• Journal of the Korean Ceramic Society
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• v.53 no.2
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• pp.129-133
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• 2016

$MnO_2$ was added to the $0.95(Na_{0.5}K_{0.5})NbO_3-0.05CaTiO_3$ (NKN-CT) ceramics in order to promote the densification and improve the poling efficiency by increasing the resistance of the specimens. Densification and abnormal grain growth occurred in the $MnO_2$-added NKN-CT ceramics sintered at $1020^{\circ}C$, indicating that $MnO_2$ assisted the liquid-phase sintering of these materials. $Mn^{3+}$ ions were considered to enter the A-site of the matrix, thereby producing the free electrons, which interacted with the holes resulting from the evaporation of alkali ions. This interaction results in an increase in the resistance of the specimens. The increased resistance improved the poling efficiency and, hence, the dielectric and piezoelectric properties of the NKN-CT ceramics. A few of the $Mn^{3+}$ ions that entered the B-site of the NKN-CT matrix led to a slight increase in the mechanical quality factor.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.415-424
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• 2017

The purpose of this study is to investigate the effect of sulfate (${SO_4}^{2-}$) and magnesium ($Mg^{2+}$) ions on sulfate resistance of Alkali-activated materials using Fly ash and Ground granulated blast furnace slag (GGBFS). In this research, 30%, 50% and 100% of GGBFS was replaced by sodium silicate modules ($Ms(SiO_2/Na_2O)$, molar ratio, 1.0, 1.5 and 2.0). In order to investigate the effects of $Mg^{2+}$ and ${SO_4}^{2-}$, compression strength, weight change, lengh expansion of the samples were measured in 10% sodium sulfate ($Na_2SO_4$), 10%, 5% and 2.5% magnesium sulfate ($MgSO_4$), 10% magnesium nitrate ($Mg(NO_3)_2$), 10% [magnesium chloride ($MgCl_2$) + sodium sulfate ($Na_2SO_4$)] and 10% [magnesium nitrate $(Mg(NO_3)_2$ + sodium sulfate ($Na_2SO_4$)] solution, respectively and X-ray diffraction analysis was conducted after each experiment. As a result, when $Mg^{2+}$ and ${SO_4}^{2-}$ coexist, degradation of compressive strength and expansion of the sample were caused by sulfate erosion. It was found that the reaction of $Mg^{2+}$ with Calcium Silicate Hydrate (C-S-H) occurred and $Ca^{2+}$ was produced. Then the Gypsum ($CaSO_4{\cdot}2H_2O$) was formed due to reaction between $Ca^{2+}$ and ${SO_4}^{2-}$, and also Magnesium hydroxide ($Mg(OH)_2$, Brucite) was produced by the reaction between $Mg^{2+}$ and $OH^-$.

• Journal of the Korea Concrete Institute
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• v.20 no.3
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• pp.405-412
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• 2008

Six alkali-activated (AA) concrete mixes were tested to explore the significance and limitations of developing an environmental friendly concrete. Ground granulated blast-furnace slag and powder typed sodium silicate were selected as source material and an alkaline activator, respectively. The main parameter investigated was the replacement level of lightweight fine aggregate to the natural sand. Workability and mechanical properties of lightweight AA concrete were measured: the variation of slump with time, the rate of compressive strength development, the splitting tensile strength, the moduli of rupture and elasticity, the stress-strain relationship, the bond resistance and shrinkage strain. Test results showed that the compressive strength of lightweight AA concrete sharply decreased when the replacement level of lightweight fine aggregate exceeded 30%. In particular, the increase in the discontinuous grading of lightweight aggregate resulted in the deterioration of the mechanical properties of concrete tested. The measured properties of lightweight AA concrete were also compared, wherever possible, with the results obtained from the design equations specified in ACI 318-05 or EC 2, depending on the relevance, and the results predicted from the empirical equations proposed by Slate et al. for lightweight ordinary Portland cement concrete. The stress-strain curves of different concrete were compared with predictions obtained from the mathematical model proposed by Tasnimi. The measured mechanical properties of lightweight AA concrete generally showed little agreement with the predictions obtained from these equations.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.2
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• pp.94-101
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• 2016

This paper presents an investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(0, 30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0) and initial curing temperatures($23^{\circ}C$ and $70^{\circ}C$). The tests involved immersions for a period of 6 months into 10% solutions of sodium sulfate and magnesium sulfate. The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, as higher GGBFS replace ratio or Ms shown higher compressive strengths on 28 days. In case of immersed in 10% sodium sulfate solution, the samples shows increase in long-term strength. However, for samples immersed in magnesium sulfate solutions, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$); the gypsum increased up to 6 months continuously.

