• 대한원격탐사학회지
• /
• 제22권6호
• /
• pp.495-505
• /
• 2006

에어로졸 종류별 구분을 위하여, 2005년 한해 동안 동북아시아지역을 대상으로 MODIS 에어로졸 자료인 에어로졸 광학두께(AOT)와 미세입자 비율(FF)을 분석하였다. 동북아시아 (북위 $20\sim50$도, 동경 $110\simt50$도)의 해양에서 관측된 에어로졸 자료를 이용하였다. AOT와 FF의 상호관계를 이용하면 주요 3가지 대기 오염 에어로졸인 먼지 입자, 해염입자, 오염 입자를 구분할 수 있다. 먼지 입자의 경우 주로 높은 AOT (>0.3)와 낮은 FF(<0.65)의 특징으로 봄철 빈번히 발생한다. 2005년 봄철 평균 AOT에 대한 먼지 입자의 기여도가 24.0%로 다른 계절보다 큼을 알 수 있다. 주로 인위적으로 발생하는 오염입자의 경우 높은 FF(>0.65)와 넓은 AOT범위에서 관측되었다. 여름철 오염입자의 평균 AOT는 $0.31{\pm}0.05$이고 전체 AOT에 대한 기여도는 79.8%로 여름철 오염 입자에 의한 영향이 큼을 알 수 있었다. 해염입자의 특징으로는 대부분의 AOT가 0.1이하로 낮은 AOT(<0.3)값이 나타났으며 FF의 경우 먼지입자보다는 크고 오염입자보다는 낮은 범위의 값이 주로 나타났다. 계절적으로 봄철$(0.33{\pm}0.11)$에 가장 높은 AOT값이 나타났으며(FF; $0.66{\pm}0.21$), 가을철 가장 낮은 AOT$(0.19{\pm}0.05)$값이 나타낫다(FF; $0.60{\pm}0.14$). 공간분포 특징으로는 중국연안으로 갈수록 높아지는 AOT특징이 나타났고, 이는 편서풍대에 속하는 관측지역의 지형학적인 특징으로 인해 중국대륙의 공단지역에서 발생한 에어로졸의 이동 때문인 것으로 여겨진다.증권업자의 중개활동으로 간주되어야 한다. 채권 ETS의 중개 규모가 일정 수준을 넘어설 경우 거래소에 준하는 보고, 공시 및 감시 요건이 부과되는 것이 바람직하다. 다섯째, 채권시장의 효율성을 강화하기 위해서 채권 ETS에 대해서 적용되는 투명성 강화, 시장분할 방지, 공정거래 등에 대한 규제는 거래 대상의 특성에 따라서 탄력적으로 조정될 수 있어야 한다.\pm}8.93ppm,\;20.19{\pm}0.97ppm,\;15.19{\pm}1.66ppm,\;21.20{\pm}1.88ppm,\;15.71{\pm}0.91ppm,\;55.48{\pm}2.42ppm,\;52.12{\pm}2.44ppm,\;23.80{\pm}1.98ppm$ 그리고 $11.14{\pm}0.51ppm$인 것으로 나타났다(비타민 C의 $SC_{50}$ 값:$9.61{\pm}0.93ppm$). 특히 마테 추출물과 솔잎 추출물은 총 페놀 함량이 높으면서 DPPH 라디칼과 superoxide anion 라디칼을 동시에 효율적으로 포착하는 효능을 지니고 있는 것으로 나타났다. 결론적으로 마테와 솔잎의 상업적인 추출물은 기능성 항산화제로서 유용한 소재로 사용 가능 할 것으로 사료된다.트폴리오보다 약 5배정도의 높은 1개월 평균초과수익률을 실현하였고, 반전거래전략의 유용성을 충분히 발휘하기 위하여 장단기의 투자기간을 설정할 경우에 6개월에서 36개월로 이동함에 따라 6개월부터 24개월까지는 초과수익률이 상승하지만, 이후로는 감소하므로, 반전거래전략을 활용하는 경우 주식투자기간은 24개월이하의 중단기가 적합함을 발견하였다. 이상의 행태적 측면과 투자성과측면의 실증결과를 통하여 한국주식시장에 있어서 시장수익률을 평균적으로 초과할 수 있는 거래전략은 존재하므로 이러한 전략을 개발 및 활용할

