• 제목/요약/키워드: Active Oxygen

검색결과 728건 처리시간 0.026초

흰쥐 성상세포에서 산소농도의존성 유전자의 분리 (Isolation of a Hypoxia/Reoxygenation Regulatory Factor in Rat Astrocytes)

  • 박정애;송현석;이혜신;김규원
    • 약학회지
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    • 제50권2호
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    • pp.124-128
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    • 2006
  • Astrocyte has emerged as an active regulator of brain function, which connects between blood vessels and neurons as well as is a structural component of the blood-brain barrier, From its structural characteristics, astrocyte seems to sensitively respond to oxygen tension, and, in turn, generate diverse cellular cascades. Therefore, to reveal astrocytlc events by oxygen change, we screened genes whose expressions are upregulated under reoxygenation after hypoxic stress using cDNA representational difference analysis (RDA) technique. Meteorin that regulates glial differentiation was isolated from primary cultured rat astrocytes as a hypoxia/reoxygenation regulatory factor. We cloned rat version of Meteorin (rMe-teorin) and determined full-size sequences of rMeteorin. In addition, RT-PCR analysis revealed that Meteorin was increased under reoxygenation in astrocytes and highly expressed in the developing brain. Collectively, these results suggest that Meteorin may regulate astrocyte-mediated effects in response to the change of oxygen tension in the pathophysiological states.

Synthesis and reactivity over molybdenum carbide crystallites

  • Choi, Jeong-Gil
    • 한국결정성장학회지
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    • 제20권2호
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    • pp.74-79
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    • 2010
  • The synthesis and reactivities of molybdenum carbide crystallites were examined in this study. Especially, the effect of synthesis conditions were scrutinized on the preparation of molybdenum carbide crystallites. In order to perform this purpose, various characterization techniques such as BET surface area and oxygen uptake measurements were employed for the synthesized molybdenum carbide crystallites. First of all, the molybdenum carbide crystallites were synthesized using molybdenum oxide crystallites and methane gas or methane-hydrogen mixture. The experimental results showed that BET surface areas ranged from $7.4m^2/g$ to $31m^2/g$ and oxygen uptake values varied from $8.1{\mu}mol/g$ to $24.3{\mu}mol/g$. The Mo compounds were found to be active for ammonia decomposition reaction. Even though there are some molybdenum carbide crystallites that were exceeded by Pt/$Al_2O_3$ crystallite, the steady state reactivities for other molybdenum carbide crystallites were comparable to or even higher than that determined for the Pt/$Al_2O_3$ crystallite. These results implied that molybdenum carbide crystallites could be one of the promising crystallites that might be substitutes for Pt-like noble metal crystallites in the petroleum processes.

3구 노즐을 이용한 산소의 용존율 향상 (Enhance of Dissolved Oxygen Rate using a 3-prong Nozzle)

  • 박영식
    • 한국환경과학회지
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    • 제24권7호
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    • pp.947-954
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    • 2015
  • Dielectric barrier discharge plasma is a new technique in water pollutant degradation, which that is characterized by the production of chemically active species such as hydroxyl radicals, ozone, hydrogen peroxide, etc. If dissolving of plasma gas generated in the plasma reaction has increased, it is possible to increase the contaminant removal capacity. In this study, the improvement on the dissolving performance of plasma gas was evaluated by the indirect method measuring the overall oxygen transfer coefficient. Experiments were conducted to examine the effects of nozzle type, distance from water surface, air supply rate and liquid circulation rate. The experimental results showed that the $K_{La}$ value of the 3-prong nozzle is 2.67 times higher than the diffuser. The order of $K_{La}$ value with nozzle type ranked in the following order: 3-prong nozzle (inner diameter, less 1 mm) > circular nozzle (inner diameter, 1.5 mm) > ellipse nozzle (short diameter 1 mm, long diameter 2.5 mm) > circular nozzle (inner diameter, 3 mm). Optimal liquid circulation rate was appeared to be 1.7 L/min, the value of $K_{La}$ was 0.510 1/min. The value of $K_{La}$ with increasing air supply rate was revealed in the form of an exponential such as $K_{La}=0.3581e^{0.2919^*air\;flow\;rate}$.

