• Title/Summary/Keyword: Addition-Elimination

Search Result 330, Processing Time 0.021 seconds

An ab initio Study on the Molecular Elimination Reactions of Methacrylonitrile

  • Oh, Chang-Young;Park, Tae-Jun;Kim, Hong-Lae
    • Bulletin of the Korean Chemical Society
    • /
    • v.26 no.8
    • /
    • pp.1177-1184
    • /
    • 2005
  • Ab initio quantum chemical molecular orbital calculations have been performed for the unimolecular decomposition of methacrylonitrile ($CH_3C(CN)=CH_2$), especially for HCN and $H_2$ molecular elimination channels. Structures and energies of the reactants, products, and relevant species along the individual reaction pathways were determined by MP2 gradient optimization and MP4 single point energy calculations. Direct four-center elimination of HCN and three-center elimination of H2 channels were identified. In addition, H or CN migration followed by HCN or H2 elimination channels via the methylcyanoethylidene intermediate was also identified. Unlike the case of crotonitrile previously studied, in which the dominant decomposition process was the direct three-center elimination of HCN, the most important reaction pathway should be the direct threecenter elimination of $H_2$ in the case of methacrylonitrile.

A New Ordering Method Using Elimination Trees (삭제나무를 이용한 새로운 순서화 방법)

  • Park, Chan-Kyoo;Doh, Seung-yong;Park, Soon-dal
    • Journal of Korean Institute of Industrial Engineers
    • /
    • v.29 no.1
    • /
    • pp.78-89
    • /
    • 2003
  • Ordering is performed to reduce the amount of fill-ins of the Cholesky factor of a symmetric positive definite matrix. This paper proposes a new ordering algorithm that reduces the fill-ins of the Cholesky factor iteratively by elimination tree rotations and clique separators. Elimination tree rotations have been used mainly to reorder the rows of the permuted matrix for the efficiency of storage space management or parallel processing, etc. In the proposed algorithm, however, they are repeatedly performed to reduce the fill-ins of the Cholesky factor. In addition, we presents a simple method for finding a minimal node separator between arbitrary two nodes of a chordal graph. The proposed reordering procedure using clique separators enables us to obtain another order of rows of which the number of till-ins decreases strictly.

An Experimental Study of NO_x$ Reduction Using PPCP (PPCP장치를 이용한 NO_x$ 저감에 대한 실험적 연구)

  • 정태용;허문회
    • Journal of the Korean Society of Safety
    • /
    • v.12 no.2
    • /
    • pp.95-101
    • /
    • 1997
  • The confidence of new technology development for NO_x$ components elimination is obtained as conclusion based 1ike followings ; 1) The technology using PSC spark is a excellent methods for NO_x$ components elimination above 70% without by-product pollutants. 2) Some materials like Oxygen, Vaporized Water and Ammonia, increase the of NO_x$ elimination by staged addition. 3) Environmental conditions like pulse frequency and peak voltage are the important dosing factors for pollutants elimination effects. 4) As the PSC technic is the up-to-date one for pollutions elimination the research and development must be executed continuously for the purpose of theoretical establishment. And the application field must be broaden in future.

  • PDF

Application of Bacterial Foraging Algorithm and Genetic Algorithm for Selective Voltage Harmonic Elimination in PWM Inverter

  • Maheswaran, D.;Rajasekar, N.;Priya, K.;Ashok kumar, L.
    • Journal of Electrical Engineering and Technology
    • /
    • v.10 no.3
    • /
    • pp.944-951
    • /
    • 2015
  • Pulse Width Modulation (PWM) techniques are increasingly employed for PWM inverter fed induction motor drive. Among various popular PWM methods used, Selective Harmonic Elimination PWM (SHEPWM) has been widely accepted for its better harmonic elimination capability. In addition, using SHEPWM, it is also possible to maintain better voltage regulation. Hence, in this paper, an attempt has been made to apply Bacterial Foraging Algorithm (BFA) for solving selective harmonic elimination problem. The problem of voltage harmonic elimination together with output voltage regulation is drafted as an optimization task and the solution is sought through proposed method. For performance comparison of BFA, the results obtained are compared with other techniques such as derivative based Newton-Raphson method, and Genetic Algorithm. From the comparison, it can be observed that BFA based approach yields better results. Further, it provides superior convergence, reduced computational burden, and guaranteed global optima. The simulation results are validated through experimental findings.

Processing of Code Optimization in CTOC (CTOC에서 코드 최적화 수행)

  • Kim, Ki-Tae;Yoo, Weon-Hee
    • Journal of Korea Multimedia Society
    • /
    • v.10 no.5
    • /
    • pp.687-697
    • /
    • 2007
  • Although the Java bytecode has numerous advantages, there are also shortcomings such as slow execution speed and difficulty in analysis. Therefore, in order for the Java class file to be effectively executed under the execution environment such as the network, it is necessary to convert it into optimized code. We implemented CTOC for transforming to optimized code. In Optimization, SSA Form that distinguish variable by assignment is used to determine value and type statically. Copy propagation, dead code elimination optimization is applied to SSA Form. However, existing SSA Form is related to variable than expression. Therefore, in this paper, to performing optimization to SSA Form expression, after performing copy propagation and dead code elimination, in addition to that, partial redundant expression elimination is performed

  • PDF

Application of the Extended Grunwald-Winstein Equation to Solvolyses of n-Propyl Fluoroformate and a Consideration of Leaving Group Effects

