• Title/Summary/Keyword: AgI

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Growth Factors of Hyphal Anastomosis Groups of Rhizoctonia solani Kuhn I. Effects of Temperature, pH, Carbon and Nitrogen Sources (Rhizoctonia solani의 균사융합군별 생장요인 I. 온도, PH, 탄소원 및 질소원의 영향)

  • Kim Hyung Moo
    • Korean Journal Plant Pathology
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    • v.1 no.1
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    • pp.72-78
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    • 1985
  • The effects of temperature. pH, carbon and nitrogen sources on the growth of Rhizoctonia solani were studied by using five hyphal anastomosis groups(four cultural types, 7 isolates) of the fungus. The ranges of optimum temperature were $20^{\circ}C$ in the AG 2-1, AG 2-2 and AG 4, and $25^{\circ}C$ in the AG 1-IA, AG 1-IB, AG 3, AG 5. The optimum pH for the mycelial growth was 6-7 in the fungus. Glucose in the AG 1-lA, AG 1-IB, AG 2-2, AG 3 and AG 5, sucrose in the AG 2-1 and fructose in the AG 4 were the most effective for the mycelial growth, but glycerine, cellulose and lactose were not effectively utilized as nutrients. $Ca(NO_3)_2$ in the AG 1-IA, AG 1-IB and AG 4, asparagine in the AG 2-1, $KNO_3$ in the AG 2-2 and $NaNO_3$ in the AG 5 were the best nitrogen sources for the mycelial growth, but $NH_4NO_3$ was not easily utilized by the fungus. Nitrate and organic nitrogens for the fungal growth were utilized better than ammonium nitrogen.

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Two Crystal Structures of Dehydrated $Ag^+$ and $Rb^+$ Exchanged Zeolite A, $Ag^{12-x}Rb_{x}-A$, x = 2 and 3 ($Ag^+$ 이온과 $Rb^+$ 이온으로 치환된 제올라이트 A ($Ag^{12-x}Rb_{x}-A$, x = 2 및 3) 를 탈수한 결정구조)

  • Yang Kim;Seong Hwan Song;Duk Soo Kim;Young Wook Han;Dong Kyu Park
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.18-24
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    • 1989
  • Two crystal structures of dehydrated $Ag^+$ and $Rb^+$ exchanged zeolite A, stoichiometries of $Ag_{9}Rb_{3}-A$ (a = 12.278(2)${\AA}$) and $Ag_{10}Rb_{2}-A$ (a = 12.286(2)${\AA}$) per unit cell, have been determined by single crystal x-ray diffraction techniques. Their structures were solved and refined in the cubic space group Pm3m at 21(1)$^{\circ}$C. The crystals of $Ag_{10}Rb_{2}-A$ and $Ag_{10}Rb_{2}-A$ were prepared by flow methods using exchanged solution in which mole ratios of AgNO$_3$ and RbNO$_3$ were 1:5 and 1:50, respectively, with the total concentration of 0.05 M. The structures of the dehydrated $Ag_{9}Rb_{3}-A$ and the $Ag_{10}Rb_{2}-A$ were refined to the final error indices, $R_1$ = 0.064 and $R_2$ = 0.060 with 291 reflections, and $R_1$ = 0.063 and $R_2$ = 0.080 with 416 reflections respectively, for which I >3${\sigma}$(I). In both structures, one reduced silver atom per unit cell was found inside the sodalite cavity. It may be present as a hexasilver cluster in 1/6 of the sodalite units or as an isolated Ag atom coordinated to 4 $Ag^+$ ions in each sodalite unit to give $(Ag_5)^{4+}$, symmetry 4 mm. In the structure of dehydrated $Ag_{9}Rb_{3}-A$, 8 $Ag^+$ ions lie on the threefold axis and each is nearly at the center of the 8-rings at the sites of $D_{4h}$ symmetry. In the structure of dehydrated $Ag_{10}Rb_{2}-A$, two crystallographically different eight 6-ring $Ag^+$ ions were found; $7Ag^+$ ions in the (111) planes of their O(3) framework oxygens and one $Ag^+$ ion inside of sodalite cavity. Two crystallographically different 8-ring cations were also found; two $Rb^+$ ions at the centers of the 8-oxygen rings and one $Ag^+$ ion into the large cavity. Both structures indicate that $Rb^+$ ions prefer to occupy the 8-ring sites, while $Ag^+$ ions prefer to occupy the 6-ring sites.