Electrochemical Activity of a Blue Anatase TiO2 Nanotube Array for the Oxygen Evolution Reaction in Alkaline Water Electrolysis

  • Han, Junhyeok;Choi, Hyejin;Lee, Gibaek;Tak, Yongsug;Yoon, Jeyong
    • Journal of Electrochemical Science and Technology
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    • 제7권1호
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    • pp.76-81
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    • 2016
  • An anatase TiO2 nanotube array (NTA) was fabricated by anodization and successive heat treatments. When the anatase TiO2 NTA was cathodically polarized, its color changed to blue, and it could be used as an electrochemically active anode for an oxygen evolution reaction (OER) in alkaline water electrolysis. The structure of the blue anatase TiO2 NTA was controlled by the anodization conditions and its catalytic activity increased with an increase of the surface area. The activity of the blue anatase TiO2 NTA gradually reduced with the continued OER because of the partial oxidation of Ti3+ to Ti4+. However, an intermittent cathodic regeneration process could significantly slow its reduction rate. The blue anatase TiO2 NTA could be an alternative anode for alkaline water electrolysis.

ZnO-SnO2 투명박막트랜지스터의 특성에 미치는 산소분압 및 후속열처리의 영향 (The Effects of Oxygen Partial Pressure and Post-annealing on the Properties of ZnO-SnO2 Thin Film Transistors)

  • 마대영
    • 한국전기전자재료학회논문지
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    • 제25권4호
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    • pp.304-308
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    • 2012
  • Transparent thin film transistors (TTFT) were fabricated using the rf magnetron sputtered ZnO-$SnO_2$ films as active layers. A ceramic target whose Zn atomic ratio to Sn is 2:1 was employed for the deposition of ZnO-$SnO_2$ films. To study the post-annealing effects on the properties of TTFT, ZnO-$SnO_2$ films were annealed at $200^{\circ}C$ or $400^{\circ}C$ for 5 min before In deposition for source and drain electrodes. Oxygen was added into chamber during sputtering to raise the resistivity of ZnO-$SnO_2$ films. The effects of oxygen addition on the properties of TTFT were also investigated. 100 nm $Si_3N_4$ film grown on 100 nm $SiO_2$ film was used as gate dielectrics. The mobility, $I_{on}/I_{off}$, interface state density etc. were obtained from the transfer characteristics of ZnO-$SnO_2$ TTFTs.

계면활성제 혼합 천연지방산유지 고형 비누의 세척성 및 생분해성 연구 - 생분해성을 중심으로 - (A Study on the Washing Effect Biodegradation of Natural Fat Soap - On Based Biodegradation -)

  • 이봉연;류덕환;이태관
    • 한국의류산업학회지
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    • 제5권3호
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    • pp.289-294
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    • 2003
  • The purpose of the study was to get the valuable data for developing the new natural fat soaps which have an excellent biodegradation performance. Thus, natural fat soaps mixed with the two types of detergents (AOS and LAS) on the various concentrations were made and the biodegradation of the samples were analysed by Dissolved Oxygen method using active sludge. Also, the results were compared with the commercial synthetic detergents and market soaps. The results from the study were the followings: 1. The plant fat soap and the wasted oil soap with the concentration of 5 mg/l and 15 mg/l had an excellent biodegradation rather than animal fat soap. 2. There was little difference among samples with the concentration of 5 mg/l, but there was much difference among them with the concentration of 15 mg/l. 3. The periods for consuming oxygen of wasted oil soap mixed AOS and LAS was the fastest.

