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Coloration and Chemical Stability of SiO2 and SnO2 Coated Blue CoAl2O4 Pigment (SiO2, SnO2 코팅된 청색 CoAl2O4 안료의 색상, 물성 평가 연구)

  • Yun, JiYeon;Yu, Ri;Pee, Jae-Hwan;Kim, YooJin
    • Journal of Powder Materials
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    • v.21 no.5
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    • pp.377-381
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    • 2014
  • This work describes the coloration, chemical stability of $SiO_2$ and $SnO_2$-coated blue $CoAl_2O_4$ pigment. The $CoAl_2O_4$, raw materials, were synthesized by a co-precipitation method and coated with silica ($SiO_2$) and tin oxide ($SnO_2$) using sol-gel method, respectively. To study phase and coloration of $CoAl_2O_4$, we prepared nano sized $CoAl_2O_4$ pigments which were coated $SiO_2$ and $SnO_2$ using tetraethylorthosilicate, $Na_2SiO_3$ and $Na_2SiO_3$ as a coating material. To determine the stability of the coated samples and their colloidal solutions under acidic and basic conditions, colloidal nanoparticle solutions with various pH values were prepared and monitored over time. Blue $CoAl_2O_4$ solutions were tuned yellow color under all acidic/basic conditions. On the other hand, the chemical stability of $SiO_2$ and $SnO_2$-coated $CoAl_2O_4$ solution were improved when all samples pH values, respectively. Phase stability under acidic/basic condition of the core-shell type $CoAl_2O_4$ powders were characterized by transmission electron microscope, X-ray diffraction, CIE $L^*a^*b^*$ color parameter measurements.

Oral Cancer Awareness of the General Public in Saudi Arabia

  • Al-Maweri, Sadeq Ali;Tarakji, Bassel;Alsalhani, Anas B;Al-Shamiri, Hashem M;Alaizari, Nader Ahmed;Altamimi, Mohammad Al Sakran;Darwish, Shourouk
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.8
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    • pp.3377-3381
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    • 2015
  • Background: The aim of this study was to assess the level of awareness and knowledge about signs and risk factors of oral cancer in the general population in Saudi Arabia. Materials and Methods: A self-administered questionnaire was used to collect information from Saudi adults aged 15 years and older. A total of 679 persons participated in the survey. Descriptive statistics were calculated and chi-square tests, t-tests, and one-way analysis of variance (ANOVA) were used to examine differences between groups. The significance level was set at p<0.05. Results: Only 53.6% of the participants had heard of oral cancer. Smoking and alcohol consumption were identified as the major risk factors by 81.7% and 56.3% of the participants, respectively. Only 22.2% and 18.2%, respectively, were able to correctly identify red and white lesions as early signs of oral cancer. Participants with less than high school education were significantly less aware, and had much less knowledge, of the signs and risk factors of oral cancer (p<0.05). Conclusions: This survey demonstrates a general lack of awareness among the public about oral cancer and a lack of knowledge about its signs and risk factors. There is a clear need to inform and educate the public in matters relating to the known risk factors associated with oral cancer. A media campaign informing the public about oral cancer is clearly required.

Effect of Silicon Application on Growth Response of Alfalfa Seedlings Grown under Aluminum Stress in Pots

  • Yoon, Il-Kyu;Kim, Min-Jun;Min, Chang-Woo;Khan, Inam;Lee, Byung-Hyun
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.41 no.3
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    • pp.162-167
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    • 2021
  • Aluminum (Al) stress in acidic pH is known to decrease the growth and productivity of alfalfa. However, not much is known about how the application of silicon (Si) affects the Al stress response in alfalfa. This study was conducted to evaluate the effect of exogenous application of Si on the growth of alfalfa seedlings exposed to Al stress in pots. Alfalfa seedlings grown in pots for 2 weeks were treated either Al stress (pH 4.0, 0.2 mM Al) or Al stress + Si (1 mM) for 5 days, lengths and biomass of shoot and root, and chlorophyll and carotenoid contents in leaf tissues were analyzed respectively. Al stress treatment inhibited shoot and root growth, and decreased fresh and dry weights, and chlorophyll content in leaves, but increased carotenoid content. In contrast, when alfalfa seedlings treated with Al stress combined with Si, delayed growth caused by Al stress of shoot and root of alfalfa seedlings was restored, dry weight was increased and chlorophyll content of leaf tissue was increased, but carotenoid content was decreased. These results suggest that Si has a function of alleviating Al toxicity in alfalfa, of which it exhibits a mitigating effect by a function that overlaps with some of the intracellular functions of carotenoids.