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Two Crystal Structures of Fully Dehydrated $Ag_{12-2x}Co_x-A (x = 3 and 4.5)$ (완전히 탈수한 $Ag_{12-2x}Co_x-A$ (x = 3 및 4.5)의 결정구조)

  • Seung Hwan Song;Duk Soo Kim;Jong Yul Park;Un Sik Kim;Yang Kim
    • Journal of the Korean Chemical Society
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    • v.32 no.6
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    • pp.520-527
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    • 1988
  • The crystal structures of $Co^{2+}\;and\;Ag^+\;exchanged\;zeolite\; A,\; Ag_6Co_3$-A(a = 12.131(5)$\AA$) and $Ag_3Co_{4.5}$-A(a = 12.145(1)$\AA$), have been determined by single crystal X-ray diffraction techniques. Both structures were solved and refined in the cubic space group Pm3m at 21(1)$^{\circ}C$. Full-matrix leastsquares refinement converged to the final error indices of R1 = 0.045 and R2 = 0.041 for $Ag_3Co_{4.5}-A,\; and\; R1 = 0.066\; and\; R2 = 0.076\; for\; Ag_6Co_3$-A using the 258 and 189 reflections, respectively, for which I > 3$\sigma$(I). Both structures indicate that CO(Ⅱ)ions are coordinated by three framework oxygens; the Co(II) to O(3) distances are 2.118(4)$\AA$ for $Ag_3Co_{4.5}$-A and 2.106(1)$\AA$ for $Ag_6Co_3-A$, respectively. In each structure, the angle substended at Co(II), O(3)-Co(II)-O(3) is ca 120°, close to the idealized trigonalplanar value. $Co^{2+}$ ions prefer to 6-ring sites and $Ag^+$ ions prefer to 8-ring site when total number of cations is more than 8. The crystals of hydrated and dehydrated $Ag_{12-2x}Co_x-A (x > 4.5)$ had no crystalline diffraction pattern, indicating the apparent exchange limit of $Co^{2+}\; into\; Ag_{12}-A\; is\; 4.5 Co^{2+}$ ions per unit cell. $Co^{2+}$ ions hydrolyze $H_2O$ molecules and $H_3O^+$ concentraction is accumulating. These $H_3O^+$ ions destroy the zeolite structures.

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Serum HBsAg and Anti-HBs Positive Rate among a City Health Center Visitors (일개 도시 보건소 이용자들의 혈청 HBsAg 및 Anti-HBs 양성률)

  • Shin, Mal-Sook;Hwang, Tae-Yoon;Kim, Chang-Yoon
    • Journal of Preventive Medicine and Public Health
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    • v.30 no.3 s.58
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    • pp.508-517
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    • 1997
  • Hepatitis B virus(HBV) infection is one of the major health problems in Korea and HBsAg positive rate was known to be about $5\sim15%$ in general population. This study was conducted to identify the positive rates of serum HBsAg and anti-HBs among community population regarded as having hish HBV vaccination rate than in previous decade, using EIA(Enzyme immunoassay) method, in Seo-Gu, Taegu, Korea. The study subjects were 1,160 who visited Seo-Gu Health Center for check-up serologic markers of hepatitis 3. The data were obtained from the serologic test for hepatitis markers and questionnaire survey was conducted to obtain the general characteristics, vaccination history, past history of hepatitis and other liver disease, and exposure history to risk factors of hepatitis of the study subjects. The positive rates of HBsAg and anti-HBs were 5.2% and 62.4% respectively. The positive rates of HBsAg for male and female were 6.6% and 4.3% respectively. The age was divided into two groups as group I (less than 15 years old), group II (more than 16 years old) according to the hypothesis that these two groups might be different in HBV vaccination rate. HBV vaccination rates for group I and II were 83.1% and 52.3%. The positive rates of HBsAg for group I and II were 2.6% and 6.5%. The positive rates of HBsAg for the vaccinated people of the group I and II were 2.2% and 3.5%, the positive rates of anti-HBs for the vaccinated people of the group I and II were 70.1% and 71.1% respectively. The most significant factor in positive rate of HBsAg was 'hepatitis carrier in family'. Multiple logistic regression analysis revealed that 'hepatitis history' and 'hepatitis carrier in family' were significant variables for positivity of HBsAg, and 'hepatitis B vaccination' was only a significant variable for positivity of anti-HBs.