소금용액에 포함된 글루코오스 농도의 전기화학적 측정 (Electrochemical Determination of Glucose Concentration Contained in Salt Solution)

  • 김영한
    • 한국항만학회지
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    • 제14권4호
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    • pp.475-479
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    • 2000
  • A possibility of the implementation of a quartz crystal sensor to the determination of chemical oxygen demand is examined by checking the electrochemical behavior of the sensor in a glucose solution. Since the surface of a quartz crystal has to be oxidized, a relatively active metal is coated on the surface of a usual 9 MHz AT-cut crystal. The electrochemical behavior is investigated by measuring the changes of current, resonant frequency and resonant resistance while a constant potential is applied. The crystal is installed in a specially designed container, and a quartz crystal analyzer is utilized to measure the frequency and resistance simultaneously. The variations of the measurements are examined at different concentrations of glucose solution, and a proper relation between the concentrations of glucose solution, and a proper relation between the concentration and the measurements is analyzed. As a result, it is found that a linear relation between the concentration of less than 900 ppm and the peak current when a constant potential of -180 mV (SSCE) is applied. The relation can be utilized for the determination of glucose concentration in sea water, and considering a direct relation between gluose concentration and chemical oxygen demand tells a possibility of the measurement of chemical oxygen demand using quartz crystal oscillators.

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광용혈에 대한 플라보노이드의 세포막 보호작용에 관한 연구 (Protective Effects of The Flavonoids on Cell Membrane in the Photohemolysis)

  • Park Soo-Nam;Boo
    • 대한화장품학회지
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    • 제15권1호
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    • pp.1-36
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    • 1989
  • The protective effects of 24 flavonoids against singlet oxygen - induced photohemolysis of rabbit erythrocytes were investigated and compared with their antioxidant activities. 1. All the flavonoid aglycons investigated besides flavone and 7,8-benzoflavone showed tad dose-dependant Protective effects. Especially galagin showed the most Pronounced effect under the experimental condition. 2. The order of the radical-scavenging activities of flavonoids was as follow (-)-EGCG > flavonols > flavonols > flavones > flavanonols. The radical-scavenging activities of flavonoid glycosides were not different from those of their aglycons. 3. When added after irradiation, flavonoids did not alter the photohemolysis pattern of control. In this study, several antioxidant were found and it was newly found that Photohemolysis experiment is a convenient, reproductive diagnostic method in the screening and researching the compound which has antioxidant activity or protective effect on cell membrane against active oxygen species.

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Flavonoids with Bradykinin Antagonistic Effects from Scutellariae Radix

  • YunChoi, Hye-Sook;Yoo, Kyung-Sook;Chung, Sung-Hyun;Yang, Hyun-Sook;Choi, Jin-Jae;Kim, Young-Joo
    • 생약학회지
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    • 제23권4호
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    • pp.234-239
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    • 1992
  • Seven flavonoid components were isolated from fr. C of Scutellariae radix which showed antagonistic effects against bradykinin(BK). The results indicated that two oxygen functions (either -OH or $-OCH_3$) at 2'- and 6'-positions and/or an oxygen function at 6-position of flavone seemed to be favored for the BK inhibitory activities. Skullcapflavone-II(IV) which contains $6-OCH_3$, 2'-OH and $6-OCH_3$ in the structure was the most active among the flavones tested.

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Influence of the cathode catalyst layer thickness on the behaviour of an air breathing PEM fuel cell

  • Ferreira-Aparicio, Paloma;Chaparro, Antonio M.
    • Advances in Energy Research
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    • 제2권2호
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    • pp.73-84
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    • 2014
  • Fuel cells of proton exchange membrane type (PEMFC) working with hydrogen in the anode and ambient air in the cathode ('air breathing') have been prepared and characterized. The cells have been studied with variable thickness of the cathode catalyst layer ($L_{CL}$), maintaining constant the platinum and ionomer loads. Polarization curves and electrochemical active area measurements have been carried out. The polarization curves are analyzed in terms of a model for a flooded passive air breathing cathode. The analysis shows that $L_{CL}$ affects to electrochemical kinetics and mass transport processes inside the electrode, as reflected by two parameters of the polarization curves: the Tafel slope and the internal resistance. The observed decrease in Tafel slope with decreasing $L_{CL}$ shows improvements in the oxygen reduction kinetics which we attribute to changes in the catalyst layer structure. A decrease in the internal resistance with $L_{CL}$ is attributed to lower protonic resistance of thinner catalyst layers, although the observed decrease is lower than expected probably because the electronic conduction starts to be hindered by more hydrophilic character and thicker ionomer film.