• Title/Summary/Keyword: Alkaline solution

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Effect of Corrosion Conditions on the Luster Change of Metallic Yarns and Fabric - Analysis of Changes in Reflection and Transmission -

  • Shin, Hye-Sun;Kim, Jong-Jun;Jeon, Dong-Won
    • Journal of Fashion Business
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    • v.12 no.3
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    • pp.54-61
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    • 2008
  • The glitter of lame fabrics containing the metallic yarns may further be altered by $Na_2CO_3$ aqueous solution at an elevated temperature. In this study, the effect of the corrosion treatment on the yarn luster was evaluated using image analysis. The alkaline solution treatment was found to be more effective on the aluminum-based specimens than on the silver-based specimens. It was found that corrosion percentage measurement based on the transmission analysis may provide reasonable quantitative index, even if the measurement relies on an indirect method. Based on the quantitative results, the alkaline treatment condition for the specific specimen would be optimized for a desired glitter modification.

Comparison of Acidic and Alkaline Bath in Electroless Nickel Plating on Porous Carbon Substrate (다공성 탄소전극상 무전해 니켈도금의 산성과 알칼리용액 비교 연구)

  • Chun, So-Young;Kang, In-Seok;Rhym, Young-Mok;Kim, Doo-Hyun;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.2
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    • pp.105-110
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    • 2010
  • Electroless nickel plating on porous carbon substrate for the application of MCFC electrodes was investigated. Acidic and alkaline bath were used for the electroless nickel plating. The pore sizes of carbon substrates were 16-20 ${\mu}m$ and over 20 ${\mu}m$. The carbon surface was changed from hydrophobic to hydrophilic after immersing the substrate in an ammonia solution for 40 min at $60^{\circ}C$. The contact angle of water was decreased from $85^{\circ}C$ to less than $20^{\circ}$ after ammonia pretreatment. The deposition rate in the alkaline bath was higher than that in the acidic bath. The deposition rate was increased with increasing pH in both acidic and alkaline bath. The content of phosphorous in nickel deposit was decreased with increasing pH in both acidic and alkaline bath. The contents of phosphorous is low in alkaline bath. The minimum concentration of $PdCl_2$ for the electroless nickel plating was 10 ppm in alkaline bath and 5 ppm in acidic bath. The thickness of nickel was not affected by the concentration of $PdCl_2$.

A Study on the Alkali Hydrolysis of PET fabrics with Ultrasonic Application(II)- Surface Porosity and Oligomer Analysis - (초음파를 적용한 PET 직물의 알칼리 가수분해에 관한 연구(II) - 기공특성과 올리고머 분석 -)

  • 김삼수;서말용;박성우;윤태희;이승구;허만우
    • Textile Coloration and Finishing
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    • v.14 no.6
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    • pp.305-312
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    • 2002
  • In order to give a silk-like touch to PET fabrics, the PET fabrics were treated with NaOH alkaline solution in various conditions. In alkaline treatment, the liquor flow type pilot weight reduction apparatus with magnetostrictive ultrasonic transducer was used for the study. The effects of ultrasonic application, treatment time and temperature at NaOH 4% and 6"A solution on the decomposition rate of PET fabrics. From the results of the decomposition rate of PET fabrics, the qualitative and quantitative analysis of oligomer after decomposition of PET fabrics carried out by the HPLC. On the other hand, the surface pore characteristics of decomposition PET fabrics measured by porosimetery. The pore characteristics on the surface of treated PET fiber depended on the decomposition rate and did not depend on the ultrasonic cavitation. The pore diameter of alkaline untreated PET fiber were 15A and those of treated PET fibers were 5~6$\AA$ at the maximum pore volume. The average pore sizes of fiber before and after treatment were 141 h and 160h, respectively. Total amount of oligomer of the untreated PET fibers were 1.70wt% and 67.7% of total oligomer occupied with PET cyclic trimer and PET cyclic tetramer. Total amount of oligomer of fiber with 26.9% and 48.0% of weight loss without ultrasonic application were 1.78wt% and 1.79wt%, respectively. Also total amount oligomer of fibers which were reduced 27.7% and 48.2% of weight loss with ultrasonic application were 1.74wt%. This result showed that the removal rate of oligomer in the process of alkaline hydrolysis with ultrasonic higher than that of without ultrasonic application.tion.