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Response of Systemic Fungicides of Rhizoctonia spp. Causing Rhizoctonia Blight on Turfgrass (잔디에 Rhizoctonia 마름병을 유발하는 Rhizoctonia spp.의 침투성 살균제에 대한 반응)

  • Chang, Taehyun;Lee, Seong Jun
    • Weed & Turfgrass Science
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    • v.2 no.4
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    • pp.387-394
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    • 2013
  • The Rhizoctonia blight causing by Rhizoctonia spp. is an important disease of turfgrass, requiring fungicide application to maintain acceptable conditions for turfgrass good qualities in the golf course. The experiment was conducted to determine the mean 50% effective concentration inhibiting mycelial growth ($EC_{50}$) value of to flutolanil, pyraclostrobine and hexaconazole to Rhizoctonia solani AG-1 IB, Rhizoctonia cerealis and Rhizoctonia solani AG2-2IV isolated from Gyeongbuk province of Korea in vitro. Five discriminatory concentrations of each fungicide were used to detect in vitro sensitivity. The mean of $EC_{50}$ values to three systemic fungicides was the lowest isolate of R. solani AG-1 IB. However, the sensitivity of fungicides to Rhizoctonia solani AG2-2IV were higher mean $EC_{50}$ value of 0.026 ${\mu}g\;a.i.\;ml^{-1}$ of pyraclostrobine and 0.044 ${\mu}g\;a.i.\;ml^{-1}$ of flutolanil. R. cerealis was the lowest sensitivity to hexaconazole which was an average $EC_{50}$ value of 0.022 ${\mu}g\;a.i.\;ml^{-1}$. Inhibition of mycelial growth rate (%) by three combine fungicides using the $EC_{50}$ value of each fungicide was the highest R. solani AG2-2IV. Results of this study were may confirmed in vitro response fungicide of three Rhizoctonia species for control of Rhizoctonia blight in the field.

Four Crystal Sturctures of Dehydrated Ag$^+$ and Tl$^+$ Exchanged Zeolite A, Ag$_{12-x}Tl_x$-A, x = 2, 3, 4, and 5

  • Kim, Duk-Soo;Song, Seong-Hwans;Kim, Yang
    • Bulletin of the Korean Chemical Society
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    • v.9 no.5
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    • pp.303-308
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    • 1988
  • Four crystal structures of dehydrated Ag(I) and Tl(I) exchanged zeolite A, $Ag_{12-x}Tl_x$-A, x = 2, 3, 4, and 5, have been determined by single-crystal x-ray diffraction techniques. Their structures were solved and refined in the cubic space group Pm3m at $21(1)^{\circ}C$. All crystals were ion exchanged in flowing streams of mixed $AgNO_3\;and\;TlNO_3$ aqueous solution, followed by dehydration at $350^{\circ}C$ and $2{\times}10^{-6}$ Torr for 2 days. In all of these structures, one-sixth of the sodalite units contain octahedral hexasilver clusters at their centers and eight $Ag^+$ ions are found on threefold axes, each nearly at the center of a 6-oxygen ring. The hexasilver cluster is stabilized by coordination to eight $Ag^+$ ions. The Ag-Ag distance in the cluster, ca. 2.92 ${\AA}$, is near the 2.89 ${\AA}$ bond length in silver metal. The remaining five-sixths of the sodalite units are empty of silver species. The first three $Tl^+$ ions per unit cell preferentially associate with 8-oxygen rings, and additional $Tl^+$ ions, if present, are found on threefold axes in the large cavity.

Expression of Hepatitis B Viral Core Antigen Gene in Excherichia coli (대장균에서 한국형 B형 간염바이러스 내면항원 유전자의 발현)

  • 최수근;이원상;김성기;노현모
    • Korean Journal of Microbiology
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    • v.29 no.2
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    • pp.80-84
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    • 1991
  • We cloned and expressed hepatitis B viral core antigen (HBcAg) gene in E. coli using $P_{L}$ promoter system. For optimal expression of the gene, we undertook the studies on the effects of the distance between Shine-Dalgarno (SD) sequence and start codon, copy number of repressor gene, induction temperature, and the stability of the core antigen. The results demonstrated that the induction at 37.deg.C was more efficient than at 42.deg.C, and the 11 base pairs (bp) distance between SD sequence and start codon of HBcAg gene was more efficient than the 15 bp distance in E. coli. The copy number of cI857 repressor gene did not influence on the expression of HBcAg, and the expression level of HBcAg in mutant type (low protease activity) and wild type strains was almost the same. The produced core antigen appeared to be HBcAg not HBeAg judged by two different radioimmunoassat (RIA) kits. This result suggested that the antigen was stable in E. coli.i.

