• Title/Summary/Keyword: Air pollutants concentration

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Heavy Metal Distributions of Soils in the Vicinity of Shi-Hwa Industrial Complex Region (시화공업단지 주변지역 토양의 중금속 분포)

  • 송영배;이상모
    • Journal of Soil and Groundwater Environment
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    • v.8 no.2
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    • pp.87-91
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    • 2003
  • This study was carried out to investigate the heavy metal distributions of soils in the vicinity of Shi-Hwa industrial complex region, where the air pollutants from industrial area could affect the soil environment of near residential and green areas. The ranges of contents of As, Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn in soils were 0.58~3.81, ND~0.91, 0.15~6.33, ND~l.86, 0.14~110.27, ND~l.17, 0.04~10.59, 1.16~86.48 and 1.83~212.65 mg/kg, respectively. For all industrial, residential and green areas, the heavy metal contents were much lower than the standard of Korean Soil Environmental Preservation Act or the critical concentration which phytotoxicity is considered to be possible. Mean values of contents of As were similar in industrial, residential and green areas. However, the mean values of contents of Cd and Cr in industrial area were higher 10 and 5 times than those in residential and green area, respectively. And also the mean values of contents of Co, Cu, Hg, Ni, Pb and Zn in industrial area were higher 2~3 times than those in residential and green area.

Occupational Exposure Aspects of Gasoline Vapor According to the Use of a Gasoline Vapor Recovery System (주유소 유증기 회수설비 사용에 따른 가솔린 증기의 개인노출양상)

  • Lee, Heemyung;Won, Jong-Uk;Kim, Chi-Nyon;Roh, Jaehoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.2
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    • pp.156-165
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    • 2015
  • Objectives: The purpose of this study was to investigate the possible effects of a gasoline vapor recovery system on personal exposure levels of gasoline vapor constituents including benzene, toluene, ethyl benzene, xylene(BTEX), and methyl tert-butyl ether(MTBE) among gas station workers in a metropolitan area. Methods: Thirty-one gas station workers at ten gas stations in a metropolitan area were selected as subjects for this study. Test method PV2028 as recommended in the OSHA process was used for sampling and analysis. Results: The personal exposure levels of benzene, toluene, ethyl benzene, xylene, MTBE and gasoline vapor in the gas station workers were $0.0018{\pm}0.0069ppm$, $0.0077{\pm}0.0137ppm$, $0.0002{\pm}0.0008ppm$, $0.0016{\pm}0.0084ppm$, $0.2619{\pm}0.3340ppm$, and $1.4940{\pm}1.7984ppm$, respectively. After adjustment for refueling frequency and volume, personal exposure levelswere higher in the gas stations where gasoline vapor recovery systems(Stage II) were not installed, but the results were not statistically significant. Gasoline vapor concentrations showed a positive correlation to the level of MTBE, a gasoline additive. Conclusions: Vapor recovery systems(Stage II) were effective not only in reducing emissions of air pollutants, but also in reducing exposure to hazardous substances among gas station workers. In addition, acorrelation between gasoline vapors and MTBE concentration was confirmed.

Preparation and Application of Charcoal-Encapsulated Methyl Silica Microcapsules (활성탄을 함유한 메틸실리카 마이크로캡슐의 제조 및 응용)

  • Ahn, Bok-Yeop;Lee, Yu-Mi;Ham, Myung-Kyung;Rhee, Dong-Seok
    • Journal of Industrial Technology
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    • v.23 no.A
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    • pp.199-206
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    • 2003
  • The charcoal-encapsulated methyl silica microcapsules were prepared by a O/W microemulsion sol-gel method, and the adsorption properties on aquatic humic acid were investigated. The capsules prepared were spherical, $100{\sim}1000{\mu}m$ in size. The size distribution was controllable by adjusting the size of charcoal powder, charcoal/methyl silica ratio, and agitating speed in O/W sol-gel process. Adsorption efficiency of charcoal for aquatic humic acid was decreased after encapsulation by methyl silica shell. The decreased adsorption efficiency can be dependent on the decrease of the BET surface area and pore volume after encapsulation. Diffusion properties of humic acid through the capsule shell also played an important role on adsorption efficiency. Therefore, the reasonable target pollutants for the capsules can be VOC or odor molecules which can overcome diffusion barrier through shell of capsules in air condition. Functionalization methods for the charcoal-encapsulated $CH_3(SiO)_n$ microcapsules by incorporation of $TiO_3$ as a phtocatalytic function and by incorporation of inorganic pigment as a color function were also investigated. $TiO_2$ coating properties were controllable by adjusting pH, temperature, and the concentration of $TiOSO_4$. In XRD measurement, the crystal form of the coated $TiO_2$ was anatase. For the colorization of the capsules, inorganic pigments were more efficient than organic dyes, and various color was introduced to the capsules using inorganic pigments.

