• Title/Summary/Keyword: Advanced composite materials

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The Strength of Sintered Body with the Composition and the Forming Process of LTCC Materials (LTCC 소재의 조성과 성형 공정에 따른 소결체의 강도 특성)

  • Gu, Sin Il;Shin, Hyo Soon;Yeo, Dong Hun;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.1
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    • pp.27-32
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    • 2013
  • According to the composition of LTCC material, though it was thought that bulk defect which was made in forming process effects on the densification during the sintering, it was not reported systemically. In this study, we evaluated crystal structure, 3 point bending strength, hardness and microstructure of the samples by uniaxial pressing and tape casting using the commercial powders of the crystallizing glass and the glass/ceramic composite. In the case of glass/ceramic composite, Viox-001 powder with residual glass in the sintering, 3 point bending strength was similar regardless of forming process due to fill the bulk defect by residual glass. In the case of crystallizing glass, MLS-22, because glass phase was small in the sintering, glass did not fill the pore in the sample by uniaxial pressing process, therefore, the 3 point bending strength of it was 167 MPa. However, the 3 point bending strength of the sample by tape casting was 352 MPa and much higher. Meanwhile, crystal structure and hardness were similar regardless of forming process.

Cure Kinetics and Thermal Properties of Epoxy Resin Initiated by Methylanilinium Salts as a Latent Cationic Curing Agent (잠재성 양이온 경화제로서 methylanilinium 염에 의해 개시된 에폭시 수지의 경화 동력학 및 열적 특성)

  • 김택진;박수진;이재락
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.11a
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    • pp.34-37
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    • 2000
  • The effect of novel N-crotyl-N,N-dimethyl-4-methylanilinium hexafluroantimonate (CMH) curing agent on cure behavior and thermal properties of DGEBA epoxy cationic system was investigated. From DSC measurements of DGEBA/CMH system, it was shown that this system exhibits an excellent thermal latent characteristic in a given temperature and reveals complex cure behavior as indicated by multiple exotherms. The conversion and conversion rate of DGEBA/CMH system increased with increasing the concentration of initiator due to high activity of CMH. Viscoelastic properties during gel formation of DGEBA with CMH were investigated by rheological techniques under isothermal condition. The gel time obtained from the modulus crossover. point t(G')=G", was affected by high curing temperature and concentration of CMH, resulting in high degree of network formation in cationic polymerization. The thermal stabilities were discussed in terms of the activation energy for decomposition and thermal factors determined from TGA measurements.ents.

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Microfracture Behavior of Metallic-Continuous-Fiber-Reinforced Amorphous Matrix Composites Fabricated by Liquid Pressing Process (액상가압공정으로 제조된 금속 연속섬유강화 비정질 복합재료의 미세파괴거동)

  • Lee, Kyuhong;Lee, Sang-Bok;Lee, Sang-Kwan;Lee, Sunghak
    • Korean Journal of Metals and Materials
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    • v.46 no.8
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    • pp.524-537
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    • 2008
  • Zr-based amorphous alloy matrix composites reinforced with metallic continuous fibers were fabricated by liquid pressing process, and their fracture properties were investigated by directly observing microfracture process using an in situ loading stage installed inside a scanning electron microscope chamber. About 60 vol.% of metallic fibers were homogeneously distributed inside the amorphous matrix. Apparent fracture toughness of the stainless-steel- and tungsten-fiber-reinforced composites was lower than that of monolithic amorphous alloy, while that of the Ta-fiber-reinforced composite was higher. According to the microfracture observation, shear bands or cracks were initiated at the amorphous matrix, and the propagation of the initiated shear bands or cracks was effectively blocked by fibers, thereby resulting in stable crack growth which could be confirmed by the fracture resistance curve (R-curve) behavior. This increase in fracture resistance with increasing crack length improved fracture properties of the fiber-reinforced composites, and could be explained by mechanisms of formation of multiple shear bands or multiple cracks at the amorphous matrix and blocking of crack or shear band propagation and multiple necking at metallic fibers.

Effect of Boron Nitride on Mechanical Properties, Thermal and Electrical Conductivities of Carbon Fiber Reinforced Plastics (탄소섬유강화 복합소재의 열적, 전기적, 기계적 특성에 대한 질화붕소 첨가제의 효과)

  • Hong, Hyunkee;Bae, Kwak Jin;Yu, Jaesang
    • Composites Research
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    • v.33 no.3
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    • pp.153-160
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    • 2020
  • In this paper, hexagonal boron nitride (h-BN) particles were added between the sheets of prepreg, and the effect of on many properties of BN-embedded carbon fiber reinforced plastics was investigated. The amount of BN particles which corresponds with 0 to 15 wt% of total resin weight was used as an additive material. The tensile strength and the inter-laminar shear strength of BN-embedded CFRP samples were improved by maximally 13.6%, and 6.7%, respectively. The tendency changes of thermal, electrical conductivities and the morphology of cross-section of CFRPs were also observed. This study suggests the possibility of controlling the characteristics of carbon fiber-BN-epoxy composites to use for aerospace applications.

Advanced 'green' composites

  • Netravali, Anil N.;Huang, Xiaosong;Mizuta, Kazuhiro
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.269-282
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    • 2007
  • Fully biodegradable high strength composites or 'advanced green composites' were fabricated using yearly renewable soy protein based resins and high strength liquid crystalline cellulose fibers. For comparison, E-glass and aramid ($Kevlar^{(R)}$) fiber reinforced composites were also prepared using the same modified soy protein resins. The modification of soy protein included forming an interpenetrating network-like (IPN-like) resin with mechanical properties comparable to commonly used epoxy resins. The IPN-like soy protein based resin was further reinforced using nano-clay and microfibrillated cellulose. Fiber/resin interfacial shear strength was characterized using microbond method. Tensile and flexural properties of the composites were characterized as per ASTM standards. A comparison of the tensile and flexural properties of the high strength composites made using the three fibers is presented. The results suggest that these green composites have excellent mechanical properties and can be considered for use in primary structural applications. Although significant additional research is needed in this area, it is clear that advanced green composites will some day replace today's advanced composites made using petroleum based fibers and resins. At the end of their life, the fully sustainable 'advanced green composites' can be easily disposed of or composted without harming the environment, in fact, helping it.

A Study on the Prediction of Warpage During the Compression Molding of Glass Fiber-polypropylene Composites (유리섬유-폴리프로필렌 복합재료의 압축 공정 중 뒤틀림 예측에 관한 연구)

  • Gyuhyeong Kim;Donghyuk Cho;Juwon Lee;Sangdeok Kim;Cheolmin Shin;Jeong Whan Yoon
    • Transactions of Materials Processing
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    • v.32 no.6
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    • pp.367-375
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    • 2023
  • Composite materials, known for their excellent mechanical properties and lightweight characteristics, are applied in various engineering fields. Recently, efforts have been made to develop an automotive battery protection panel using a plain-woven composite composed of glass fiber and polypropylene to reduce the weight of automobiles. However, excessive warpage occurs during the GF/PP compression molding process, which makes car assembly challenging. This study aims to develop a model that predicts the warpage during the compression molding process. Obtaining out-of-plane properties such as elastic or shear modulus, essential for predicting warpages, is tricky. Existing mechanical methods also have limitations in calculating these properties for woven composite materials. To address this issue, finite element analysis is conducted using representative volume elements (RVE) for woven composite materials. A warpage prediction model is developed based on the estimated physical properties of GF/PP composite materials obtained through representative volume elements. This model is expected to be used for reducing warpages in the compression molding process.