• Journal of Korean Society of Forest Science
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• v.7 no.1
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• pp.8-18
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• 1968

This experiment is a comparative study of influence on the seedling in individual pH treatment of culture soil I. T-R ratio and growth 1. T-R ratio has almost similar tendency in its range according to tree species, but in individual treatment there were lots of differences. In the strong acidic and the strong alkali conditions T-R ratio was small. This means the seedling body is out of balance. 2. Where the resistance to H-ion was stronger, the growth of root-system, that is, the resistance of fine root was comparatively better. 3. The growth of root system was greatly influenced by pH, and in the condition of pH3, pH8, pH9, the growth was especially worse. 4. Ginkgo biloba, Pinus rigida and Pinus banksiana kept on growing in the strong acidic condition. 5. The growth season has higher pH of culture soil than the dormant season, and tree species which have strong resistance of acidic had better growth and had stronger resistance of draught in the acidic condition of culture soil ; especially, Pinus rigida and Pinus banksiana were worse in the alkali condition. II Seedling pH 1. According to the tree species, there were differences in seedling pH, and tree species, considred to be strong in resistance of draught, had been high in seedling pH. 2. Seedling pH of the growth season was higher than that of the dormant season. 3. Seedling pH was not significant in pH treatment of the culture soil.

• Journal of Korean Society of Forest Science
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• v.60 no.1
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• pp.51-57
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• 1983

Properties and glue shear strength of each water soluble rues-phenol copolymer adhesive and phenolic resin adhesive were examined as a high temperature curing binder through the manufacture of plywood made of Kapur veneer. The former has different molar ratio and the latter was made from different catalyst method. The results are summarized as follows: 1) Specific gravities of air dried plywood manufactured from each adhesive ranged from 0.67 to 0.82 and their moisture contents met the K.S. standard 2) In dry and wet shear strength, adhesives with 60 percent of non volatile content showed higher values than those with 50 percent except phenolic resin. Urea-phenol copolymer resin with 20 percent of phenol content exhibited the highest, and that with 70 percent the lowest. Filling effect of wood flour on the bonding strength is great in urea-phenol copolymer resin with more than 50 percent of phenol content, especially significant in 50 percent of non volatile content including alkali catalyst phenolic resin. Alkali and acid catalyst methods were the highest among the adhesive manufacture methods. In wet strength, urea resin belongs to the lowest group. 3) In glue shear strength after boiling and drying test, no method for manufacturing phenolic formaldehyde resin adhesive was stronger than alkali and acid catalyst methods. Phenolic resin made from alkali catalyst method needs a wood flour filler to improve the bonding quality. Urea-phenol copolymer resin with 10 percent of phenol content showed the reasonable water resistance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.2
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• pp.74-80
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• 2011

In this study, it is evaluated on the properties of mechanical performance, autogenous shrinkage and chloride resistance for application of high performance concrete for bridge deck overlay used slag powder and fly ash as a representative by-product of industrialization. According to test results, it is evaluated that the durability of concrete is improved the properties of chloride resistance, autogenous shrinkage and alkali aggregate reaction by using hydraulic mineral admixtures. It is considered to have a green construction and an economic feasibility on recycling of by-product as a improved concrete for durability and efficiency in materials and constructions.