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Estimation of polycyclic aromatic hydrocarbons emission from sewage sludge of sewerage treatment plants in Korea

  • Kim, Dong-Hwan;Hwang, Jong-Seob;Lee, Min-Hee;Ok, Gon
    • Journal of Environmental Science International
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    • v.12 no.11
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    • pp.1167-1171
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    • 2003
  • Polycyclic aromatic hydrocarbons (PAHs) are an important group of organic contaminants present in sewage sludge, due to their persistence, toxic, bioaccumulative and long range transfer. These characters make themselves as Persistent Organic Pollutants(POPs) in Long Range Transboundary Air Pollutions convention(LRTAP) of Europe. A method of the gas chromatographicmass spectrometric (GCMS) determination of PAHs present in sewage sludge was developed and applied to analyzed samples from five sewerage treatment plants (SWTPs), having different treatment types. PAHs were extracted from freeze-dried samples by toluene 16 hours in a soxhlet extraction system. The sludge extracts were cleaned-up by an activated silica gel column chromatography. The sum of the 16 US Environmental Protection Agency PAHs sewage sludge samples varied from 2.44 to 4.82 $\mu\textrm{g}$/g. Concentration of emission carcinogen PAHs(PAHcarc), such as Benzo(a)anthracene, Benzo(b)f1uoranthene, Benzo(k)f1uoranthene, Benzo(a)pyrene, Dibenzo(a,h)anthracene and Indeno( 1,2,3-cd)pyrene ranged from 0.62 to 1.03 $\mu\textrm{g}$/g. The total amount of PAHs emission from sewage sludge in Korea was calculated as a top-down approach. PAHs and $\Sigma$PAHcarc from sewage treatment plants had emitted to environment by several pathway. The highest amount of emission to the environment was remarked in the ocean dumping(PAHs and $\Sigma$PAHcarc emissions were 1155.95 kg/year and 5040.32 kg/year, respectively).

Removal of Phenol Loaded with Activated Carbon by Potentiostatic Method (정전위전해에 의한 활성탄에 함유된 페놀 제거)

  • 김성우;박승조
    • Resources Recycling
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    • v.10 no.4
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    • pp.18-23
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    • 2001
  • Air pollutants, phenol was generated in case of thermal regeneration of used activated carbon loaded with phenol and because of this problem, removal process of phenol were studied. Electrolytic oxidation of samples, used S.company granular activated carbon (WS-GAC), used C.company granular activated carbon (WC-GAC) and used L.company granular activated carbon (WL-GAC) loaded with phenol carried out by potentiostatic method in this study. In case of experiment was to come into operation in condition of samples containing 100 mg/g phenol, supporting electrolyte was 1.0% sodium chloride solution, Ti-Ir (10$\times$10$\textrm{cm}^2$) electrode and electrode distance was 2 cm, current density was $1.25 A/dm^2$, Obtained from the results of electrolytic oxidation experiments were not detected residual phenol. And then we knew about reaction time of electrolytic oxidation, current density, concentration of supporting electrolyte and electrode and electrode distance were 60 minutes, 1.25 A/dm$^2$, 1.0%, 2 cm.

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A study of Heat & Smoke Extraction Effects by the Various Operation of funnel Fan Shaft Ventilation (터널팬 샤프트 환기 방식에 따른 열 및 연기배출효과에 관한 연구)

  • Rie, Dong-Ho;Yoo, Ji-Oh
    • Fire Science and Engineering
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    • v.18 no.2
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    • pp.49-56
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    • 2004
  • Today's popular ventilation systems include the combined jet fans and electrostatic precipitation systems or the combined jet fans and vertical shaft system. Tunnels with these two ventilation systems applied have been designed and opened, more and more interest has been put in maintenance of a tunnel after opening. Therefore. it is to become more important to come up with the optimal operation mode and the method for the evaluation of ventilation system. In this study, to evaluate a tunnel ventilation and its economy, a dynamic simulation program was developed which can simulate the unsteady-state tunnel air velocity and concentration of pollutants according to the traffic flow variations and operation condition of a ventilation system. We clarified the effectiveness usage on tunnel ventilation by using it and also we could found the most economical ventilation operation mode by application in real exit tunnel. We obtained that combination of fan system and electrostatic precipitation system was more economical than jet fan priority operation mode.

Effect of addition of a catalystic layer on Denitrification System efficiency in a 500 MW Coal-fired Power Plant (500 MW 석탄화력발전소 촉매단추가에 따른 탈질설비 효율에 미치는 영향)

  • Lee, Sang Soo;Moon, Seung-Jae
    • Plant Journal
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    • v.17 no.1
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    • pp.58-66
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    • 2021
  • The government has recently come up with a policy to tighten regulations on air pollutant emissions due to public concerns over the emission of pollutants such as fine dust. The coal-fired power plant is speeding up the improvement of the performance of environmental facilities, and this paper deals with the cases of performance improvement by adding a catalyst to the 500 MW standard coal-fired power DeNox system, and examines the change in the performance factors according to the addition of catalysts and the efficiency of NOx removal. The DeNOx efficiency before and after improvement increased from 80% to 88%, and the conversion rate of SO2/SO3, ammonia slip which are performance factors satisfied the design assurance value, but exceeded the design assurance value for differential pressure. At the same time, the ammonia slip concentration and differential pressure items increased as the NOx removal efficiency increased, resulting in the need for management and improvement.