Characteristics of Water Contamination and Precipitates of Acid Mine Drainage, Bongyang Abandoned Coal Mine, Danyang, Chungbuk Province with Emphasis on Fe and Al behaviors (충북 단양 봉양폐탄광 산성광산배수의 수질오염과 침전물의 특성: 철, 알루미늄의 거동을 중심으로)

  • Choo, Chang Oh;Lee, Jin Kook
    • The Journal of Engineering Geology
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    • v.29 no.2
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    • pp.163-183
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    • 2019
  • We investigated acid mine drainage (AMD) of Bongyang abandoned coal mine, Danyang, Chungbuk Province with emphasis on geochemical contaminants in AMD and precipitates using chemical analyses, XRD, SEM, IR, and $^{27}Al$ NMR. Water chemistry changes with pH and oversaturation of chemical species. According to calculation of saturation index, the AMD is saturated with various Fe, Al minerals. Orange or orcher precipitates are composed of schwertmannite and goethite, associated with Leptothrix orchracea bacteria, whereas whitish precipitates are composed mostly of alumimous minerals such as basaluminite with poor crystallinity. The whitish precipitates include trace $Al_{13}$-Tridecamer. It is important to control the precipitation and solubility of aluminous species for ensuring remediation and control for the AMD discharged from the Bongyang abandoned coal mine.

Microstructure and Mechanical Properties of Hypereutectic Al-Si Alloy Bars Processed via Horizontal Continuous Casting (수평연속주조한 과공정 Al-Si합금 소경봉의 미세조직 및 기계적성질)

  • Kim, Wan-Chul;Park, Ji-Ha;You, Bong-Sun;Park, Won-Wook
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.585-591
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    • 1997
  • Hyper-eutectic Al-17.5wt%Si alloy bars of 25 mm in diameter were produced by horizontal continuous casting process. Effect of both casting speed and primary Si refiner (AlCuP) on microstructure and mechanical properties of the alloy have been investigated. With increasing a weight fraction of AlCuP, the average primary Si size decreased down to $20 {\mu}m$. On the contrary, there was no notable changes of microstructure and primary Si size according to the casting speed in the experimental range of this study, indicating that the cooling rate should be increased to optimize and refine microstructure and primary Si size. The experimental results including hardness, tensile strength and wear resistance tests of the processed alloy bars showed a good possibility to develop the high performance wear resistant Al-Si alloy.

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A Study on the Microstructures and Properties of $Al-SiC)_p$ Metal Matrix Composites Fabricated by Spray Forming Process (분무성형법에 의해 제조된 $Al-SiC)_p$ 금속기 복합재료의 미세조직과 성질에 관한 연구)

