), linear strain triangle (LST), bi-linear-rectangle(Q4),and quadratic-rectangle(Q8). The bar model was subjected to uniaxial loading whereas in case of the cantilever model moment loading was used. In the uniaxial loading case, all basic element results of the displacement and stress in x-direction agreed well with the exact solutions. In the moment loading case, the displacement in y-direction using LST and Q8 elements were acceptable compared to the exact solution, but CST and Q4 elements had to be improved by the mesh refinement.

• Journal of Photoscience
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• 제4권3호
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• pp.147-160
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• 1997

INTRODUCTION : Various types of organic reactions in the crystalline state, so-called "topochemical reaction", have been reported in this century." Among the reactions, [2+2] photocycloaddition of diolefin crystals are one of the most intensively investigated examples. In the topochemical reaction in a pure sense, the space group symmetry is perfectly preserved throughout the reaction as were demonstrated by the crystalline-state photopolymerization of 2,5-distyrylpyrazine (2,5-DSP) and photodimerization of propyl $\alpha$-cyano-4-[2-(4-pyridyl) ethenyl]cinnamate. 2,5-DSP was initially prepared by Franke and in 1958 Koelsch and Gumprecht described briefly in their article of diazine-derivatives that it was found that the compound (2,5-DsP) was converted into a colorless insoluble polymer (\ulcorner) dec. 331~331$\circ$ when the solid was exposed for a few hours to ultraviolet light. Wright described in his book as if Koelsch and Gumprecht had investigated both the structure of the photoproduct and the crystal structure 2,5-DSP in detail. However, in the paper, they have not described any study on chemically correct analysis and crystallography of the resulting photoproduct at all. In 1967, one of present authors (M. H.) independently made the same observation as Franke that brilliant yellow crystal of 2,5-DSP was converted into powdery white substance under the sunlight in the course of a preparative study of pyrazine-2,5-dicarboxylic acid from 2,5-DSP. He investigated this phenomenon and concluded for the first time that a linear highmolecular-weight polymer crystal ([$\eta$] > 3.0 in $CF_3COOH$ solution) with recurring cyclobutane units in the main chain, had been produced from 2,5-DSP crystal by the action of sunlight.on of sunlight.

• 대순사상논총
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• 제18권
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• pp.123-134
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• 2004

The aim on this paper is to explain the present state and circumstance in the course of arranging historic classical books in China. In order to approach its purpose, it should make it clear to define the word of "The present"(當代). Furthermore, we need to take a deep notice on the arrangements itself of historic classical books, its influences and contributions, reflecting this process carefully with those historical, cultual and social points of view due to the meaning of "The present" in China. Starting from this considerate view, first of all, I would like to determine the accurate time of "The present" to be the period of time from October, 1949 to December, 2003. It can be described very suitably well as "bamboo sprouts grow fast after a rainfall"(雨後春荀). This tremendous works in the arrangements of Classics have gone through sweets and bitters of times during 50 and several years. However, this work in process has overcome so much troubles and exclude obstacles in doing so, gradually begun to bear tasteful fruit of many publications, about 10,000 works so far. Although it has gone far with very little amount of works in comparison with the remains that would be put in order in the incoming future, it succeed effectively to the spirit and soul in Chinese culture and people. Illuminating the development in its historical steps and analyzing elaborately flows in cultural and ideal elements, it is known that this work of arrangements not only give a very firm basis for excellent Chinese cultural tradition, but also extend high level of idea and thoughts in their thoughts so that build up the spirit in socialism on the solid foundation. This paper will give a explanation and analysis on this works and its contributions. At the same time, it examine and give a good, careful, and close look on the arrangement of historic classical books in China by various means of classifying into various types and style, searching for many methods, and showing indication and directions that might be right in "the present".

• 한국전자통신학회논문지
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• 제15권3호
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• pp.421-432
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• 2020

