• Title/Summary/Keyword: AlInN

Search Result 3,189, Processing Time 0.032 seconds

Formation Mechanism of a Large Schottky Barrier Height for Cr-AlGaN/GaN Heterostructure (Cr/n-AlGaN/GaN Schottky Contact에서 높은 쇼트키 장벽 형성 메카니즘에 관한 연구)

  • Nam, Hyo-Duk;Lee, Yeung-Min;Jang, Ja-Soon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.24 no.4
    • /
    • pp.266-270
    • /
    • 2011
  • We report on the formation mechanism of large Schottky barrier height (SBH) of nonalloyed Cr Schottky contacts on strained Al0.25Ga0.75N/GaN. Based on the current-voltage (I-V) and capacitance-voltage (C-V) data, the SBHs are determined to be 1.98 (${\pm}0.02$) and 2.07 (${\pm}0.02$) eV from the thermionic field emission and two-dimensional electron gas (2DEG) calculations, respectively. Possible formation mechanism of large SBH will be described in terms of the formation of Cr-O chemical bonding at the interface between Cr and AlGaN/GaN, low binding-energy shift to surface Fermi level, and the reduction of 2DEG electrons.

Nitrogenation of Coal Ash in the Presence of Carbon and Product Distributions of AlN, SiC and Si₃N₄ (석탄회의 탄소가 첨가된 질화반응과 AlN, SiC 그리고 Si₃N₄의 생성분포)

  • 양현수;홍원표;노재성;서동수;손응권
    • Journal of the Korean Ceramic Society
    • /
    • v.27 no.8
    • /
    • pp.956-956
    • /
    • 1990
  • A nitrogenation of coal ash in the presence of carbon was carried out to examine the effects of reaction temperature, reaction time and carbon composition on the formation of AlN, SiC and Si3N4. Decreasing the particle size increased the formation of AlN and its maximum composition in the product was obtaiend under 1450∼1500℃, 2 hours of reaction time and about 30% of carbon addition(on the basis of sample weight). Compositions of SiC and Si3N4 were distributed to the opposite so that SiC showed a higher composition compared with Si3N4 at a lower temperature, a shorter reaction time and a greater carbon addition.

Synthesis of AlN Powder from Al2(SO4)3.18H2O: I. Precipitation Method (Al2(SO4)3.18H2O로부터 AlN 분말의 합성: I. 침전법)

  • 이홍림;송태호
    • Journal of the Korean Ceramic Society
    • /
    • v.28 no.6
    • /
    • pp.465-470
    • /
    • 1991
  • AlN powder was synthesized by carbothermal reduction and nitridation of aluminum hydroxides precipitated in 5∼11 pH range from Al2(SO4)3$.$18H2O aqueous solution. Nitridation reactivity of hydroxide, which depends on precipitation pH, reaction temperature and time, was examined by XRD analysis at 1200∼1350$^{\circ}C$ and compared with that of commercial ${\alpha}$-Al2O3. Hydroxides obtained at higher pH could be more easily nitridated and, considering DTA/TG and BET results, the reason seems to be specific surface area difference of reactants depending on the content of decomposed structural water and the transition rate from transition-Al2O3 to ${\alpha}$-Al2O3.

  • PDF

Efficiency Improvement with $Al_2O_3/SiN_x$ Rear Passivation of p-type Mono-crystalline Silicon Solar Cells ($Al_2O_3/SiN_x$ 후면 적층 패시베이션을 이용한 결정질 실리콘 태양전지의 효율 향상 연구)

  • Cheon, Joo Yong;Beak, Sin Hey;Kim, In Seob;Chun, Hui Gon
    • Journal of the Semiconductor & Display Technology
    • /
    • v.12 no.3
    • /
    • pp.47-51
    • /
    • 2013
  • Current research trends of solar cells has focused on the high conversion efficiency and low-cost production technology. Passivation technology that can be easily adapted to mass production. Therefore, this study conducted experiments with aim of the following two methods for the fabrication of high-efficiency crystalline silicon solar cells. In the first task, an attempt is formation of local Al-BSF to a number of locally doped dots to increase the conversion efficiency of solar cells to reduce the loss of $V_{oc}$ overcome. The second major task, rear surface apply in $Al_2O_3/SiN_x$ stack layer, $Al_2O_3$ prominent negative fixed charge characteristics. As the result of task, Local Al-BSF and $Al_2O_3/SiN_x$ stack layer applied to the p-type single crystalline silicon solar cells, the average $V_{oc}$ of 644mV, $I_{sc}$ of 918mV and conversion efficiency of 18.70% were obtained.