  • 김춘근
    • Journal of Powder Materials
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    • v.1 no.1
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    • pp.42-51
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    • 1994
  • 6061Al-SiCP metal matrix composite materials(MMCs) were fabricated by injecting SiCP particles directly into the atomized spray. The main attraction of this technique is the rapid fabrication of semi-finished, composite products in a combined atomization, particulate injection(10 $\mu\textrm{m}$, 40 $\mu\textrm{m}$, SiCP) and deposition operation. Conclusions obtained are as follows; The microstructure of the unreinforced spray formed 6061Al alloy consisted of relatively fine(50 $\mu\textrm{m}$) equiaxed grains. By comparision, the microstructure of the I/M materials was segregated and consisted of relatively coarse(150 $\mu\textrm{m}$) grains. The probability of clustering of SiCP particles in co-sprayed metal matrix composites increased it ceramic particle size(SiCP) was reduced and the volume fraction was held constant. Analysis of overspray powders collected from the spray atomization and deposition experiments indicated that morphology of powders were nearly spherical and degree of powders sphercity was deviated due to composite with SiCp particles. Interfacial bonding between matrix and ceramics was improved by heat treatment and addition of alloying elements(Mg). Maximum hardness values [Hv: 165 kg/mm2 for Al-10 $\mu\textrm{m}$ SiCp Hv--159 kg/mm2 for Al-40 $\mu\textrm{m}$SiCp] were obtained through the solution heat treatment at $530^{\circ}C$ for 2 hrs and aging at $178^{\circ}C$, and there by the resistance were improved.

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Fabrication of α-Alumina Nanopowders by Thermal Decomposition of Ammonium Aluminum Carbonate Hydroxide (AACH) (암모늄 알루미늄 탄산염(hhCH)의 열분해에 의한 α-알루미나 나노분말 제조)

  • O, Yong-Taeg;Shin, Dong-Chan;Kim, Sang-Woo
    • Journal of the Korean Ceramic Society
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    • v.43 no.4 s.287
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    • pp.242-246
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    • 2006
  • [ ${\alpha}-Al_2O_3$ ] nanopowders were fabricated by the thermal decomposition and synthetic of Ammonium Aluminum Carbonate Hydroxide (AACH). Crystallite size of 5 to 8 nm were fabricated when reaction temperature of AACH was low, $8^{\circ}C$, and the highest $[NH_4{^+}][AlO(OH)_n{(SO_4){^-}}_{3-n/2}][HCO_3]$ ionic concentration to pH of the Ammonium Hydrogen Carbonate (AHC) aqueous solution was 10. The phase transformation fem $NH_4Al(SO_4)_2$, rhombohedral $(Al_2(SO_4)_3)$, amorphous-, ${\theta}-,\;{\alpha}-Al_2O_3$ was examined at each temperature according to the AACH. A Time-Temperature-Transformation (TTT) diagram for thermal decomposition in air was determined. Homogeneous, spherical nanopowders with a particle size of 70 nm were obtained by firing the 5 to 8 m crystallites, which had been synthesized from AACH at pH 10 and $8^{\circ}C,\;at\;1150^{\circ}C$ for 3 h in air.

A Study on the Influence of Al Alloy Sacrificial Anode Efficiency due to Marine Environmental Variation (해양환경 변화가 알루미늄합금 희생양극의 효율에 미치는 영향에 관한 연구)

  • 김도형
    • Journal of Ocean Engineering and Technology
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    • v.14 no.2
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    • pp.106-111
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    • 2000
  • Recently it was reported that the life of Al Sacrifical anode is being used in port piers has been significantly shortened compared with the original design life (e.g. average life shortened from 20 years to 13-15 year) Those factors involving these problems mentioned above were seemed to be a quality of anode material and diverse environmental factors such as pH flow rate temperature Dissolved oxygen Chemical oxygen demand and resistivity etcm In this study flow rate and contamination degree(pH) of sea water affecting to sacrificial anode life hve been investigated in terms of electrochemical characteristics of Al alloy sacrificial anode It was known that the lifetime of Al alloy anode was shortened not only by increasing of self-corrosion quantity by varying flow rate of sea water but also by increasing corrosion current density due to the potential difference increment between Al anode and steel structure cathode by varying contamination degree of sea water. Especially when anode current density is from 1mA/cm2 to 3mA/cm2 and flow rate of sea water is under 2m/s anode current efficiency is 90% above However flow rate is over 2m/s anode current efficiency fell down sharply due to erosion corrosion as well as galvanic corrosion.