  • Seong, Mi-Hye;Kyong, Jin-Burm;Kim, Dong-Kook;Kevill, Dennis N.
    • Bulletin of the Korean Chemical Society
    • /
    • v.29 no.9
    • /
    • pp.1747-1751
    • /
    • 2008
  • Reactions of n-propyl fluoroformate in a variety of pure and binary solvents have been studied at 40.0 {^{\circ}C}. The extended (two-term) Grunwald-Winstein equation has been applied to the specific rates of solvolysis of npropyl fluoroformate. The sensitivities (l = 1.80 ${\pm}$ 0.17 and m = 0.96 ${\pm}$ 0.10) to changes in solvent nucleophilicity and solvent ionizing power and the $k_F/k_{Cl}$ values are similar to those for solvolyses of n-octyl fluoroformate over the full range of solvents, suggesting that the addition step of an addition-elimination mechanism is ratedetermining. These observations are also compared with those previously reported for the corresponding chloroformate and fluoroformate esters.

Effectiveness of elimination inflowing algae in water treatment plant using natural algae remover (천연 조류 제거제를 이용한 정수장 유입 조류 제거 효율)

  • Jung, Hoyoung;Kim, Younghee
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.33 no.4
    • /
    • pp.311-319
    • /
    • 2019
  • The purpose of this study was to analyze water treatment characteristics, including the efficiency of removing algae from water purification plants, by installing a demonstration facility for decontamination of algae, including natural algae remover injection equipment, in the water purification plant. Jar-test showed that the optimum injection of natural decontaminant was 20 mg/L. Of the water contaminant treatment efficiency of the intake and water purification plants, Chl-a averaged 74.0% elimination efficiency from $5.0mg/m^3$ to $1.3mg/m^3$ and the maximum treatment efficiency was 91.5% removal efficiency when the inflow concentration of Chl-a was $11.8mg/m^3$. In addition, 51.2% and 47.1% of the taste and odor indicator items, geosmin and 2-MIB, resulted from the overgrowth and decaying of algae, respectively, to identify toxic substances and odor reduction effects. In addition, elimination efficiencies of SS and Turbidity materials were higher than 70.0%. In the injection of natural algae remover, no effects such as sudden changes in water quality due to secondary reactions were found, and appropriate levels were maintained under water treatment conditions.

An On-Line Harmonic Elimination Pulse Width Modulation Scheme for Voltage Source Inverter

  • Salam, Zainal
    • Journal of Power Electronics
    • /
    • v.10 no.1
    • /
    • pp.43-50
    • /
    • 2010
  • This paper proposes a new harmonic elimination PWM (HEPWM) scheme for voltage source inverters (VSI) based on the curve fittings of certain polynomials functions. The resulting equations to calculate the switching angle of the HEPWM require only the addition and multiplication processes; therefore any number of harmonics to be eliminated and the fundamental amplitude of the pole switching waveform (NP1) can be controlled on-line. An extensive angle error analysis is carried out to determine the accuracy of the algorithm in comparison to the exact solution. To verify the workability of the technique, an experimental single phase VSI is constructed. The algorithm is implemented on a VSI using a 16-bit microprocessor. The results obtained from the test rig are compared to the theoretical prediction and the results of the MATLAB simulations.

The Relaxation and Elimination Characteristics of Polarization-Photoinduced Dichrosim in Obliquely Deposited Amorphous Chalcogenide Thin Films (경사 증착된 비정질 칼코게나이드 박막에 평광-광유기된 이색성의 이완 및 소거 특성)

  • Park, Soo-Ho;Chun, Jin-Young;Lee, Hyun-Yong;Chung, Hong-Bay
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.11 no.10
    • /
    • pp.891-896
    • /
    • 1998
  • The relaxation and elimination characteristics of polarization-photoinduced dichroism have been investigated in amorphous chalcogenide thin films deposited having normal(0。) and obique (80。) vapor incident angles. The dark relaxation kinetics of dichroism from a saturation point(D\ulcorner\ulcorner) to a certain relaxation point(D\ulcorner\ulcorner) grew to be longer on subsequent cycles of switching on and off of the inducing light, and these decays are changed from simple exponential decay to stretched exponential decay. The dichroism induced by a long time(~3.3 hrs) exposure exhibited the characteristics of longer time maintenance and smaller decreasing rate, in contrast with that by a short time (~min) exposure. In addition, the dichroism was eliminated by the exposure of non-polarized He-Ne laser.

  • PDF

A Study on the Automatic Elimination of Free Edge for Sheet Metal Forming Analysis (박판성형해석을 위한 자동 프리에지 제거에 관한 연구)

  • 유동진
    • Transactions of Materials Processing
    • /
    • v.13 no.7
    • /
    • pp.614-622
    • /
    • 2004
  • A new approach for the automatic elimination of free edges in the finite element model for the analysis of sheet metal forming processes is presented. In general, the raw finite element model constructed from an automatic mesh generator is not well suited for the direct use in the downstream forming analysis due to the many free edges which requires tedious time consuming interactive graphic operations of the users. In the present study, a general method for the automatic elimination of free edges is proposed by introducing a CAD/CAE hybrid method. In the method a trimmed parametric surface is generated to fill the holes which are orginated from the free edges by using the one step elastic finite element analysis. In addition, mesh generation algorithm is suggested which can be used in the general trimmed surface. In order to verify the validity of the proposed method, various examples including actual automobile sheet metal parts are given and discussed.