Comparison of Degradation Behaviors for Titanium-based Hard Coatings by Pulsed Laser Thermal Shock

  • Jeon, Seol;Lee, Heesoo
    • Journal of the Korean Ceramic Society
    • /
    • v.50 no.6
    • /
    • pp.523-527
    • /
    • 2013
  • Ti-based coatings following laser ablation were studied to compare degradation behaviors by thermomechanical stress. TiN, TiCN, and TiAlN coatings were degraded by a Nd:YAG pulsed laser with an increase in the laser pulses. A decrease in the hardness was identified as the pulses increased, and the hardness levels were in the order of TiAlN > TiCN > TiN. The TiN showed cracks on the surface, and cracks with pores formed along the cracks were observed in the TiCN. The dominant degradation behavior of the TiAlN was surface pore formation. EDS results revealed that diffusion of substrate atoms to the coating surface occurred in the TiN. Delamination occurred in the TiN and TiCN, while the TiAlN which has higher thermal stability than the TiN and TiCN maintained adhesion to the substrate. It was considered that the decrease in the hardness of the Ti-based hard coatings is attributed to surface cracking and the diffusion of substrate atoms.

Effect of V/III Ratio Variation on the Properties of AlN Epilayers in HVPE (HVPE법에 의해 성장된 AlN 에피층의 V/III비에 따른 특성변화)

  • Son, Hoki;Lim, Tae-Young;Lee, Mijai;Kim, Jin-Ho;Kim, Younghee;Hwang, Jonghee;Oh, Hae-Kon;Choi, YoungJun;Lee, Hae-Yong;Kim, Hyung Sun
    • Korean Journal of Materials Research
    • /
    • v.23 no.12
    • /
    • pp.732-736
    • /
    • 2013
  • AlN epilayers were grown on a c-plane sapphire substrate using hydride vapor phase epitaxy (HVPE). A series of AlN epilayers were grown at $1120^{\circ}C$ with V/III ratios 1.5, 2.5 and 3.5, and the influence of V/III ratio on their properties was investigated. As the V/III ratio was increased, the surface roughness (RMS roughness), Raman shift of $E_2$ high peaks and full-width at half-maximum (FWHM) of symmetrical (002) & asymmetrical (102) of the AlN epilayers increased. However, the intensities of the Raman $E_2$ high peaks were reduced. This indicates that the crystal quality of the grown AlN epilayers was degraded by activation of the parasitic reaction as the V/III ratio was increased. Smooth surface, stress free and high crystal quality AlN epilayers were obtained at the V/III ratio of 1.5. The crystal quality of AlNepilayers is worsened by the promotion of three-dimensional (3D) growth mode when the flow of $NH_3$ is high.

Five new species of genus Hyattella (Dictyoceratida: Spongiidae) from Korea

  • Young A Kim;Kyung Jin Lee
    • Journal of Species Research
    • /
    • v.13 no.1
    • /
    • pp.32-40
    • /
    • 2024
  • Five new species of the genus Hyattella (Dictyoceratida: Spongiidae) were collected from Jejudo and Gageodo, Korea: Hy. gukheulensis n. sp., Hy. regularis n. sp., Hy. lenis n. sp., Hy. membrana n. sp., and Hy. asper n. sp. Hyattella gukheulensis n. sp. is similar to Hy. munseomensis Sim et al., 2015 in shape, but differs in skeletal structure. Hyattella regularis n. sp. is close to Hy. bakusi Sim et al., 2015 but differs in regular secondary fibres at the surface membrane. Hyattella lenis n. sp. is unique by having numerous windings at the surface. Hyattella membrana n. sp. is similar to Hy. bakusi Sim et al., 2015 in shape, but differs in surface and skeletal fibres. Hyattella asper n. sp. is close to Hy. lendenfeldi Sim and Lee, 2014 in skeletal fibres, but differs in thin secondary fibres. This new species has numerous dense cored primary fibres.