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First-Principle Calculation Study of Cu Adsorption on X-doped (X=Ru, P, Si) 𝛾-Al2O3 (X-doped (X=Ru, P, Si) 𝛾-Al2O3 상의 Cu 흡착 제일원리 계산 연구)

  • LEE, EUNHYE;JI, HYUNJIN;CHOI, EUNYEONG;LEE, JUNGHUN;CHO, JANGHYEON
    • Journal of Hydrogen and New Energy
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    • v.33 no.1
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    • pp.105-112
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    • 2022
  • Copper (Cu)-based catalysts have been widely used in a methanol steam reforming (MSR) reaction for hydrogen production for air-independent propulsion (AIP) applications and their good catalytic activities have attracted much attention. However, the agglomeration of the catalytic active site Cu causes deteriorating the catalytic performance and suppression of Cu agglomeration is a crucial issue in the AIP applications that the MSR system is typically operated at 250-300℃ for a long time. R. Sakai et al. recently showed a computational study on the anchoring effect that reduces an agglomeration of active sites by doping in a supporter. In order to present the anchoring effect on 𝛾-Al2O3 supported Cu-based catalysts, in this study, the adsorption energies of Cu on X-doped (X=ruthenium, phosphorus, silicon) 𝛾-Al2O3 were calculated and Cu adsorption energy decreased due to a change of the electronic structure originated from doping, thereby proving the anchoring effect.

Studies on the Asplund Pulping of Wood for Paper Pulp(II) -Effect of some cellulose stabilizers added to the alkaline chip-treatment and the peroxide bleaching on the quality of larchwood asplund pulps- (제지용(製紙用) 아스플룬드펄프 제조(製造)에 관한 연구(II) -일본 잎갈나무��의 알카리 전처리(前處理)와 아스플룬드 펄프의 과산화물(過酸化物) 표백(漂白)에서 셀룰로오스 안정제(安定劑)의 영향(影響)에 관하여-)

  • Lim, Kie-Pyo
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.3
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    • pp.7-15
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    • 1981
  • A Japanese larch has been reforested very much in Korea, but it is not used as a wood resources for paper pulp by now. So this study is carried out to utilize the larchwood for paper pulp manufacture through the Asplund pulping process. The experiment on increasing in the brightness of the pulp is made through the addition of $MgSO_4$, $ZnSO_4$, $Al_2(SO_4)_3$, and KI as a cellulose stabilizer in chip treatment with caustic soda which is followed by high-temperature defibration and conventional peroxide bleaching (5% NaOH plus 2% additive salt per wood in cold pretreatment), or in high-consistency (30%) pulp bleaching of hydrogen peroxide and peracetic acid (100% acitve oxygen per lignin) for conventional one. The results obtained are as follows: 1. The solution of 0.5% additive salts had different pH by the sort of bases that was pH 5.7 in $MgSO_4$, liquor, pH 4.9 for $ZnSO_4$, and pH 2.9 for $Al_2(SO_4)_3$, and in the precepitation of bases which ranged to pH 6-13 for $MgSO_4$, pH 5-12 for $ZnSO_4$, and pH 3-10 for $Al_2(SO_4)_3$. 2. The cellulose stabilizer affective in high-consistency peroxide bleaching was KI, $MgSO_4$, and $ZnSO_4$, but has made a little improvement in de lignification and brightness of pulp in comparison with no addition. 3. The higher alkalinity in the chip treatment has made the higher strength and brightness of larchwood Aspiund pulp instead of downing the pulp yield. And the effective compound for cellulose stabilizer in caustic soda pretreatment of chip was $ZnSO_4$, $Al_2(SO_4)_3$ and KI in order for the conventional peroxide bleaching after Asplund pulping. 4. Therefore, the more effective additives for cellulose stabilization in high-temperature defibration of larchwood suppose to be $ZnSO_4$, $Al_2(SO_4)_3$, and KI, while KI and $MgSO_4$ for peroxide bleaching.

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