• Title/Summary/Keyword: Alkaline material

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Properties of the Handsheet Paper made from Silk Fibers and Paper Mulberry (楮皮를 포함하는 絹紙의 特性)

  • 강경돈;이기훈;정병희;류운영;남중희
    • Journal of Sericultural and Entomological Science
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    • v.41 no.3
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    • pp.201-204
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    • 1999
  • The silk/paper mulberry paper was prepared by recycling of the hard twisted silk waste and its mechanical properties was investigated. The silk waste was pretreated with sodium hydroxide(0.5%) and sodium carbonate(4%) to make it easy for beating and fibrillation. The silk/paper mulberry hand sheet paper has better mechanical properties of tearing strength and air permeability compared with the traditional and modified traditional paper. Treating with alkaline solution, the hard twisted silk waste could be used for an novel composite material.

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Effect of Alkaline Activator and Curing Condition on the Compressive Strength of Cementless Fly Ash Based Alkali-Activated Mortar (시멘트를 사용(使用)하지 않은 플라이애시 알칼리 활성(活性) 모르타르의 압축강도(壓縮强度)에 미치는 알칼리 활성제(活性劑) 및 양생조건(養生條件)의 영향(影響))

  • Kang, Hyun-Jin;Ryu, Gum-Sung;Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Kim, Sung-Wook;Lee, Jang-Hwa
    • Resources Recycling
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    • v.18 no.2
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    • pp.39-50
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    • 2009
  • Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of fly ash, a by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effective in the reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in order to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

Hydration Properties of Cement Matrix using Electrolysis Alkaline Aqueous and Ground Granulated Blast Furnace Slag (전기분해 알칼리 수 및 고로슬래그 미분말 혼입 시멘트 경화체의 수화 특성)

  • Jung, Yoong-Hoon;Kim, Ho-Jin;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.185-190
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    • 2021
  • Cement has been used as a main material in the modern construction industry. However, it has been pointed out as a main cause of global warming due to carbon dioxide generated during manufactured. Recently, research that replacing cement substitute to industrial by-products such as Blast Furnace Slag which is by-producted in steelworks. When Blast Furnace Slag is used as a cement substitute, it shows a problem of lower initial strength, which is caused by glassy membrane on the particle surface. In this study, we used Electrolysis Alkaline Aqueous to improve the usability and problem of lower initial strength. As a result of the experiment, cement matrix using Blast Furnace Slag and Alkaline Aqueous showed initial strength and hydrate product were developed than that using general mixing water. Also, as a result of porosity analysis, It was confirmed that cement matrix using Alkaline Aqueous and Blast Furnace Slag has a tighter structure in internal porosity and porosity distribution than using general mixing water.

Carbonation Resistance Property of Mortar using Electrolysis Aqueous (전기분해수를 배합수로 활용한 모르타르의 탄산화 저항 특성)

  • Jeong, Su-Mi;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.204-210
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    • 2022
  • Cement is pointed out as the main cause of carbon dioxide emission in the construction industry. Many researchs are underway to use blast furnace slag, an industrial by-product, as a substitute for cement to reduce carbon dioxide emitted during the manufacturing the cement. When blast furnace slag is used as a substitute for cement, it has advantages such as long-term strength and chemical resistance improvement. However, blast furnace slag has a problem that makes initial strength low. This is due to the impermeable film on the surface created during the production of blast furnace slag. The created film is known to be destroyed in an alkaline environment, and based on this, previous studies have suggested a solution using various alkali activators. But, alkali activator is dangerous product since it is a strong alkaline material. And it has the disadvantage in price competitiveness. In this study, an experiment was conducted to improve the initial hydration reactivity of the blast furnace slag to secure the initial strength of the mortar substituted with the blast furnace slag and to check whether the carbonation resistance was increased. As a result of the experiment, it was confirmed that the mortar using alkaline water showed higher strength than the mortar using tap water, and there were more hydration products generated inside. In addition, it was confirmed that the mortar using alkaline water as a compounding water had high carbonation resistance.