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Flotation-Spectrophotometric Determination of Ag(I) at the 10-7 mol L-1 Level Using Iodide and Ferroin as an Ion-associate

  • Hosseini, Mohammad Saeid;Hashemi-Moghaddam, Hamid
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1529-1532
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    • 2005
  • A simple and cost effective method for separation and preconcentration of Ag(I) at the $10^{-7}\;mol\;L^{-1}$ level in the environmental and mineral samples is present. The method is based on the flotation of Ag(I)-iodide complex as an ion-associate with ferroin in pH of 4 from a large volume of an aqueous solution (500 mL) using nheptane. The floated layer was then dissolved in dimethylsulfoxide (DMSO) for the subsequent spectrophotometric determination. Beer's law was obeyed over a range of 2.0 ${\times}$ $10^{-7}$-4.0 ${\times}$ $10^{-6}$ mol $L^{-1}$ with the apparent molar absorptivity of 2.67 ${\times}$ $10^5$ L $mol^{-1}\;cm^{-1}$. The detection limit (n = 5) was 4 ${\times}$ $10^{-8}$ mol $L^{-1}$, and RSD (n = 5) obtained for 2.0 ${\times}$ $10^{-6}$ mol $L^{-1}$ of Ag(I) was 2.2%. The interference effects of a number of elements was studied and found that only $Hg^{2+}$ at low concentration, and $Pb^{2+}$, $Cd^{2+}$, $Cu^{2+}$, and $Fe^{3+}$ ions at moderately high concentrations were interfered. To overcome on these interference effects, the solution was treated with EDTA at a buffering pH of 4 and passed through a column containing Amberlite IR-120 ionexchanger resin, just before the flotation process. The proposed method was applied to determine of Ag(I) in a synthetic waste water, a photographic washing sample and a geological sample and the results was compared with those obtained from the flame atomic absorption spectrometry. The results were satisfactorily comparable with together, so that the applicability of the proposed method was confirmed in encountering with the real samples.

Effect of transverse compressive stress on $I_{c}$ degradation characteristics in Bi-2223 superconducting tapes (Bi-2223 초전도테이프의 임계전류 열화특성에 미치는 횡방향 압축응력의 영향)

  • 신형섭;김병수;오상수;하동우;하홍수
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.02a
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    • pp.101-104
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    • 2003
  • Influences of transverse compressive stress on the critical current ( $I_{c}$) in AgMg and AgMn alloy sheathed Bi-2223 tapes were investigated at 77 K and 0 T. The $I_{c}$ degradation behavior depending on sample specifications was discussed in viewpoints of n-value and damage morphology. As a result, Bi-2223 tapes showed a significant drop in $I_{c}$ for stresses greater than 50MPa. The AgMg sheathed Bi-2223 tapes representing higher $I_{c}$ showed a lower $\sigma$$_{irr}$ and a significant $I_{c}$ degradation with increase in compressive stress. There existed a voltage tap separation dependency of the $I_{c}$ degradation behavior caused by the transverse compressive stress.sive stress.s.

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Enhancement of n-i-p flexible microcrystalline silicon thin film solar cell efficiency through improved light trapping (Light trapping 개선을 통한 n-i-p 플렉서블 미세결정질 실리콘 박막 태양전지의 효율 향상)

  • Jang, Eunseok;Baek, Sanghun;Lee, Jeong Chul;Park, Sang Hyun;Song, Jinsoo;Rhee, Young Woo;Cho, Jun-Sik
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.58.1-58.1
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    • 2010
  • Stainless Steel의 유연한 기판을 사용하여 ZnO:Al/Ag의 후면전극에서 Ag 증착 실험조건 변화를 통해서 light trapping을 개선한 n-i-p 구조의 플렉서블 미세결정질 실리콘 박막 태양전지를 제작하였다. 실험 방법으로 마그네트론 스퍼터를 사용하여 Stainless Steel 기판 위에 ZnO:Al/Ag를 증착하여 후면전극으로 사용되는 back reflector를 제작하였으며 그 위에 미세결정질 실리콘 박막을 증착하였다. Back reflector에서 Ag 박막의 증착 온도가 증가할수록 표면결정 성장으로 roughness가 증가하여 반사도를 증가하였다. 또한, Ag 박막 증착 두께와 압력 변화에 따른 광학적 특성변화를 Atomic Force Microscope(AFM), Scanning Electron Microscopy(SEM),UV-visible-nIR spectrometry로 조사하여 최적의 조건을 찾았으며 개선된 back reflector의 특성이 n-i-p 구조의 플렉서블 미세결정질 실리콘 박막 태양전지에 적용하여 light trapping의 증가가 태양전지에서 광학적인 특성 변화 및 효율 향상에 영향을 주는지 Photo IV와 EQE(External Quantum Efficiency)를 통하여 조사하였다.

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