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
• /
• pp.61-68
• /
• 1997

The morphology and size distribution of chromium oxides and the concentration measurement of atomic arsenic have been studied in laminar diffusion flames. Nitrogen was added to vary flame temperatures in hydrogen flames. Ethene flames were used in order to investigate the potential for interaction between the soot aerosol that is formed in these flames and the chromium aerosol. Two sources of chromium compounds were introduced: chromium nitrate and chromium hexacarbonyl. A detailed investigation of the morphology was carried out by scanning electron microscopy (SEM). The amounts of Cr(VI) and total Cr were determined by a spectrophotometric method and by X-ray fluorescence spectrometry, respectively. Also, LIF was used for the measurement of atomic arsenic, which was excited at 197.2 nm and was detected at 249.6 nm. Results showed that the morphology of the particles varied with the flame temperature and with the chromium source. The particles were characterized by porous structures, cenospheres and agglomerated dense particles when chromium nitrate solution was added to the flames. At low to moderate temperatures, porous sintered cenospheric structures were formed, in some cases with a blow hole. At higher temperatures, an agglomerated cluster which was composed of loosely sintered submicron particles was observed. It was also found that the emission of Cr(VI) from the undiluted $H_2$ flame was more than 10 times larger than in the 50% $H_2$ / 50% $N_2$ flame on a mass basis. Single point LIF measurement of atomic arsenic indicated that arsenic exist only in the low temperature, fuel rich region.

• 한국대기환경학회지
• /
• 제12권2호
• /
• pp.167-177
• /
• 1996

To investigate the source-receptor relationships aerosol model has been used to simulate the distribution behavior of the yellow sand. Data for meteorological fields were obtained by Meso-scale Analysis and Prediction Model System/Seoul National University (MAPMS/SNU) for five days (10-14 April 1988). To obtain the distributions of concentration of yellow sand,the aerosol model has been modified to allow quantifications of relative concentration distributions of yellow sand. Source regions of yellow sand were delineated by soil maps of China and emission rate as a function of wind stress(Westphal et al., 1987). Using 3-dimensional wind fields the backward trajectories from 3 receptor grids at the layer of .sigma. =0.95, 0.9, 0.85, 0.8 were calculated. In order to facilitate quantitative assessment of source-receptor relationships, it was assumed that the perturbations in along-trajectory and cross-trajectory proceed linearly with time, in accord with Gaussian distribution characteristics. On the basis of this assumption, the probability fields were calculated from every grid point with source strength 1. Using these probability fields and emission retes, the potential contributions of upstream sources along the trajectories were estimated. The results of this study indicate that the application of trajectory modeling is useful in investigating the quantitative relationship between source and receptor regions.

• 한국대기환경학회지
• /
• 제29권2호
• /
• pp.152-162
• /
• 2013

The physico-chemical characteristics and nanostructure of the aerosol samples from a coal-fired power plant, a charcoal kiln and diesel vehicles were investigated with focusing on black carbon (BC). Aerosols from the coal-fired power plant were mostly comprised of mineral ash spheres which are heterogeneously mixed. The main components of the aerosols from coal-fired power plant were calcium compounds, iron oxide, alumino-silicate without BC. The typical combustion-generated BC which shows the shape of bunch of grapes with 20~50 nm particles which were detected in aerosol particles from diesel vehicles. The nanostructure of each BC particle shows the shape of concentric circles which is comprised of closely-packed graphene layers. Aerosols from charcoal kiln were likely condensed organic carbon generated from the low-temperature combustion process.

• 한국대기환경학회지
• /
• 제15권5호
• /
• pp.575-586
• /
• 1999

The size-resolved number concentrations of aerosols ranging from 0.3 to 25 $mu extrm{m}$ were observed in Seoul and Anmyondo in the west coast of Korea during an Yellow Sand phenomenon in April 1998. Number size distributions of aerosols observed in both places are characterized by decrease in small particles of diameter less than 1${\mu}{\textrm}{m}$ and increase in large size between 1.35 and 10${\mu}{\textrm}{m}$ in heavy dust period. For particles in this size range, there was a good correlation between number concentrations observed in both places during the Yellow Sand episode. On the other hand, the number of small particles less than 0.82${\mu}{\textrm}{m}$ decreased, but the correlation between these particles in both places was enhanced during more intense dust period. The number of coarse particle larger than 10 ${\mu}{\textrm}{m}$ showed a distince diurnal variation without a significant change in amplitude, which was more visible in Seoul. It suggests that these coarse particles were more affected by local sources. Form these results, it was range of 1~10${\mu}{\textrm}{m}$ originated possibly from the dust source regions and the source signature depended on the degree of dust intensity.

• 한국환경과학회지
• /
• 제19권7호
• /
• pp.799-806
• /
• 2010

In an effort to characterize temporal and spatial variability of $PM_{10}$ and to quantitatively estimate contribution of sea salt aerosol to $PM_{10}$ mass in Busan area, twenty four-hour averaged concentration of $PM_{10}$ were measured in two distinct areas, Gwaebeopdong(inland) and Dongsamdong(seashore), Busan for summer and fall, 2007. It was found that sea salt accounted for 2.9% and 9.5% of $PM_{10}$ mass in Gwaebeopdong and Dongsamdong, respectively for the study period, indicating that contribution of sea salt to $PM_{10}$ mass and total ion concentration in seashore area were consistently higher by a factor of three compared to inland area. Temporal analysis suggested that sea salt contributions to $PM_{10}$ in Dongsamdong were higher in summer due to the southerly sea breeze while there was no significant fluctuation of sea salt contribution for the summer and fall months in Gwaebeopdong. Sea salt enrichment factors($EF_{sea}$) of $K^+$ $Ca^{2+}$ and ${SO_4}^{2-}$ (>10) indicated major contributions from anthropogenic sources and EFs of $Mg^{2+}$ and $Cl^-$ exhibited strong association with oceanic origins for both areas.