Phenolic Glycosides Isolated from Safflower (Carthamus tinctorius L.) Seeds Increase the Alkaline Phosphatase (ALP) Activity of Human Osteoblast-like Cells

  • Kim, Dong-Hyun;Lee, Jin-Hee;Ahn, Eun-Mi;Lee, Youn-Hyung;Baek, Nam-In;Kim, In-Ho
    • Food Science and Biotechnology
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    • v.15 no.5
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    • pp.781-785
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    • 2006
  • The chemical compositions of the seeds of the safflower (Carthamus tinctorius L.) plant were evaluated to determine possible compound having proliferative effects on human osteoblast cells. Three-[4,5-dimethylthiazole-2-yl]-2,5-diphenyltetrazolium bromide (MTT) test and alkaline phosphatase (ALP) activity were used to assess the effects of the isolates on the human osteoblast-like line (Saos-2). Activity guided fractionation led to the isolation of ALP activating lignin and alkaloid glycosides through the extraction of the seeds, solvent partitioning and repeated silica gel and octadecyl silica (ODS) column chromatographic separations. The data from Nuclear Magnetic Resonance (NMR), Mass (MS), and Infrared (IR) analyses enabled the determination of the chemical structure and characterization of two compounds as a tracheloside and an N-(p-coumaroyl)-serotonin mono-${\beta}$-D-glucopyranoside. These two compounds showed respectively $149.2{\pm}4.2$ and $138.9{\pm}3.5%$ ALP activity compared to the control when evaluated at a concentration of $100\;{\mu}g/mL$.

Relationship Between the Dose of Clodronate and Serum Level of Alkaline Phosphatase, Calcium, and Phosphate During Orthodontic Tooth Movement

  • Choi, Josefina;Baek, Seung-Hak;Chang, Young-Il
    • Journal of Korean Dental Science
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    • v.3 no.1
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    • pp.32-38
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    • 2010
  • Objective : To evaluate the relationship between the dose of Clodronate and serum level of alkaline phosphatase (ALP), calcium (Ca), and phosphate (PO4) during orthodontic tooth movement MaterialS and MethodS: A total of 18 sex-matched Wistar rats (weight=180~230g, mean age=8 weeks) were allocated into the 2.5mM Clodronate (2.5C) group, 10mM Clodronate (10C) group, or control group (n=6 for each group). After the application of a nickel-titanium closed coil spring (force of 60g) between the upper central incisors and first molars (UFM), 2.5C, 10C, or saline was injected every third day into the subperiosteum of the alveolar bone adjacent to UFM for the experimental and control groups. The animals were sacrificed 17 days later. Trunk blood was quickly collected into a heparinized tube and centrifuged at 2,000 rpm for 20 min. The plasma was used for the biochemical assays of the serum level of ALP, Ca, and PO4. Kruskall-Wallis test and Mann-Whitney test with Bonferroni correction were performed for the statistical analyses. Results : Dose-dependent increase in the level of ALP (P<0.01) and decrease in the level of Ca (P<0.001) were observed among the control, 2.5C, and 10C groups. Although there was no significant difference in PO4 between the 2.5C and 10C groups, the 10C group showed a significantly higher level of PO4 than the control group (P<0.01). Conclusion : Since Clodronate induced significant dose-dependent change in the serum level of ALP, Ca, and PO4 during orthodontic tooth movement, orthodontists should consider these biochemical markers not only as a diagnostic tool for bone turnover rate but also as a monitoring tool for orthodontic tooth movement.

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Studies on the Application of the Spent Alkaline Manganese Batteries Powder as an Adsorbent for Nickel Ion (폐(廢)알칼리망간전지(電池) 분말(粉末)의 니켈 이온 흡착제(吸着劑)로서의 활용(活用)에 관한 연구(硏究))

  • Baek, Mi-Hwa;Kim, Dong-Su;Sohn, Jeong-Soo
    • Resources Recycling
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    • v.17 no.2
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    • pp.63-69
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    • 2008
  • The adsorption features of $Ni^{2+}$ onto spent alkaline manganese batteries powder have been investigated with the adsorbent dose, initial concentration of adsorbate and temperature as the experimental variables. The adsorption reaction of $Ni^{2+}$ ion followed the pseudo-second order rate model, and the adsorption rate constants($k_2$) decreased with increasing initial concentration of nickel ion. The equilibrium adsorption data were fitted to the Langmuir and Freundlich models. The Freundlich model represents the equilibrium data better than the Langmuir model in this initial adsorbate concentration range. As the temperature increased, the adsorbed amount of nickel ion at equilibrium was also increased, which indicated that the adsorption reaction was endothermic. Based on the experimental results obtained along with temperatures, thermodynamic parameters such as ${\Delta}H^{\circ},\;{\Delta}G^{\circ},\;and\;{\Delta}S^{\circ}$ were calculated.