Evaluation of Micro End-Milling Characteristics of AlN-hBN Composites Sintered by Hot-Pressing (열간가압소결에 의해 제조된 AlN-hBN 복합재료의 마이크로 엔드밀링 가공특성 평가)

  • Baek, Si-Young;Cho, Myeong-Woo;Seo, Tae-Il
    • Korean Journal of Metals and Materials
    • /
    • v.46 no.6
    • /
    • pp.390-401
    • /
    • 2008
  • The objective of this study is to evaluate various machining characteristics of AlN-hBN machinable ceramics in micro end-milling process for its further application. First, AlN based machinable ceramics with hBN contents in the range of 10 to 20vol% were prepared by hot-pressing. Material properties of the composites, such as relative density, Vickers hardness, flexural strength, Young's modulus and fracture toughness were measured and compared. Then, micro end-milling experiments were performed to fabricate micro channels using prepared system. During the process, cutting forces, vibrations and AE signals were measured and analyzed using applied sensor system. Machined micro channel shapes and surface roughness were measured using 3D non-contact type surface profiler. From the experimental results, it can be observed that the cutting forces, vibrations and AE signal amplitudes decreased with increasing hBN contents. Also, measured surface roughness and profiles were improved with increasing hBN contents. As a result of this study, optimum machining conditions can be determined to fabricate desired products with AlN-hBN machinable ceramics based on the experimental results of this research.

Antioxidation mechanism of Al metal powders on $Al_2O_3-C$ refractory ($Al_2O_3-C$계 내화물에서 알루미늄 금속분말의 산화억제 메카니즘)

  • 류정호;임창성;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.8 no.1
    • /
    • pp.97-105
    • /
    • 1998
  • Antioxidation mechanism of Al metal powders on $Al_2O_3-C$ refractory was investigated in temperature range from 800 to $1400^{\circ}C$. The addition of 5 wt% Al metal powders suppressed the oxidation of carbon in $Al_2O_3$-C sample. The carbons were distributed uniformly on the surface and the interface of the $Al_2O_3$-C-Al. Reaction products of $Al_4C_3$ and AIN were found with a composition of Al-C at temperatures between 800 and $1200^{\circ}C$ and transformed to $Al_2O_3$ above $1400^{\circ}C$. Cavity structures related to the to the formation of $Al_4C_3$ were observed for the AI-C after heating at $1000^{\circ}C$ ofr 1 hour. Thermodynamic mechanism was considered to discuss the formation $Al_4C_3$, AlN and their transformation to $Al_2O_3$, which leads to the effect of oxidation resistance.

  • PDF

Implementation of High Carrier Mobility in Al-N Codoped p-Type ZnO Thin Films Fabricated by Direct Current Magnetron Sputtering with ZnO:Al2O3 Ceramic Target

  • Jin, Hujie;Xu, Bing;Park, Choon-Bae
    • Transactions on Electrical and Electronic Materials
    • /
    • v.12 no.4
    • /
    • pp.169-173
    • /
    • 2011
  • In this study, Al-N codoped p-type zinc oxide (ZnO) thin films were deposited on Si and homo-buffer layer templates in a mixture of $N_2$ and $O_2$ gas with ceramic ZnO:(2 wt% $Al_2O_3$) as a sputtering target using DC- magnetron sputtering. X-ray diffraction spectra of two-theta diffraction showed that all films have a predominant (002) peak of ZnO Wurtzite structure. As the $N_2$ fraction in the mixed $N_2$ and $O_2$ gases increased, field emission secondary electron microscopy revealed that the surface appearance of codoped films on Si varied from smooth to textured structure. The p-type ZnO thin films showed carrier concentration in the range of $1.5{\times}10^{15}-2.93{\times}10^{17}\;cm^{-3}$, resistivity in the range of 131.2-2.864 ${\Omega}cm$, and mobility in the range of $3.99-31.6\;cm^2V^{-1}s^{-1}$ respectively.