본 논문에서는 S-밴드 군용 레이더에 사용되고 기존의 TWTA를 대체하기 위해 GaN HEMT 기반 증폭모듈을 이용하여 개발한 2kW급 반도체증폭기(SSPA)를 제안하였다. 제안한 SSPA는 8개의 증폭모듈로 이루어진 고출력증폭모듈, 구동증폭모듈, 제어모듈 및 전원공급 장치로 이루어져 있다. 제안한 SSPA는 1) 증폭모듈과 구성부품은 공간적 제약으로 작은 패키지에 통합설계 되었으며, 2) PCB 내장형 하모닉필터를 이용하여 고주파를 제거하였으며, 그리고 3) 입력신호의 듀티 변화에 대응하여 일정한 출력이 유지되도록 하는 자동이득조절기를 설계하였다. 제안된 SSPA는 최대 48 dB의 이득과 3.1~3.5 GHz의 주파수 대역에서 63-63.6 dBm의 출력 전력을 보였다. 자동이득조절 기능은 15-20 dBm의 입력전력 변동에도 대해서, 출력전력이 63dBm 전후로 일정하게 유지하는 것을 확인하였다. 마지막으로 MIL-STD-810의 시험기준을 만족하는 높은 (55 ℃) / 낮은 (-40 ℃) 온도시험 프로파일을 이용한 온도시험을 통해 개발된 시스템의 신뢰성을 검증하였다. 개발된 SSPA는 경량, 고출력, 고이득, 안전기능, 낮은 수리비, 짧은 수리시간 등 측면에서 기존의 TWTA 증폭기보다 우수한 것을 확인하였다.

• 한국진공학회지
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• 제22권2호
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• pp.79-85
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• 2013

희토류 이온 $Eu^{3+}$와 $Dy^{3+}$가 각각 도핑된 $CaMoO_4$ 광체 분말을 고상반응법으로 합성하였다. 모든 형광체 분말의 결정 구조는 활성제 이온의 종류와 농도비에 관계없이 주 회절 피크(112)를 갖는 정방 정계이었다. $Eu^{3+}$ 이온이 도핑된 형광체의 경우에, $Eu^{3+}$ 이온의 농도가 0.01~0.10 mol 영역에서 결정 입자의 크기는 전반적으로 증가하였고, 비교적 균일한 크기 분포를 가지면서 조약돌 형태를 나타내었으며, 흡광 스펙트럼은 311 nm를 정점으로 넓게 퍼져있는 전하 전달 밴드와 파장 영역 360~470nm에서 약한 피크를 갖는 다수의 흡수선이 관측되었으며, 주 발광 스펙트럼은 $Eu^{3+}$ 이온의 $^5D_0{\rightarrow}^7F_2$ 전이에 의한 618 nm에 피크를 갖는 강한 적색 발광이었다. $Dy^{3+}$ 이온이 도핑된 분말의 경우에, 흡광 스펙트럼은 303 nm에 피크를 갖는 전하 전달 밴드와 상대적으로 세기가 약한 다수의 $Dy^{3+}$ 이온의 전이 신호가 발생하였으며, 주 발광 스펙트럼은 $^4F_{9/2}{\rightarrow}^7H_{13/2}$ 전이에 의한 578 nm에 피크를 갖는 황색 발광 스펙트럼이 관측되었다.

• 한국표면공학회지
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• 제53권4호
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• pp.131-137
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• 2020

A series of Dy³⁺, Sm³⁺, and Dy³⁺/Sm³⁺ doped Gd₂WO₆ phosphors were synthesized by the conventional solid-state reaction. The X-ray diffraction patterns revealed that all of the diffraction peaks could be attributed to the monoclinic Gd₂WO₆ crystal structure, irrespective of the type and the concentration of activator ions. The photoluminescence (PL) excitation spectra of Dy³⁺-doped Gd₂WO₆ phosphors contained an intense charge transfer band centered at 302 nm in the range of 240-340 nm and two weak peaks at 351 and 386 nm. Under an excitation wavelength of 302 nm, the PL emission spectra consisted of two strong blue and yellow bands centered at 482 nm and 577 nm. The PL emission spectra of the Sm³⁺-doped Gd₂WO₆ phosphors had a series of three peaks centered at 568 nm, 613 nm, and 649 nm, corresponding to the ⁶G_5/2 → ⁶H_5/2, ⁶G_5/2 → ⁶H_9/2, and ⁶G_5/2 → ⁶H_11/2 transitions of Sm³⁺, respectively. The PL emission spectra of the Dy³⁺- and Sm³⁺-codoped Gd₂WO₆ phosphors showed the blue and yellow emission lines originating from the ⁴F_9/2 → ⁶H_15/2 and ⁴F_9/2 → ⁴H_13/2 transitions of Dy³⁺ and reddish-orange and red emission bands due to the ⁴G_5/2 → ⁶H_7/2 and ⁴G_5/2 → ⁶H_9/2 transitions of Sm³⁺. As the concentration of Sm³⁺ increased from 1 to 15 mol%, the intensities of two PL spectra emitted by the Dy³⁺ ions gradually decreased, while those of the three emission bands due to the Sm³⁺ ions slowly increased, thus producing the color change from white to orange. The CIE color coordinates of Gd₂WO₆:5 mol% Dy³⁺, 1 mol% Sm³⁺ phosphors were (0.406, 0.407), which was located in the warm white light region.