Measurement of the Corrosion Rate of Aluminum in Alkaline Solution (알칼리 용액에서 알루미늄의 부식속도 측정)

  • Shim Eun-Gi;Hwang Young-Gi;Chun Hai-Soo
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.117-122
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    • 1999
  • This study investigated the corrosion rate of aluminum in alkaline solution. It was performed to observe the effects of alloy element, alkalinity (KOH concentration), solution temperature, and inhibitor and its concentration in the solution. Among species of aluminum, AA-1050 showed the lowest corrosion rate due to its high purity $(>199\%)$, whereas alloys containing Mg anuor Mn were highly corroded, relatively. The corrosion rate could be reduced over than $50\%$ by saturating the solution with ZnO, while ZnAc did not work as an inhibitor. The inhibition effect of ZnO increased with increasing the alkalinity and solution temperature. It was found that the corrosion rate linearly increased with the concentration of KOH in first order and exponentially decreased with the inverse of the solution temperature. An analysis of the corroded material covered the surface of aluminum was made by SEM and EDS. According to the analytical results by using XRD, it was confirmed that $Al(OH)_3$ was produced from the corrosion of aluminum in KOH solution.

Effects of Amino Acids, Carbohydrates and Phosphorus Sources on Growth and Alkaline Phosphatase Activity of the Marine Cyanobacterium Anabaena sp. Strain CA

  • Singh, Jeet Bahadur;Vyas, Deepak;Kumar, Har Darshan
    • Journal of Microbiology and Biotechnology
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    • v.7 no.2
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    • pp.127-131
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    • 1997
  • Alkaline phosphatase (APase) was found to be inducible in Anabaena sp. strain CA Growth was less than control in presence of most amino acids except glycine and serine, but most amino acids enhanced APase activity. Highest APase activity was recorded in tyrosine supplemented culture followed by hydroxyproline, cystein, valine and glutamic acid. Threonine supplemented material showed lowest APase level (1.8 nmol/mg protein/min). Lactose, glucose, sodium pyruvate and succinate stimulated growth but not APase activity. APase activity was high in the presence of sucrose, mellibiose, mannitol, arabinose, maltose and sorbose, even though the growth in these supplements was less than in control. Organic phosphate sources supported good growth of the organism. Best growth occurred in presence of inorganic phosphate, adenosine diphosphate, fructose 1,6-diphosphate or ribulose 1,5-diphosphate, followed by other phosphorus sources tested. APase activity in presence of any of the organic phosphate sources was 3 to 5 fold low as compared to phosphate limited culture. Also, there was no APase activity in cultures grown on inorganic phosphate. These data indicate that most amino acids and a few carbohydrates (sucrose, mellibiose, arabinose and sorbose) are suitable for APase production. Lactose, glucose, pyruvate or succinate may be used as a carbon source during photoheterotrophic growth of the cyanobacterium. Glycine and serine are preferred nitrogen sources for its growth. Phosphate repressible APase activity has been found in Anabaena sp. strain CA.

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Low molecular weight silk fibroin increases alkaline phosphatase and type I collagen expression in MG63 cells

  • Kim, Jwa-Young;Choi, Je-Yong;Jeong, Jae-Hwan;Jang, Eun-Sik;Kim, An-Sook;Kim, Seong-Gon;Kwon, Hae-Yong;Jo, You-Young;Yeo, Joo-Hong
    • BMB Reports
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    • v.43 no.1
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    • pp.52-56
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    • 2010
  • Silk fibroin, produced by the silkworm Bombyx mori, has been widely studied as a scaffold in tissue engineering. Although it has been shown to be slowly biodegradable, cellular responses to degraded silk fibroin fragments are largely unknown. In this study, silk fibroin was added to MG-63 cell cultures, and changes in gene expression in the MG-63 cells were screened by DNA microarray analysis. Genes showing a significant (2-fold) change were selected and their expression changes confirmed by quantitative RT-PCR and western blotting. DNA microarray results showed that alkaline phosphatase (ALP), collagen type-I alpha-1, fibronectin, and transforming growth factor-${\beta}1$ expressions significantly increased. The effect of degraded silk fibroin on osteoblastogenic gene expression was confirmed by observing up-regulation of ALP activity in MG-63 cells. The finding that small fragments of silk fibroin are able to increase the expression of osteoblastogenic genes suggests that controlled degradation of silk fibroin might accelerate new bone formation.