• 한국입자에어로졸학회지
• /
• 제7권1호
• /
• pp.31-44
• /
• 2011

The hourly volatile organic compounds(VOCs) concentrations between 2005 and 2008 at Bulgwang photochemical assessment monitoring station were investigated to establish a method for quality assurance and quality control(QA/QC) procedure. Systematic error, erratic error, and random error, which was manifested by outlier and highly fluctuated data, were checked and removed. About 17.3% of the raw data were excluded according to the proposed QA/QC procedure. After QA/QC, relative standard deviation for representing 15 species concentrations decreased from 94.7-548.0% to 63.4-125.8%, implying the QA/QC procedure is proper. For further evaluation about the adequacy of QA/QC procedure, principal components analysis(PCA) was carried out. When the data after QA/QC procedure was used for PCA, the extracted principal components were different from the result from the raw data and could logically explain the major emission sources(gasoline vapor, vehicle exhaust, and solvent usage). The QA/QC procedure based on the concept of errors is inferred to proper to be applied on VOCs. However, an additional QA/QC step considering the relationship between species in the atmosphere needs to be further considered.

• 한국입자에어로졸학회지
• /
• 제15권2호
• /
• pp.57-65
• /
• 2019

Recently, there has been much research on the effect of fine dust on human body with increasing interest in the fine dust. Thermal power plant, which is considered as one of the main sources of fine dust, is reported to be responsible for 14% of the total amount of domestic fine dust in the Republic of Korea. Therefore, dust collecting devices in the thermal power plant need to be improved. In this study, the electrostatic precipitator (ESP) was considered to substitute for a mist eliminator used in flue gas desulfurization facility. By considering real situation in the flue gas desulfurization facility, the collection efficiency of the ESP was evaluated by using the sprayed limestone slurry particles. The collection efficiency of the ESP was higher than that of the mist eliminator, showing the possibility of replacing the mist eliminator with the ESP in flue gas desulfurization facility.

• 한국입자에어로졸학회지
• /
• 제20권1호
• /
• pp.13-24
• /
• 2024

The concentrations of polycyclic aromatic hydrocarbons (PAHs) and elemental carbon (EC) in particulate matter, typical primary aerosols have decreased in Seoul between 2003 and 2018 (80% for PAHs and 85% for EC). The yearly mean benzo[a]pyrene (BaP) concentration has been lower than 1 ng/m3 since 2010-2011, the target value set by the European Union (EU) and China. A series of policies related to solid fuel and vehicle in South Korea and China should be effective in the reduction of the ambient PAHs and EC concentrations. But the emission data of PAHs and EC at both countries did not support that hypothesis. Possible causes are uncertainties in the emission inventories of primary carbonaceous aerosols in South Korea and China, although there may be a minor effect of the emissions from North Korea on the concentrations in Seoul. Thus the further policy directions against PAHs and EC such as improvements of emissions inventories and measurements, intensive regulation of non-road mobile sources and control of PAHs derivatives are discussed.

• 한국대기환경학회지
• /
• 제14권2호
• /
• pp.143-152
• /
• 1998

The aerosol concentrations of ionic components were measured on a daily basis from a coastal monitoring site located at Kosan, Cheju Island from 26 September to 5 October 1997 as a field-intensive for a LRTAP project The chemical species we investigated include most of important inorganic species (i.e., Cl-, NO3-, F-, SO42-, Na+, NH4+, and K+) and some organic species (i.e. formats, acetate, and methanesulfonate (MSA) ions). The concentration data of those important inorganic and organic species obtained during this study were evaluated to properly address their chemical and physical characteristics. Most of major inorganic components including sulfate, sodium, chloride, and potassium ions exhibited very conservative relationships with each other such that the concentration ratios of any pair are quite analogous to that of seawater ratio. Since the oceans serve as the major sources of ionic constituents, their concentration changes appear to be senstively reflected by the factors affecting air-sea processes such as an increase in wind speed or changes in wind direction. A comparative analysis of sulfur-containing species such as seasalt (SS) and nonseasalt (NSS) sulfate and MSA were also made to assess the factors influencing the S cycling. An evaluation of NSS/SS ratios suggests that most of sulfate be associated with NSS fraction rather than 55 one. The finding of lower MSA/NSS-SO42- ratio along with a line of physical evidence such as intrusion of anthropogenically affected air mass suggests that the oxidation of S species have been promoted under the conditions encountered during the study period. Finally, the concentration data of carboxylic species (such as formats and acetate ions) were also analyzed. Although the existence of temporal trends were difficult to assess, these data indicate that their contribution to the precipitation acidity may not be significant enough.