• Korean Journal of Materials Research
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• v.24 no.6
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• pp.285-292
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• 2014

Commercial activated-carbon used as the electrode material of an electric double-layer capacitor (EDLC) was posttreated with various acids and alkalis to increase its capacitance. The carbon samples prepared were then heat-treated in order to control the amount of acidic functional groups formed by the acid treatments. Coin-type EDLC cells with two symmetric carbon electrodes were assembled using the prepared carbon materials and an organic electrolyte. The electrochemical performance of the EDLC was measured by galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the various activated carbons, the carbon electrodes (CSsb800) prepared by the treatments of coconutshell-based carbon activated with NaOH and $H_3BO_5$, and then heat treated at $800^{\circ}C$ under a flow of nitrogen gas, showed relatively good electrochemical performance. Although the specific-surface-area of the carbon-electrode material ($1,096m^2/g$) was less than that of pristine activated-carbon ($1,122m^2/g$), the meso-pore volume increased after the combined chemical and heat treatments. The specific capacitance of the EDLC increased from 59.6 to 74.8 F/g (26%) after those post treatments. The equivalent series resistance of EDLC using CSsb800 as electrode was much lower than that of EDLC using pristine activated carbon. Therefore, CSsb800 exhibited superior electrochemical performance at high scan rates due to its low internal resistance.

• Journal of Conservation Science
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• v.35 no.4
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• pp.317-329
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• 2019

Slag was collected from the iron-producing furnace site in Saengsoegol, Baegun mountain, where iron was manufactured by a righteous army against Japan in the Gwangyang region; then, the iron-manufacturing technique of the early modern period was investigated through scientific analysis. In the microstructure analysis results of the selected samples, iron bloom was mainly observed together with magnetite and fayalite. In the component analysis results of the compounds, it was confirmed that the furnace was built by using gangue of alkali feldspar or plagioclase series, and the ironmaking work was performed at a high temperature of at least 1050℃, because mullite was identified together with cristobalite and hercynite. Based on the chemical composition, it was speculated that low-grade iron ores were used as raw materials, and it seemed that the yield was low, because the total Fe content of the smelting slag samples was 37.72-49.93%. It was difficult to confirm whether a slag former was used, and it seemed that materials easily obtained nearby were used when the furnace was built, without considering the corrosion resistance. It appeared that the ironmaking work was performed at the Gwangyang Saengsoegol iron-producing furnace based on the direct ironmaking method in an environment that could escape the vigilance of the Japanese Empire to produce weapons that would be used for the resistance against Japan. It seemed that there was neither an advanced ironware production system nor a mass production system, and small-scale works were performed in short periods of time.

• Advances in concrete construction
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• v.2 no.2
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• pp.109-123
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• 2014

This paper presents chloride induced corrosion durability of reinforcing steel in geopolymer concretes containing different contents of sodium silicate ($Na_2SiO_3$) and molarities of NaOH solutions. Seven series of mixes are considered in this study. The first series is ordinary Portland cement (OPC) concrete and is considered as the control mix. The rest six series are geopolymer concretes containing 14 and 16 molar NaOH and $Na_2SiO_3$ to NaOH ratios of 2.5, 3.0 and 3.5. In each series three lollypop specimens of 100 mm in diameter and 200 mm in length, each having one 12 mm diameter steel bar are considered for chloride induced corrosion study. The specimens are subjected to cyclic wetting and drying regime for two months. In wet cycle the specimens are immersed in water containing 3.5% (by wt.) NaCl salt for 4 days, while in dry cycle the specimens are placed in open air for three days. The corrosion activity is monitored by measuring the copper/copper sulphate ($Cu/CuSO_4$) half-cell potential according to ASTM C-876. The chloride penetration depth and sorptivity of all seven concretes are also measured. Results show that the geopolymer concretes exhibited better corrosion resistance than OPC concrete. The higher the amount of $Na_2SiO_3$ and higher the concentration of NaOH solutions the better the corrosion resistance of geopolymer concrete is. Similar behaviour is also observed in sorptivity and chloride penetration depth measurements. Generally, the geopolymer concretes exhibited lower sorptivity and chloride penetration depth than that of OPC concrete. Correlation between the sorptivity and the chloride penetration of geopolymer concretes is established. Correlations are also established between 28 days compressive strength and sorptivity and between 28 days compressive strength and chloride penetration of geopolymer concretes.