The Proteinase Distributed in the Intestinal Organs of Fish 3. Purification and Some Enzymatic Properties of the Alkaline Proteinases from the Pyloric Caeca of Skipjack, Katsuwonus vagans

  • PYEUN Jae-Hyeung;KIM Hyeung-Rak;HEU Min-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.2
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    • pp.85-96
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    • 1988
  • Purification and some properties of alkaline proteinases in the pyloric caeca of skipjack, Katsuwonus vagans, were investigated. Four alkaline proteinases, temporarily designated proteinases I, II, III and IV, were identified from the tissue extract of the pyloric caeca by ammonium sulfate fractionation, DEAE-Sephadex A-50 chromatography, and Sephadex G-100 and G-200 gel filtration. Result of disc-polyacrylamide gel electrophoretic analysis showed that the purified proteinases II and III were homogenous with the yields of $1.5\%\;and\;1.2\%$, and those specific activities were increased to 33 to 37 fold over that of the crude enzyme solution, respectively. Molecular weight of the proteinases II and III determined by sephadex G-100 gel filtration were 28,500 and 24,200, respectively. The optimum conditions for the caseinolytic activity of the two enzymes were pH 9.6 and $48^{\circ}C$. The reaction rates of the two alkaline proteinases were constant to the reaction time to 80 min in the reaction mixture of $3.4{\mu}g/ml$ of enzyme concentration and $2\%$ casein solution. The Km values against casein substrate determined by the method of Lineweaver-Burk were $0.56\%$ for proteinase II and $0.30\%$ for proteinase II. The proteinases II and III were inactivated under the presence of $Ag^+,\;Hg^{2+},\;Ni{2+},\;Fe^{2+},\;and\;Cu^{2+}$, and but activated by $Mn^{2+}\;and\;Ca^{2+}$ and markedly inhibited by the soybean trypsin inhibitor and N-p-toluenesulfonyl-L-lysine chloromethyl ketone. Therefore, the proteinases II and III were found to be a group of serine proteases and assured to be trypsin-like proteinases.

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Analysis on Variation of Primary Elements of Stainless Steel Interacting with Alkali Solution (알칼리 전해액의 상호작용에 의한 Stainless Steel 주성분의 변화 분석)

  • Byun, Chang-Sub;Lim, Soo-Gon;Kim, Su-Kon;Choi, Ho-Sang;Shin, Hoon-Kyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.7
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    • pp.522-527
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    • 2013
  • In this paper, We studied the change of surface and variation of elements on both electrodes of hydrogen generator of alkaline electrolysis in use of FE-SEM and SIMS. We used the stainless steel 316(600 ${\mu}m$) as electrode in condition of 25%KOH, $60^{\circ}C$ Temperature. The results show that the intensity of elements (C, Si, P, S, Ti, Cr, Mn, Fe, Ni, Mo) of Positive Electrode are decreased as much as about $10^1{\sim}10^3 $than the original electrode. Thickness of Positive Electrode is decreased about 40 ${\mu}m$ after chemical reaction. The negative electrode, however, shows a slight variation in the intensity of elements (C, Si, P, Fe, Ni, Mn, Mo) but Change of thickness and surface' shape of electrode show nothing after chemical reaction. The change in thickness and variation of Stainless Steel 316 cause the lifetime of electrode to be shorted. We also observed hydrogen, oxygen, potassium in both electrodes. Especially, The potassium is increased in proportional with depth of positive electrode. this means the concentration of alkali solutions is changed. and so we have to supply alkaline solution to generator in order to produce same quantity of hydrogen gas continuously. we hope that this study gives a foundation to develop the electrode for hydrogen generator of alkaline electrolysis.