A Case Study of Expanding the Health Impact Assessment on the Residential Development Projects (주거지 개발계획에 대한 건강영향평가 확대와 사례분석)

  • Kim, Eunchae;Ha, Jongsik;Tak, Jongseok
    • Journal of Environmental Impact Assessment
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    • v.31 no.4
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    • pp.250-264
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    • 2022
  • The development projects subject to health impact assessment (HIA) in the current environmental impact assessment (EIA) system are limited to some projects under Article 12 of the Enforcement Decree of the Environmental Health Act (Additional Assessment Objects Subject to Health Impact Assessment Items), but health impact-related matters are being evaluated and reviewed during consultation. In particular, when a development site is planned around some pollutant sources in a residential development plan, it is evaluated and reviewed whether the site meets the risk criteria through a current concentration survey of major hazardous air pollutants. This study prepared a quantitative method to confirm the validity of the location of the residential area to be developed in the residential development plan and proposed a plan to expand the project subject to HIA within the EIA procedure. A detailed methodology was proposed by reviewing the screening and scoping procedures of the EIA system, and a case analysis of the urban development plan discussed in the past was conducted to verify the methodology.

Distribution characteristics of dioxin concentration in pyrolysis-gasification-melting process facilities (생활폐기물 열분해-가스화-용융공정시설에서 다이옥신의 분포특성)

  • Son, Jihwan;Kim, Kiheon;Kang, Youngyeol;Park, Sunku
    • Analytical Science and Technology
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    • v.20 no.1
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    • pp.10-16
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    • 2007
  • This research was designed to investigate the formations of hazardous air pollutants in the MSWs pyrolysis-gasification-melting process. In this survey, PCDDs/PCDFs (polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofuran) were investigated in the two facilities (A and B facilities). In A facility, the PCDDs/DFs concentrations were 0.88, 2.29, 0.16 ng I-TEQ/$m^3$ respectively on the secondary incinerator, boiler and stack. In B facility, the PCDDs/PCDFs concentrations were 0.22, 0.05 ng I-TEQ/$m^3$ respectively on the pyrolysis-gasification-melting furnace and stack. The concentrations of PCDDs/PCDFs increased due to resynthesis during cooling process in the both facilities. High concentrations of PCDDs/PCDFs isomers were founded as 2, 3, 4, 7, 8-PeCDF, 2, 3, 4, 6, 7, 8-HxCDF and 1, 2, 3, 6, 7, 8-HxCDF orderly in A facility, and 2, 3, 4, 7, 8-PeCDF, 1, 2, 3, 7, 8-PeCDD and 2, 3, 4, 6, 7, 8-HxCDF orderly in B facility.

Evaluation on Air Quality inside Subway Driver Cabin by Monitoring PM, $CO_2$, and CO Levels (서울 일부 지하철 승무원석의 PM, 이산화탄소, 일산화탄소 모니터링에 의한 실내 공기질 특성 평가)

  • Kwag, Hyun-Suk;Jin, Ku-Won;Kim, Won;Yang, Won-Su;Choi, Sang-Jun;Park, Dong-Uk
    • Journal of Environmental Health Sciences
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    • v.31 no.5 s.86
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    • pp.379-386
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    • 2005
  • [ $PM_{10},\;PM_{2.5},\;CO_2\;and\;CO$ ] in driver cabins of subway line from 5 to 8 were monitored from 07:00 through 21:00 (or 19:30 or 20:00) on May. Driver cabin of subway line 7 showed the highest $PM_{10},\;PM_{2.5},\;CO_2\;and\;CO$ concentrations. General Linear Model indicated that subway line, subway location (ground and underground track) and running time (morning and afternoon) significantly influenced the concentrations of $PM_{10},\;PM_{2.5},\;CO_2\;and\;CO$ (p=0.000). Daily profile of $PM_{10},\;PM_{2.5},\;CO_2\;and\;CO$, expressed as an 30 minutes average, showed similar variation pattern over day period. These concentrations showed the highest concentrations between 07:00 and 09:00 of rush hour, slightly dropped and again rose slightly after 18:00. In correlation analysis, significant relations among $PM_{10},\;PM_{2.5},\;CO_2\;and\;CO$ were detected (p<0.01). In particular, correlation coefficient between $PM_{10}\;and\;PM_{2.5}$ was highly significant (r=0.884). Regression analysis also concluded that $PM_{10}$ concentration significantly explained 71.4% of variation of $PM_{2.5}$ concentration (p=0.000, $R^2=0.714$). Correlations by CO with $PM_{10}\;and\;PM_{2.5}$ were 0.451 and 0.520, which were higher than those by $CO_2$. Further study is needed to examine the sources of $PM_{2.5}$ and CO in subway and to compare pollutants concentration among subway lines.