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Characterization of Sea Salt in PM10 at Inland and Seashore in Busan, Korea

  • Jeon, Byung-Il (Department of Environmental Engineering, Silla University)
  • Received : 2010.03.29
  • Accepted : 2010.05.23
  • Published : 2010.07.31

Abstract

In an effort to characterize temporal and spatial variability of $PM_{10}$ and to quantitatively estimate contribution of sea salt aerosol to $PM_{10}$ mass in Busan area, twenty four-hour averaged concentration of $PM_{10}$ were measured in two distinct areas, Gwaebeopdong(inland) and Dongsamdong(seashore), Busan for summer and fall, 2007. It was found that sea salt accounted for 2.9% and 9.5% of $PM_{10}$ mass in Gwaebeopdong and Dongsamdong, respectively for the study period, indicating that contribution of sea salt to $PM_{10}$ mass and total ion concentration in seashore area were consistently higher by a factor of three compared to inland area. Temporal analysis suggested that sea salt contributions to $PM_{10}$ in Dongsamdong were higher in summer due to the southerly sea breeze while there was no significant fluctuation of sea salt contribution for the summer and fall months in Gwaebeopdong. Sea salt enrichment factors($EF_{sea}$) of $K^+$ $Ca^{2+}$ and ${SO_4}^{2-}$ (>10) indicated major contributions from anthropogenic sources and EFs of $Mg^{2+}$ and $Cl^-$ exhibited strong association with oceanic origins for both areas.

Keywords

References

  1. Air Pollution Research Association, 2000, Air pollutant analysis procedure standard, Dong Hwa Press Inc. 514.
  2. Baldauf, R. W., Lane, D. D., Marotz, G. A., Wiener, R. W., 2001, Performance evaluation of the portable MiniVol particulate matter sampler, Atmos. Environ., 35, 6087-6091. https://doi.org/10.1016/S1352-2310(01)00403-4
  3. Bogo, H., Otero, M., Castro, P., Ozafrán, M. J., Kreiner, A., Calvo, E. J., Negri, R. M., 2003, Study of atmospheric particulate matter in Buenos Aires city, Atmos. Environ., 37, 1135-1147. https://doi.org/10.1016/S1352-2310(02)00977-9
  4. Butler, J. D., 1979, Air Pollution Chemistry, Academic Press.
  5. Christian, E. J., 1963, Air chemistry and radioactivity, Academic Press.
  6. Chun, M. Y., Lee, Y. J., Kim, H. K., 1994, Concentration of particulate nitrate originated from sea salt in Seoul ambient air, Korean Society for Atmos. Environ., 10, 191-196.
  7. Green, W. D., 1972, Maritime and mixed maritime continental aerosols along the coast of Southern California, Journal of Geophysical Research, 77, 5152-5160. https://doi.org/10.1029/JC077i027p05152
  8. Guo, Z. G., Feng, J. L., Fang, M., Chen, H. Y., Lau, K.H., 2004, The elemental and organic characteristics of PM2.5 in Asian dust episodes in Qingdao, China, 2002, Atmos. Environ., 38, 909-919. https://doi.org/10.1016/j.atmosenv.2003.10.034
  9. Jeon, B. I., 2003, Characteristics of spatio-temporal variation for PM10 Concentration in Busan, Korean Environmental Science Society, 12, 1033-1041. https://doi.org/10.5322/JES.2003.12.10.1033
  10. Jeon, B. I., Hwang, Y. S., 2007, Study on characteristics of fine particle(PM10) concentration in Busan for five years, Environmental Impact Assessment, 16, 533-542.
  11. Kang, B. W., 1988, A study on the sea salt particles burden to aerosols in Seoul area, Master Thesis in Konkuk University.
  12. Kaya, G., Tuncel, G., 1997, Trace element and major ion composition of wet and dry deposition in Ankara, Turkey, Atmos. Environ., 31, 3985-3998. https://doi.org/10.1016/S1352-2310(97)00221-5
  13. Kim, J. H., Lim, S. H., Oh, C. H., 1994, An experimental study on the corrosion of steel in concrete near the seaside, Architectural Institute of Korea, 64, 165-171.
  14. Kim, K. H., Mishra, V. K., Kang, C. H., Choi, K. C., Kim, Y. J., Kim, D. S., 2006, The ionic compositions of fine and coarse particle fractions in the two urban areas of Korea, Journal of Environ. Manage., 78, 170-182. https://doi.org/10.1016/j.jenvman.2005.04.015
  15. Kim, K. Y., 2006, The distribution of atmospheric sea-salt concentration in Jeju Island, Master Thesis in Cheju National University.
  16. Kim, Y. P., 2000, A Modeling study on aerosol property changes due to sea-salts, Korean Society for Atmos. Environ., 16, 113-120.
  17. Lee, K. H., Ho, C. K., 1999, A study on chemical composition of dustfall sampled in Cheju Area : 2. Identification of source, Korean Society for Atmos. Environ., 15, 101-111.
  18. Mason, B., 1966, Principle of Chemistry, 3rd ed., Wiley, New York, 21-24.
  19. Mats E. R., Gustafsson, L. G., 2000, Inland transport of marine aerosols in southern Sweden, Atmos. Environ., 34, 313-325. https://doi.org/10.1016/S1352-2310(99)00198-3
  20. Ministry of Environmental, 2008, White paper on the environment.
  21. Moon, S. T., 1992, A study on the contribution of sea salt particles to suspended particulate matter, Master Thesis in Konkuk University, 52.
  22. Murphy, D. M., Anderson, J. R., Quinn, P. K., Mclnnes, L. M., Brechtel, F. J., Kreidenweis, S. M., Middlebrook, A. M., Posfai, M., Thomson, D. S., Buseck, P. R., 1998, Influence of sea-salt on aerosol radiative properties in the Southern Ocean marine boundary layer. Nature, 392, 62-65. https://doi.org/10.1038/32138
  23. O'Dowd, C. D., Smith, M. H., Consterdine, I. E., Lowe, J. A., 1997, Marine aerosol, sea-salt, and the marine sulphur cycle: a short review, Atmos. Environ., 31, 73-80. https://doi.org/10.1016/S1352-2310(96)00106-9
  24. Peter, W., 1988, Chemistry of the natural atmosphere, Academic Press. Inc.
  25. Tombach, I., Brewer, P., 2005, Natural background visibility and regional haze goals in the southeastern United States, Journal of the Air and Waste Management Association, 55, 1600-1620. https://doi.org/10.1080/10473289.2005.10464771
  26. US EPA, 2005, Review of the national ambient air standard for particulate matter: policy assessment of scientific and technical information, EPA-452/R-05-005a.
  27. Wai, K. M., Tanner, P. A., 2004, Wind-dependent sea salt aerosol in a Western Pacific coastal area, Atmos. Environ., 38, 1167-1171. https://doi.org/10.1016/j.atmosenv.2003.11.007
  28. Willison, M, J., Clarke, A. G., Zeki, E. M., 1989, Chloride aerosols in central northern England, Atmos. Environ., 23, 2231-2239. https://doi.org/10.1016/0004-6981(89)90185-6
  29. Zhang, D., Iwasaka, Y., 1999, Nitrate and sulfate in individual Asian dust-storm particles in Beijing, China in Spring of 1995 and 1996, Atmos. Environ., 33, 3213-3223. https://doi.org/10.1016/S1352-2310(99)00116-8
  30. Zhao, W., Hopke, P. K., 2004, Source appointment for ambient particles in the San Gorgonio wilderness, Atmos. Environ., 38, 5901-5910. https://doi.org/10.1016/j.atmosenv.2004.07.011