Degradation Behavior of Poly[(R)-3-hydroxybutyrate] by Using Single Crystals and Monolayers as Model Systems (단결정과 단분자막을 모델 시스템으로 한 Poly[(R)-3-hydroxybutyrate]의 분해거동)

  • Kim, Seong-Soo;Lee, Won-Ki;Ahn, Yong-Sik
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.54-58
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    • 2005
  • The hydrolytic behavior of microbial poly[(R)-3-hydroxybutyrate]](P(3HB)) has been studied by using two model systems, Langmuir monolayer and solution-grown single crystals (SCs), for elucidating the mechanism for both alkaline and enzymatic degradations. An initial degradation of SCs of P(3HB) leads to breakup lamellae parallel to their short axis (b-axis). Similarly, ridge formation on the lamellar surface appears along the b-axis at lower quenching temperature than melting temperature. Both results support that the lamellar crystals contain less-ordered and more thermally sensitive regions along the b-axis. Although the enzymatic hydrolysis of P(3HB) monolayers was similar to its alkaline one, the enzymatic degradation of P(3HB) monolayers occurred at higher constant surface pressure than the alkaline degradation. This behavior might be attributed to the size of enzymes which is much larger than that of alkaline ions; that is, the enzymes need larger contact area with monolayers to be activated.

Nitrided LATP Solid Electrolyte for Enhanced Chemical Stability in Alkaline Media (질화 처리된 LATP 고체전해질의 알칼라인 용액내에서의 내화학특성 개선 연구)

  • Seong, Ji Young;Lee, Jong-Won;Im, Won Bin;Kim, Sung-Soo;Jung, Kyu-Nam
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.45-50
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    • 2015
  • In the present work, to increase the chemical stability of the lithium-ion-conducting ceramic electrolyte ($Li_{1+x+y}Al_xTi_{2-x}Si_yP_{3-y}O_{12}$, LATP) in the strong alkaline solution, the surface of LATP was modified by the nitridation process. The surface and structural properties of nitride LATP solid electrolyte were characterized by X-ray diffraction, X-ray photoelectron spectrometer and scanning electron microscopy and ac-impedance spectroscopy, which were correlated to the chemical stability and electrochemical performance of LATP. The nitrided LATP immersed in the alkaline solution for 30 days exhibits the enhanced chemical stability than the pristine LATP. Moreover, a rechargeable hybrid Li-air battery constructed with the nitrided LATP solid electrolyte shows considerably reduced discharge-charge voltage gaps (enhanced the round-trip efficiency) in comparison to the cell constructed with pristine LATP, which indicate that the surface nitridation process can be the efficient way to improve the chemical stability of solid electrolyte in alkaline media.

The Study of Particle Removal Efficiency (PRE) with Alkaline Ozonized Water (알칼라인 오존수를 아용한 입자제거에 관한 연구)

  • Lee, Seung-Ho;Kim, Tae-Gon;Lee, Jae-Hwan;Park, Jin-Goo;Bae, So-Ik;Lee, Gun-Ho;Kim, In-Jung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.362-363
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    • 2006
  • Ozonized DI water was supplied to make alkaline cleaning solutions to replace SCI chemicals in a bath with and without recirculation. With recirculation, low dissolved ozone and low pH cause lower particle removal efficiency (PRE) of 75%. However, direct supply of ozonized water with $NH_4OH$ to a bath without recirculation resulted in higher PRE over 93 %.

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Improving the Fading of Reusable Surgical Gown by Repeated Severe Laundering and Sterilization Condition (반복되는 고온 세탁 및 멸균 환경에 대한 Reusable 수술가운 원단의 퇴색 저항성 개선 연구)

  • Kim, Ji Yeon;Min, Mun Hong;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.25 no.3
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    • pp.215-222
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    • 2013
  • The purpose of this study is to minimize fading fabrics of surgical gown by repeated severe laundering and sterilization condition. The study showed that the best conditions were reduction cleaning using sulphinic acid derivatives or glucose organic chemicals at $98^{\circ}C$ alkaline solutions. In these conditions, color difference values(dE) were below 1.0 that means unrecognizable color change by repeated laundering and sterilization. If it treated with only laundering, reduction cleaning conditions may adjust over $80^{\circ}C$ alkaline solution. In conclusion, it is needed to select the high-washing fastness dye and reduction cleaning using sulphinic acid derivatives or glucose organic chemicals at $98^{\circ}C$ alkaline solutions for removal unfixed dyes.